Material Safety Data Sheet Agilent Technologies Australia Pty Ltd 679 Springvale Road Mulgrave Victoria 3170, Australia 1800 802 402 10 percent Triton X-102 1. Identification of the material and supplier Names Product name Part No. ADG Supplier Supplier/Manufacturer Emergency telephone number Uses Area of application Material uses 10 percent Triton X-102 5185-5975 Not regulated as Dangerous Goods according to the ADG Code Agilent Technologies Australia Pty Ltd 679 Springvale Road Mulgrave Victoria 3170, Australia 1800 802 402 CHEMTREC +(44)-870-8200418 Industrial applications, Professional applications. 50 ml 2. Hazards identification Classification Risk phrases Safety phrases Statement of hazardous/ dangerous nature 3. Xi; R41 R52/53 R41- Risk of serious damage to eyes. R52/53- Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment. S26- In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S36/39- Wear suitable protective clothing and eye/face protection. HAZARDOUS SUBSTANCE. NON-DANGEROUS GOODS. Composition/information on ingredients Mixture Yes. Ingredient name CAS number Concentration 9002-93-1 <10 Other ingredients, determined not to be hazardous according to Safe Work Australia criteria, and not dangerous according to the ADG Code, make up the product concentration to 100%. There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment and hence require reporting in this section. 4. First-aid measures Inhalation Remove victim to fresh air and keep at rest in a position comfortable for breathing. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Get medical attention if adverse health effects persist or are severe. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband. Version 2 Page 1/6
4. Ingestion Skin contact Eye contact First-aid measures Protection of first-aiders Advice to doctor 5. Fire-fighting measures Extinguishing media Suitable Not suitable Special exposure hazards Hazardous thermal decomposition products Special protective equipment for fire-fighters 6. Wash out mouth with water. Remove dentures if any. Remove victim to fresh air and keep at rest in a position comfortable for breathing. If material has been swallowed and the exposed person is conscious, give small quantities of water to drink. Stop if the exposed person feels sick as vomiting may be dangerous. Do not induce vomiting unless directed to do so by medical personnel. If vomiting occurs, the head should be kept low so that vomit does not enter the lungs. Get medical attention if adverse health effects persist or are severe. Never give anything by mouth to an unconscious person. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband. Flush contaminated skin with plenty of water. Remove contaminated clothing and shoes. Get medical attention if symptoms occur. Wash clothing before reuse. Clean shoes thoroughly before reuse. Get medical attention immediately. Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10 minutes. Chemical burns must be treated promptly by a physician. No action shall be taken involving any personal risk or without suitable training. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. No specific treatment. Treat symptomatically. Contact poison treatment specialist immediately if large quantities have been ingested or inhaled. Use an extinguishing agent suitable for the surrounding fire. None known. Accidental release measures Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. This material is harmful to aquatic organisms. Fire water contaminated with this material must be contained and prevented from being discharged to any waterway, sewer or drain. In a fire or if heated, a pressure increase will occur and the container may burst. Decomposition products may include the following materials carbon dioxide carbon monoxide Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode. Personal precautions Environmental precautions Methods for cleaning up No action shall be taken involving any personal risk or without suitable training. Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilt material. Avoid breathing vapour or mist. Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective equipment (see Section 8). Avoid dispersal of spilt material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air). Water polluting material. Stop leak if without risk. Move containers from spill area. Dilute with water and mop up if water-soluble. Alternatively, or if water-insoluble, absorb with an inert dry material and place in an appropriate waste disposal container. Dispose of via a licensed waste disposal contractor. Version 2 Page 2/6
7. Handling and storage Handling Storage 8. Put on appropriate personal protective equipment (see Section 8). Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. Remove contaminated clothing and protective equipment before entering eating areas. Do not get in eyes or on skin or clothing. Do not ingest. Avoid breathing vapour or mist. Keep in the original container or an approved alternative made from a compatible material, kept tightly closed when not in use. Empty containers retain product residue and can be hazardous. Do not reuse container. Store in accordance with local regulations. Store in original container protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10) and food and drink. Keep container tightly closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabelled containers. Use appropriate containment to avoid environmental contamination. Exposure controls/personal protection Occupational exposure limits Recommended monitoring procedures Exposure controls Engineering measures Hygiene measures Eyes Hands Respiratory Skin Environmental exposure controls No exposure standard allocated. If this product contains ingredients with exposure limits, personal, workplace atmosphere or biological monitoring may be required to determine the effectiveness of the ventilation or other control measures and/or the necessity to use respiratory protective equipment. Reference should be made to appropriate monitoring standards. Reference to national guidance documents for methods for the determination of hazardous substances will also be required. No special ventilation requirements. Good general ventilation should be sufficient to control worker exposure to airborne contaminants. If this product contains ingredients with exposure limits, use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure below any recommended or statutory limits. Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period. Appropriate techniques should be used to remove potentially contaminated clothing. Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location. Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists or dusts. If contact is possible, the following protection should be worn, unless the assessment indicates a higher degree of protection chemical splash goggles. Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. Considering the parameters specified by the glove manufacturer, check during use that the gloves are still retaining their protective properties. It should be noted that the time to breakthrough for any glove material may be different for different glove manufacturers. In the case of mixtures, consisting of several substances, the protection time of the gloves cannot be accurately estimated. Use a properly fitted, air-purifying or air-fed respirator complying with an approved standard if a risk assessment indicates this is necessary. Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator. Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels. Version 2 Page 3/6
9. Physical and chemical properties Physical state Colour Odour Boiling point Melting point Vapour pressure Flash point Flammable limits Vapour density ph Auto-ignition temperature Solubility 10. Liquid. Not available. Not available. Not available. Not available. Not available. Not available. Not available. Not available. Not available. Not available. Stability and reactivity Easily soluble in the following materials cold water and hot water. Chemical stability Possibility of hazardous reactions Conditions to avoid Materials to avoid Hazardous decomposition products The product is stable. Under normal conditions of storage and use, hazardous reactions will not occur. Reactive or incompatible with the following materials oxidizing materials, reducing materials, metals, acids and alkalis. Under normal conditions of storage and use, hazardous decomposition products should not be produced. 11. Toxicological information Potential acute health effects Inhalation Ingestion Skin contact Eye contact Acute toxicity Severely irritating to eyes. Risk of serious damage to eyes. Product/ingredient name Result Species Dose Exposure LD50 Oral Rat 1800 mg/kg - Conclusion/Summary Potential chronic health effects Chronic effects Carcinogenicity Not available. Irritation/Corrosion Product/ingredient name Result Species Score Exposure Observation Conclusion/Summary Sensitiser Conclusion/Summary Not available. Not available. Eyes - Moderate irritant Rabbit - 24 hours 10 microliters Skin - Mild irritant Rabbit - 24 hours 500 microliters Chronic toxicity / Carcinogenicity / Mutagenicity / Teratogenicity / Reproductive toxicity Not available. Version 2 Page 4/6 - -
11. Toxicological information Mutagenicity Teratogenicity Developmental effects Fertility effects Over-exposure signs/symptoms Inhalation Ingestion Skin Eyes Target organs 12. Ecotoxicity Ecological information Aquatic ecotoxicity Product/ingredient name Other ecological information Bioaccumulative potential Product/ingredient name Other adverse effects Adverse symptoms may include the following pain or irritation watering redness Contains material which may cause damage to the following organs eyes. Acute LC50 5.85 mg/l Fresh water Product/ingredient name Aquatic half-life Photolysis Biodegradability - - Readily 13. Result Disposal considerations Methods of disposal This material is harmful to aquatic life with long lasting effects. Species LogPow BCF Potential 4.86 - high Crustaceans - Ceriodaphnia rigaudi - Neonate Exposure 48 hours Acute LC50 11.2 mg/l Fresh water Daphnia - Daphnia magna - 48 hours Neonate Acute LC50 4500 μg/l Fresh water Fish - Pimephales promelas 96 hours The generation of waste should be avoided or minimised wherever possible. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Waste should not be disposed of untreated to the sewer unless fully compliant with the requirements of all authorities with jurisdiction. Waste packaging should be recycled. Incineration or landfill should only be considered when recycling is not feasible. This material and its container must be disposed of in a safe way. Care should be taken when handling emptied containers that have not been cleaned or rinsed out. Empty containers or liners may retain some product residues. Avoid dispersal of spilt material and runoff and contact with soil, waterways, drains and sewers. Version 2 Page 5/6
14. Transport information Regulatory information ADG / IMDG / IATA Not regulated as Dangerous Goods according to the ADG Code. 15. Regulatory information Standard Uniform Schedule of Medicine and Poisons Not regulated. Control of Scheduled Carcinogenic Substances Ingredient name Schedule No listed substance Australia inventory (AICS) All components are listed or exempted. 16. Other information Date of issue 11/09/2013 Date of previous issue 05/08/2011. Indicates information that has changed from previously issued version. Disclaimer The information contained in this document is based on Agilent s state of knowledge at the time of preparation. No warranty as to its accurateness, completeness or suitability for a particular purpose is expressed or implied. Version 2 Page 6/6