SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1 Product identifier Trade name : 1.2 Relevant identified uses of the substance or mixture and uses advised against This information is not available. 1.3 Details of the supplier of the safety data sheet Company : Eckart GmbH Guentersthal 4 91235 Hartenstein Telephone : +499152770 Telefax : +499152777008 E-mail address : msds.eckart@altana.com Responsible/issuing person 1.4 Emergency telephone number GBK Gefahrgut Büro GmbH, Ingelheim, Germany: From outside US: : (001) 352-323-3500 (First call in English, response in your language is possible) US & Canada (toll free) : 1-800-5355-053 SECTION 2: Hazards identification GHS Classification : Acute toxicity, Category 4, Oral, H302 Skin irritation, Category 2, H315 Eye irritation, Category 2A, H319 Skin sensitisation, Category 1, H317 Chronic aquatic toxicity, Category 2, H411 Acute aquatic toxicity, Category 2, H401 GHS-Labelling Page 1 / 18 102000000482
Symbol(s) : Signal word : Warning Hazard statements : H302: Harmful if swallowed. H315: Causes skin irritation. H317: May cause an allergic skin reaction. H319: Causes serious eye irritation. H411: Toxic to aquatic life with long lasting effects. Precautionary statements : Prevention: P261 Avoid breathing dust/ fume/ gas/ mist/ vapours/ spray. P273 Avoid release to the environment. P280 Wear protective gloves. Response: P302 + P352 IF ON SKIN: Wash with plenty of water. P362 + P364 Take off contaminated clothing and wash it before reuse. Disposal: P501 Dispose of contents/ container to an approved waste disposal plant. Hazardous components which must be listed on the label Identification CAS-No. hexamethylene diacrylate 13048-33-4 vinyloxy ethoxyethyl acrylate 86273-46-3 Propylidynetrimethanol, ethoxylated, esters 28961-43-5 with acrylic acid ethyl phenyl(2,4,6-84434-11-7 trimethylbenzoyl)phosphinate phenyl bis(2,4,6-trimethylbenzoyl)- 162881-26-7 phosphine oxide 2-hydroxy-2-methylpropiophenone 7473-98-5 Propoxyliertes Neopentylglykoldiacrylat 84170-74-1 Page 2 / 18 102000000482
SECTION 3: Composition/information on ingredients Hazardous components Chemical Name CAS-No. EINECS-No. hexamethylene diacrylate 13048-33-4 235-921-9 Classification and labelling Skin Irrit.;2;H315 Eye Dam.;2A;H319 Skin Sens.;1;H317 Concentrati on[%] 30-60 vinyloxy ethoxyethyl acrylate 86273-46-3 Acute Tox.;3;H301 Skin Sens.;1;H317 10-30 Propylidynetrimethanol, ethoxylated, esters with acrylic acid 2-benzyl-2-dimethylamino-4- morpholinobutyrophenone 28961-43-5 Eye Irrit.;2A;H319 Skin Sens.;1;H317 119313-12-1 Aquatic Chronic;1;H400 Aquatic Acute;1;H400 10-30 5-10 ethyl phenyl(2,4,6- trimethylbenzoyl)phosphinate 84434-11-7 282-810-6 Aquatic Chronic;2;H411 Skin Sens.;1;H317 1-5 1-isopropyl-2,2- dimethyltrimethylene diisobutyrate 6846-50-0 229-934-9 Aquatic Chronic;3;H412 1-5 phenyl bis(2,4,6-trimethylbenzoyl)- phosphine oxide 162881-26-7 Skin Sens.;1;H317 Aquatic Chronic;4;H413 1-5 aluminium powder (stabilised) 7429-90-5 231-072-3 Flam. Sol.;1;H228 1-5 Page 3 / 18 102000000482
2-hydroxy-2-methylpropiophenone 7473-98-5 231-272-0 Acute Tox.;4;H302 1-5 Propoxyliertes Neopentylglykoldiacrylat 84170-74-1 Skin Sens.;1;H317 Aquatic Chronic;2;H411 1-5 For the full text of the H-Statements mentioned in this Section, see Section 16. SECTION 4: First aid measures 4.1 Description of first aid measures General advice : Move out of dangerous area. Show this safety data sheet to the doctor in attendance. If inhaled In case of skin contact In case of eye contact If swallowed : If unconscious place in recovery position and seek medical advice. If symptoms persist, call a physician. : If skin irritation persists, call a physician. If on skin, rinse well with water. If on clothes, remove clothes. : Immediately flush eye(s) with plenty of water. Remove contact lenses. Keep eye wide open while rinsing. If eye irritation persists, consult a specialist. : Keep respiratory tract clear. Do not give milk or alcoholic beverages. Never give anything by mouth to an unconscious person. If symptoms persist, call a physician. Take victim immediately to hospital. 4.2 Most important symptoms and effects, both acute and delayed Page 4 / 18 102000000482
This information is not available. 4.3 Indication of any immediate medical attention and special treatment needed This information is not available. SECTION 5: Firefighting measures 5.1 Extinguishing media Unsuitable extinguishing media : High volume water jet 5.2 Special hazards arising from the substance or mixture Specific hazards during firefighting : Do not allow run-off from fire fighting to enter drains or water courses. 5.3 Advice for firefighters Special protective equipment for firefighters Further information : Wear self contained breathing apparatus for fire fighting if necessary. : Collect contaminated fire extinguishing water separately. This must not be discharged into drains. Fire residues and contaminated fire extinguishing water must be disposed of in accordance with local regulations. SECTION 6: Accidental release measures 6.1 Personal precautions, protective equipment and emergency procedures Personal precautions : Use personal protective equipment. 6.2 Environmental precautions Environmental precautions : Prevent product from entering drains. Prevent further leakage or spillage if safe to do so. If the product contaminates rivers and lakes or drains inform Page 5 / 18 102000000482
respective authorities. 6.3 Methods and materials for containment and cleaning up Methods for cleaning up 6.4 Reference to other sections This information is not available. : Soak up with inert absorbent material (e.g. sand, silica gel, acid binder, universal binder, sawdust). Keep in suitable, closed containers for disposal. SECTION 7: Handling and storage 7.1 Precautions for safe handling Advice on safe handling Advice on protection against fire and explosion Hygiene measures : Do not breathe vapours/dust. Avoid exposure - obtain special instructions before use. Avoid contact with skin and eyes. For personal protection see section 8. Smoking, eating and drinking should be prohibited in the application area. Dispose of rinse water in accordance with local and national regulations. Persons susceptible to skin sensitisation problems or asthma, allergies, chronic or recurrent respiratory disease should not be employed in any process in which this mixture is being used. : Normal measures for preventive fire protection. : When using do not eat or drink. When using do not smoke. Wash hands before breaks and at the end of workday. 7.2 Conditions for safe storage, including any incompatibilities Requirements for storage areas and containers Page 6 / 18 102000000482 : Keep container tightly closed in a dry and well-ventilated place. Containers which are opened must be carefully resealed and kept upright to prevent leakage. Observe label precautions. Electrical installations / working materials must comply with the technological safety standards.
Other data : No decomposition if stored and applied as directed. 7.3 Specific end use(s) This information is not available. SECTION 8: Exposure controls/personal protection 8.1 Control parameters Germany: Components CAS-No. Value type (Form of exposure) aluminium 7429-90-5 AGW (Inhalable fraction) Further information aluminium 7429-90-5 AGW (Alveolate fraction) Further information Control parameters Update Basis 10 mg/m3 2009-02-16 DE TRGS 900 Commission for dangerous substances 1,35 mg/m3 2009-02-16 DE TRGS 900 Commission for dangerous substances aluminium 7429-90-5 PC-TWA 3 mg/m3 2007-04-27 aluminium 7429-90-5 PC-TWA 3 mg/m3 2007-04-27 8.2 Exposure controls Personal protective equipment Eye protection : Eye wash bottle with pure water Wear face-shield and protective suit for abnormal processing problems. Hand protection Page 7 / 18 102000000482
Remarks : The suitability for a specific workplace should be discussed with the producers of the protective gloves. Skin and body protection : Choose body protection according to the amount and concentration of the dangerous substance at the work place. Environmental exposure controls General advice : Prevent product from entering drains. Prevent further leakage or spillage if safe to do so. If the product contaminates rivers and lakes or drains inform respective authorities. SECTION 9: Physical and chemical properties 9.1 Information on basic physical and chemical properties Appearance Colour Odour ph Freezing point : liquid : characteristic Boiling point/boiling range : 101 C Flash point : 101 C Bulk density Flammability (solid, gas) Auto-flammability Upper explosion limit Lower explosion limit Vapour pressure Page 8 / 18 102000000482
Density Water solubility Miscibility with water Solubility in other solvents Partition coefficient: n-octanol/water Auto-ignition temperature Thermal decomposition Viscosity, dynamic Viscosity, kinematic Flow time : immiscible 9.2 Other information SECTION 10: Stability and reactivity 10.1 Reactivity No decomposition if stored and applied as directed. 10.2 Chemical stability No decomposition if stored and applied as directed. 10.3 Possibility of hazardous reactions Hazardous reactions : No decomposition if stored and applied as directed. 10.4 Conditions to avoid Conditions to avoid 10.5 Incompatible materials Materials to avoid Page 9 / 18 102000000482
10.6 Hazardous decomposition products Other information SECTION 11: Toxicological information 11.1 Information on toxicological effects Acute toxicity Components: 13048-33-4 : Acute oral toxicity : LD50 rat: > 5 000 mg/kg Method: OECD Test Guideline 401 Acute inhalation toxicity : rat: 0,14 mg/l Exposure time: 7 h Acute dermal toxicity : LD50 rabbit: 3 650 mg/kg Method: OECD Test Guideline 402 84434-11-7 : Acute oral toxicity : rat: > 5 000 mg/kg Method: OECD Test Guideline 401 Acute dermal toxicity : rat: > 2 000 mg/kg Page 10 / 18 102000000482
Method: OECD Test Guideline 402 6846-50-0 : Acute oral toxicity : LD50 rat: > 2 000 mg/kg Acute inhalation toxicity : LC50 rat: > 0,12 mg/l Exposure time: 6 h Acute dermal toxicity : LD50 guinea pig: > 2 000 mg/kg 162881-26-7 : Acute oral toxicity : LD50 rat: > 2 000 mg/kg Method: OECD Test Guideline 401 Acute dermal toxicity : LD50 rat: > 2 000 mg/kg Method: OECD Test Guideline 402 Skin corrosion/irritation Product May cause skin irritation and/or dermatitis. Serious eye damage/eye irritation Product Page 11 / 18 102000000482
May cause irreversible eye damage. Respiratory or skin sensitisation Product Causes sensitisation. Carcinogenicity Toxicity to reproduction/fertility Reprod.Tox./Development/Teratogenicity STOT - single exposure STOT - repeated exposure Aspiration toxicity Further information Product Page 12 / 18 102000000482
SECTION 12: Ecological information 12.1 Toxicity 12.2 Persistence and degradability 12.3 Bioaccumulative potential 12.4 Mobility in soil 12.5 Results of PBT and vpvb assessment 12.6 Other adverse effects Product: Additional ecological information : An environmental hazard cannot be excluded in the event of unprofessional handling or disposal., Toxic to aquatic life with long lasting effects. Page 13 / 18 102000000482
SECTION 13: Disposal considerations 13.1 Waste treatment methods Product Contaminated packaging : The product should not be allowed to enter drains, water courses or the soil. Do not contaminate ponds, waterways or ditches with chemical or used container. Send to a licensed waste management company. : Empty remaining contents. Dispose of as unused product. Do not re-use empty containers. SECTION 14: Transport information 14.1 UN number ADR : 3082 CN_DG : 3082 TDG : 3082 CFR : 3082 IMDG : 3082 IATA : 3082 14.2 Proper shipping name ADR CN_DG Page 14 / 18 102000000482 : ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (2-Benzyl-2-dimethylamino-4-morpholinobutyrophenone) : ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S (2-Benzyl-2-dimethylamino-4-morpholinobutyrophenone)
TDG CFR IMDG IATA 14.3 Transport hazard class ADR : 9 CN_DG : 9 TDG : 9 CFR : 9 IMDG : 9 IATA : 9 14.4 Packing group ADR Packaging group Classification Code Page 15 / 18 102000000482 : ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (2-Benzyl-2-dimethylamino-4-morpholinobutyrophenone) : ENVIRONMENTALLY HAZARDOUS SUBSTANCES, LIQUID, N.O.S. (2-Benzyl-2-dimethylamino-4-morpholinobutyrophenone) : ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (2-Benzyl-2-dimethylamino-4-morpholinobutyrophenone) : ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. : III (2-Benzyl-2-dimethylamino-4-morpholinobutyrophenone) : M6 Hazard identification No : 90 Labels : 9 Tunnel restriction code CN_DG Packaging group : (E) : III
Labels : 9 TDG Packaging group : III Labels : 9 CFR Packaging group : III Labels : 9 IMDG Packaging group : III Labels : 9 EmS Number IATA Packing instruction (cargo aircraft) Packing instruction (passenger aircraft) Packing instruction (LQ) Packaging group : F-A, S-F : 964 : 964 : Y964 : III Labels : 9 14.5 Environmental hazards ADR IMDG : Environmentally hazardous : Marine pollutant 14.6 Special precautions for user 14.7 Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code Page 16 / 18 102000000482
SECTION 15: Regulatory information 15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture 15.2 Chemical Safety Assessment SECTION 16: Other information Full text of H-Statements H315 H319 H317 H301 H317 H319 H317 H400 H400 H411 H317 H412 H317 H413 H228 H302 H317 H411 Causes skin irritation. Causes serious eye irritation. May cause an allergic skin reaction. Toxic if swallowed. May cause an allergic skin reaction. Causes serious eye irritation. May cause an allergic skin reaction. Very toxic to aquatic life. Very toxic to aquatic life. Toxic to aquatic life with long lasting effects. May cause an allergic skin reaction. Harmful to aquatic life with long lasting effects. May cause an allergic skin reaction. May cause long lasting harmful effects to aquatic life. Flammable solid. Harmful if swallowed. May cause an allergic skin reaction. Toxic to aquatic life with long lasting effects. The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is Page 17 / 18 102000000482
not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. Page 18 / 18 102000000482