Material Safety Data Sheet Revision Number: 004.1 Issue date: 01/04/2012 1. PRODUCT AND COMPANY IDENTIFICATION Product type: Liquid Flux Item number: M00604 Region: United States Company address: Contact information: Henkel Electronic Materials LLC Telephone: 1.888.9.HENKEL (1.888.943.6535) 14000 Jamboree Road MEDICAL EMERGENCY Phone: Poison Control Center Irvine, CA 92606 1-877-671-4608 (toll free) or 1-303-592-1711 TRANSPORT EMERGENCY Phone: CHEMTREC 1-800-424-9300 (toll free) or 1-703-527-3887 Internet: www.henkelna.com 2. HAZARDS IDENTIFICATION EMERGENCY OVERVIEW HMIS: Physical state: Liquid HEALTH: *2 Color: Green FLAMMABILITY: 3 Odor: Alcoholic PHYSICAL HAZARD: 0 Personal Protection: See MSDS Section 8 WARNING: FLAMMABLE LIQUID AND VAPOR. MAY BE HARMFUL IF ABSORBED THROUGH SKIN. MAY CAUSE SKIN IRRITATION. HARMFUL IF SWALLOWED OR INHALED. CAUSES EYE, SKIN AND RESPIRATORY TRACT IRRITATION. Relevant routes of exposure: Skin, Lungs, Eye contact from liquid, aerosols or vapor Potential Health Effects Inhalation: Skin contact: Eye contact: Ingestion: Existing conditions aggravated by exposure: Inhalation of vapors or mists of the product may be irritating to the respiratory system. Exposure to high doses may cause central nervous system depression. Such doses may also cause adverse effects in the liver, kidneys, and lungs. May cause skin irritation with discomfort or rash. Harmful if absorbed through skin. Vapors may irritate eyes. Contact with eyes will cause irritation. Liquid or vapor can cause moderate to severe irritation. May cause corneal injury. Toxic if swallowed. Extreme overexposure may result in unconsciousness and possibly death. Other pre-existing skin conditions. Pre-existing skin, respiratory, central nervous system, liver and kidney conditions may be susceptible. This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200). See Section 11 for additional toxicological information. 3. COMPOSITION / INFORMATION ON INGREDIENTS Hazardous components CAS NUMBER % 2-Propanol 67-63-0 60-100 Citric acid 77-92-9 1-5 Ammonium chloride 12125-02-9 1-5 Page 1 of 5
4. FIRST AID MEASURES Inhalation: Skin contact: Move to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention. Immediately flush skin with plenty of water (using soap, if available). Remove contaminated clothing and footwear. Wash clothing before reuse. Get medical attention. Eye contact: Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Get medical attention. Ingestion: Drink plenty of water. Call a physician immediately. 5. FIRE FIGHTING MEASURES Flash point: Autoignition temperature: 14 C (57.2 F) 399 C (750.2 F) Flammable/Explosive limits - lower: 2 % Flammable/Explosive limits - upper: 12.7 % Extinguishing media: Special firefighting procedures: Unusual fire or explosion hazards: Hazardous combustion products: Water spray (fog), foam, dry chemical or carbon dioxide. Wear self-contained breathing apparatus and full protective clothing, such as turn-out gear. Oxides of carbon. Thermal decomposition can lead to release of irritating gases and vapors. 6. ACCIDENTAL RELEASE MEASURES Use personal protection recommended in Section 8, isolate the hazard area and deny entry to unnecessary and unprotected personnel. Environmental precautions: Clean-up methods: Prevent further leakage or spillage if safe to do so. Do not allow product to enter sewer or waterways. Evacuate personnel to safe areas. Remove all sources of ignition. Wear suitable protective clothing, gloves and eye/face protection. Soak up with inert absorbent material (e.g. sand, silica gel, acid binder, universal binder, sawdust). Keep in suitable and closed containers for disposal. 7. HANDLING AND STORAGE Handling: Storage: Use only with adequate ventilation. Keep away from heat, spark and flame. Keep container closed. Empty containers retain product residue, so obey hazard warnings and handle empty containers as if they were full. Store away from heat, sparks, flames, or other sources of ignition. Store in original container until ready to use. For information on product shelf life, please review labels on container or check the Technical Data Sheet. 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Employers should complete an assessment of all workplaces to determine the need for, and selection of, proper exposure controls and protective equipment for each task performed. Page 2 of 5
Hazardous components ACGIH TLV OSHA PEL AIHA WEEL OTHER 2-Propanol 200 ppm TWA 400 ppm (980 400 ppm STEL mg/m3) TWA Citric acid Ammonium chloride 10 mg/m3 TWA Fume. 20 mg/m3 STEL Fume. Engineering controls: Respiratory protection: Eye/face protection: Skin protection: Ensure adequate ventilation, especially in confined areas. Provide local ventilation for prolonged use in a confined area. Use NIOSH approved respirator if there is potential to exceed exposure limit(s). Safety goggles or safety glasses with side shields. Chemical resistant, impermeable gloves. 9. PHYSICAL AND CHEMICAL PROPERTIES Physical state: Liquid Color: Green Odor: Alcoholic Odor threshold: Not available. ph: Vapor pressure: 6.6000000 kpa (25 C (77 F)) Boiling point/range: 82 C (179.6 F) Melting point/ range: Specific gravity: 0.826 Vapor density: Heavier than air. Flash point: 14 C (57.2 F) Flammable/Explosive limits - lower: 2 % Flammable/Explosive limits - upper: 12.7 % Autoignition temperature: 399 C (750.2 F) Evaporation rate: Solubility in water: Soluble Partition coefficient (n-octanol/water): VOC content: 73 %; 602 g/l (calculated) 10. STABILITY AND REACTIVITY Stability: Hazardous reactions: Hazardous decomposition products: Incompatible materials: Conditions to avoid: Stable Will not occur. Oxides of carbon. Thermal decomposition can lead to release of irritating gases and vapors. Oxidizing agents. Keep away from open flames, hot surfaces and sources of ignition. 11. TOXICOLOGICAL INFORMATION Hazardous components NTP Carcinogen IARC Carcinogen OSHA Carcinogen (Specifically Regulated) 2-Propanol No No No Citric acid No No No Ammonium chloride No No No Page 3 of 5
Hazardous components 2-Propanol Citric acid Ammonium chloride Health Effects/Target Organs Allergen, Blood, Brain, Central nervous system, Irritant, Kidney, Liver, Spleen Allergen, Corrosive, Eyes, Irritant Central nervous system, Eyes, Irritant, Metabolic 12. ECOLOGICAL INFORMATION Ecological information: No specific studies have been conducted by Henkel on the ecotoxicity or environmental fate of this material; however, commonly available data on the material indicate that uncontrolled releases to soil, ground water, or surface waters could entail acute and/or chronic ecological effects, depending on the quantity and concentration of such releases. Releases of volatile components to the atmosphere are not believed to entail significant ecological consequences provided such releases are within the exposure levels set forth in this document. Accordingly, all appropriate measures should be taken to avoid uncontrolled releases to the environment, and any spills or other uncontrolled releases which may occur should be contained and cleaned up immediately in accordance with Section 6. 13. DISPOSAL CONSIDERATIONS Information provided is for unused product only. Recommended method of disposal: Hazardous waste number: Follow all local, state, federal and provincial regulations for disposal. Not a RCRA hazardous waste. U.S. Department of Transportation Ground (49 CFR) Isopropanol International Air Transportation (ICAO/IATA) Isopropanol 14. TRANSPORT INFORMATION Water Transportation (IMO/IMDG) ISOPROPANOL United States Regulatory Information 15. REGULATORY INFORMATION TSCA 8 (b) Inventory Status: TSCA 12(b) Export Notification: CERCLA/SARA Section 302 EHS: CERCLA/SARA Section 311/312: CERCLA/SARA 313: California Proposition 65: All components are listed or are exempt from listing on the Toxic Substances Control Act Inventory. above reporting de minimus above reporting de minimus Fire, Immediate Health This product contains the following toxic chemicals subject to the reporting requirements of section 313 of the Emergency Planning and Community Right-To-Know Act of 1986 (40 CFR 372). Ammonium chloride (CAS# 12125-02-9). No California Proposition 65 listed chemicals are known to be present. Page 4 of 5
Canada Regulatory Information CEPA DSL/NDSL Status: All components are listed on or are exempt from listing on the Canadian Domestic Substances List. WHMIS hazard class: D.2.B, B.2 16. OTHER INFORMATION This material safety data sheet contains changes from the previous version in sections: New Material Safety Data Sheet format. Prepared by: Lou Fabrizio, Regulatory Affairs Specialist DISCLAIMER: The data contained herein are furnished for information only and are believed to be reliable. However, Henkel Corporation and its affiliates ( Henkel ) does not assume responsibility for any results obtained by persons over whose methods Henkel has no control. It is the user s responsibility to determine the suitability of Henkel s products or any production methods mentioned herein for a particular purpose, and to adopt such precautions as may be advisable for the protection of property and persons against any hazards that may be involved in the handling and use of any Henkel s products. In light of the foregoing, Henkel specifically disclaims all warranties, express or implied, including warranties of merchantability and fitness for a particular purpose, arising from sale or use of Henkel s products. Henkel further disclaims any liability for consequential or incidental damages of any kind, including lost profits. Page 5 of 5