SAFETY DATA SHEET Issue Date 15-Jul-2015 Version 1 1. PRODUCT AND COMPANY IDENTIFICATION Product identifier Product Name Other means of identification SDS# Lemon-Aid Deodorant JC-009-020 Details of the supplier of the safety data sheet Company Name Pro-Tex-All 210 S. Morton Avenue Evansville, IN 47713 812-424-8268 Emergency telephone number Emergency Telephone Chemtrec 1-800-424-9300 Classification 2. HAZARDS IDENTIFICATION OSHA Regulatory Status This chemical is considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200) Acute toxicity - Oral t classified Acute toxicity - Dermal t classified Serious eye damage/eye irritation Category 2 Label elements Warning Emergency Overview Hazard statements Causes serious eye irritation Appearance Clear Physical state Liquid Odor Lemon Precautionary Statements - Prevention Wash face, hands and any exposed skin thoroughly after handling Wear protective gloves/protective clothing/eye protection/face protection Avoid release to the environment Page 1 / 7
Precautionary Statements - Response IF exposed or concerned: Get medical advice/attention IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing If eye irritation persists: Get medical advice/attention Precautionary Statements - Disposal Dispose of contents/container to an approved waste disposal plant Hazards not otherwise classified (HNOC) Other Information Unknown Acute Toxicity 1.8% of the mixture consists of ingredient(s) of unknown toxicity Harmful to aquatic life with long lasting effects 3. COMPOSITION/INFORMATION ON INGREDIENTS Chemical Name CAS. Weight-% Trade Secret nylphenol Polyethylene Glycol Ether 127087-87-0 7-13 * 1-5 * First aid measures *The exact percentage (concentration) of composition has been withheld as a trade secret. 4. FIRST AID MEASURES General advice Skin Contact Eye contact Inhalation Ingestion Self-protection of the first aider If symptoms persist, call a physician. Wash off immediately with plenty of water for at least 15 minutes. If skin irritation persists, call a physician. Immediate medical attention is not required. Wash off immediately with soap and plenty of water while removing all contaminated clothes and shoes. Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. If symptoms persist, call a physician. Rinse thoroughly with plenty of water for at least 15 minutes, lifting lower and upper eyelids. Consult a physician. Immediately flush with plenty of water. After initial flushing, remove any contact lenses and continue flushing for at least 15 minutes. Keep eye wide open while rinsing. Remove to fresh air. If symptoms persist, call a physician. Immediate medical attention is not required. Move to fresh air in case of accidental inhalation of vapors. Immediate medical attention is not required. Rinse mouth. Drink plenty of water. Do NOT induce vomiting. Clean mouth with water and drink afterwards plenty of water. Never give anything by mouth to an unconscious person. Call a physician. Use personal protective equipment as required. Most important symptoms and effects, both acute and delayed Symptoms Any additional important symptoms and effects are described in Section 11: Toxicology Information. Indication of any immediate medical attention and special treatment needed te to physicians Treat symptomatically. 5. FIRE-FIGHTING MEASURES Page 2 / 7
Suitable extinguishing media Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Unsuitable extinguishing media Caution: Use of water spray when fighting fire may be inefficient. Specific hazards arising from the chemical Explosion data Sensitivity to Mechanical Impact ne. Sensitivity to Static Discharge ne. Protective equipment and precautions for firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures Personal precautions Use personal protective equipment as required. Avoid contact with eyes and skin. Evacuate personnel to safe areas. Keep people away from and upwind of spill/leak. Environmental precautions Environmental precautions Prevent entry into waterways, sewers, basements or confined areas. Do not flush into surface water or sanitary sewer system. Prevent further leakage or spillage if safe to do so. Prevent product from entering drains. Methods and material for containment and cleaning up Methods for containment Methods for cleaning up Prevent further leakage or spillage if safe to do so. Soak up with inert absorbent material. Pick up and transfer to properly labeled containers. After cleaning, flush away traces with water. Prevent product from entering drains. Dam up. 7. HANDLING AND STORAGE Precautions for safe handling Advice on safe handling Ensure adequate ventilation, especially in confined areas. Use personal protective equipment as required. Use with local exhaust ventilation. Do not breathe dust/fume/gas/mist/vapors/spray. Conditions for safe storage, including any incompatibilities Storage Conditions Incompatible materials Keep container tightly closed. Keep out of the reach of children. Keep containers tightly closed in a cool, well-ventilated place. Keep in properly labeled containers. ne known based on information supplied. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Control parameters Exposure Guidelines Exposure guidelines noted for ingredient(s). Chemical Name ACGIH TLV OSHA PEL NIOSH IDLH STEL: 400 ppm TWA: 200 ppm TWA: 400 ppm TWA: 980 mg/m 3 IDLH: 2000 ppm TWA: 400 ppm Page 3 / 7
NIOSH IDLH Immediately Dangerous to Life or Health (vacated) TWA: 400 ppm (vacated) TWA: 980 mg/m 3 (vacated) STEL: 500 ppm (vacated) STEL: 1225 mg/m 3 TWA: 980 mg/m 3 STEL: 500 ppm STEL: 1225 mg/m 3 Other Information Vacated limits revoked by the Court of Appeals decision in AFL-CIO v. OSHA, 965 F.2d 962 (11th Cir., 1992). Appropriate engineering controls Engineering Controls Showers, Eyewash stations & Ventilation systems. Individual protection measures, such as personal protective equipment Eye/face protection Skin and body protection Respiratory protection General Hygiene Wear safety glasses with side shields (or goggles). special technical protective measures are necessary. Prolonged or repeated contact may be drying to skin. Wear protective gloves and protective clothing if needed. If exposure limits are exceeded or irritation is experienced, NIOSH/MSHA approved respiratory protection should be worn. Positive-pressure supplied air respirators may be required for high airborne contaminant concentrations. Respiratory protection must be provided in accordance with current local regulations. Handle in accordance with good industrial hygiene and safety practice. When using do not eat, drink or smoke. Wash contaminated clothing before reuse. Regular cleaning of equipment, work area and clothing is recommended. Information on basic physical and chemical properties 9. PHYSICAL AND CHEMICAL PROPERTIES Physical state Appearance Color Odor Odor threshold Liquid Clear Yellow Lemon Property Values Remarks Method ph 8.0-9.0 Specific Gravity 1.00 Viscosity <15 cp @ 25 C Melting point/freezing point Flash point Above 200 F Boiling point / boiling range >= 212 F (at 760 mm Hg) / Evaporation rate Flammability (solid, gas) data available Flammability Limits in Air Upper flammability limit: Lower flammability limit: Vapor pressure Vapor density Water solubility Complete Partition coefficient Autoignition temperature Decomposition temperature Page 4 / 7
Other Information Density Lbs/Gal 8.34 VOC Content (%) 1.2 Reactivity data available 10. STABILITY AND REACTIVITY Chemical stability Stable under recommended storage conditions. Possibility of Hazardous Reactions ne under normal processing. Conditions to avoid Extremes of temperature and direct sunlight. Incompatible materials ne known based on information supplied. Hazardous Decomposition Products ne known based on information supplied. Information on likely routes of exposure Product Information 11. TOXICOLOGICAL INFORMATION Inhalation Eye contact Skin Contact Ingestion data available. Avoid breathing vapors or mists. May cause drowsiness or dizziness. Avoid contact with eyes. Causes serious eye irritation. data available. Avoid contact with skin. May be harmful if swallowed. Do not taste or swallow. t an expected route of exposure. Chemical Name Oral LD50 Dermal LD50 Inhalation LC50 nylphenol Polyethylene Glycol = 1310 mg/kg ( Rat ) - - Ether 127087-87-0 = 1870 mg/kg ( Rat ) = 4059 mg/kg ( Rabbit ) = 72600 mg/m 3 ( Rat ) 4 h Information on toxicological effects Symptoms Delayed and immediate effects as well as chronic effects from short and long-term exposure Sensitization Germ cell mutagenicity Carcinogenicity The table below indicates whether each agency has listed any ingredient as a carcinogen. Chemical Name ACGIH IARC NTP OSHA - Group 3 - X Reproductive toxicity STOT - single exposure STOT - repeated exposure Chronic toxicity Avoid repeated exposure. Aspiration hazard Page 5 / 7
Numerical measures of toxicity - Product Information Unknown Acute Toxicity 1.8% of the mixture consists of ingredient(s) of unknown toxicity The following values are calculated based on chapter 3.1 of the GHS document. ATEmix (oral) 12084 mg/kg ATEmix (dermal) 338250 mg/kg 12. ECOLOGICAL INFORMATION Ecotoxicity 88.8% of the mixture consists of components(s) of unknown hazards to the aquatic environment Persistence and degradability Bioaccumulation Chemical Name Partition coefficient 0.05 Other adverse effects 13. DISPOSAL CONSIDERATIONS Waste treatment methods Disposal of wastes Contaminated packaging Disposal should be in accordance with applicable regional, national and local laws and regulations. Do not reuse container. This product contains one or more substances that are listed with the State of California as a hazardous waste. Chemical Name California Hazardous Waste Status Toxic Ignitable 14. TRANSPORT INFORMATION The basic description below is specific to the container size. This information is provided for at a glance DOT information. Please refer to the container and/or shipping papers for the appropriate shipping description before tendering this material for shipment. For additional information, please contact the distributor listed in section 1 of this SDS. DOT International Inventories TSCA DSL/NDSL Please see current shipping paper for most up to date shipping information, including exemptions and special circumstances. 15. REGULATORY INFORMATION Complies Complies Legend: TSCA - United States Toxic Substances Control Act Section 8(b) Inventory DSL/NDSL - Canadian Domestic Substances List/n-Domestic Substances List Page 6 / 7
US Federal Regulations SARA 313 Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product contains a chemical or chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372 Chemical Name SARA 313 - Threshold Values % - 1.0 SARA 311/312 Hazard Categories Acute health hazard Yes Chronic Health Hazard Fire hazard Sudden release of pressure hazard Reactive Hazard CWA (Clean Water Act) This product does not contain any substances regulated as pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40 CFR 122.42) CERCLA This material, as supplied, does not contain any substances regulated as hazardous substances under the Comprehensive Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302) or the Superfund Amendments and Reauthorization Act (SARA) (40 CFR 355). There may be specific reporting requirements at the local, regional, or state level pertaining to releases of this material US State Regulations California Proposition 65 This product does not contain any Proposition 65 chemicals U.S. State Right-to-Know Regulations Chemical Name New Jersey Massachusetts Pennsylvania X X X U.S. EPA Label Information EPA Pesticide Registration Number t Applicable 16. OTHER INFORMATION NFPA Health hazards 1 Flammability 0 Instability 0 Physical and Chemical Properties Yes HMIS Health hazards 1 Flammability 0 Physical hazards 0 Personal protection X Issue Date 15-Jul-2015 Revision Date 15-Jul-2015 Revision te Disclaimer The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. End of Safety Data Sheet Page 7 / 7