Material Safety Data Sheet 1. Identification of the material and supplier Names Product name Supplier Supplier/Manufacturer Sikaflex -291 Sika (NZ) Ltd. PO Box 19 192 Avondale Auckland 1746 Telephone no. Uses Use of the substance/preparation 85-91 Patiki Road Avondale Auckland 1026 www.sika.co.nz +64 9 820 2900 Fax no. +64 9 828 4091 Emerency telephone number 2. 0800 734 607 Hazards identification Safety phrases Chemical product for construction and industry Classification R42 ERMA NZ Approval Code HSR002670, HSNO Hazard Classification 6.5A Risk phrases Statement of hazardous/danerous nature 3. Mixture R42- May cause sensitisation by inhalation. S23- Do not breathe as/fumes/vapour/spray S45- In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). HAZARDOUS SUBSTANCE. NON-DANGEROUS GOODS. Composition/information on inredients Yes. xylene 1330-20-7 1 - <10 Naphtha (petroleum), hydrodesulfurized heavy 64742-82-1 1 - <10 4,4 -methylenediphenyl diisocyanate 101-68-8 0.1 - <1 Other inredients, determined not to be hazardous accordin to NOHSC criteria, and not danerous accordin to the ADG Code, make up the product concentration to 100%. There are no additional inredients present which, within the current knowlede of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment and hence require reportin in this section. 4. First-aid measures First-aid measures Inhalation Move exposed person to fresh air. If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathin apparatus. Keep person warm and at rest. If not breathin, if breathin is irreular or if respiratory arrest occurs, provide artificial respiration or oxyen by trained personnel. It may be danerous to the person providin aid to ive mouth-to-mouth resuscitation. Get medical attention. If unconscious, place in recovery position and et medical attention immediately. Maintain an open airway. Loosen tiht clothin such as a collar, tie, belt or waistband. In the event of any complaints or symptoms, avoid further exposure. Version 1 Pae 1/7
4. Inestion First-aid measures Skin contact Eye contact Protection of first-aiders Notes to physician 5. Fire-fihtin measures Extinuishin media Special protective equipment for fire-fihters Wash out mouth with water. Remove dentures if any. Move exposed person to fresh air. Keep person warm and at rest. If material has been swallowed and the exposed person is conscious, ive small quantities of water to drink. Stop if the exposed person feels sick as vomitin may be danerous. Do not induce vomitin unless directed to do so by medical personnel. If vomitin occurs, the head should be kept low so that vomit does not enter the luns. Get medical attention if adverse health effects persist or are severe. Never ive anythin by mouth to an unconscious person. If unconscious, place in recovery position and et medical attention immediately. Maintain an open airway. Loosen tiht clothin such as a collar, tie, belt or waistband. Flush contaminated skin with plenty of water. Remove contaminated clothin and shoes. Continue to rinse for at least 10 minutes. Get medical attention if symptoms occur. Wash clothin before reuse. Clean shoes thorouhly before reuse. Immediately flush eyes with plenty of water, occasionally liftin the upper and lower eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10 minutes. Get medical attention if irritation occurs. No action shall be taken involvin any personal risk or without suitable trainin. If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathin apparatus. It may be danerous to the person providin aid to ive mouth-to-mouth resuscitation. No specific treatment. Treat symptomatically. Contact poison treatment specialist immediately if lare quantities have been inested or inhaled. Suitable Use an extinuishin aent suitable for the surroundin fire. Not suitable None known. Special exposure hazards Promptly isolate the scene by removin all persons from the vicinity of the incident if there is a fire. No action shall be taken involvin any personal risk or without suitable trainin. Hazardous combustion products Special protective equipment for fire-fihters In a fire or if heated, a pressure increase will occur and the container may burst. Fire-fihters should wear appropriate protective equipment and self-contained breathin apparatus (SCBA) with a full face-piece operated in positive pressure mode. Decomposition products may include the followin materials carbon dioxide carbon monoxide haloenated compounds metal oxide/oxides Fire-fihters should wear appropriate protective equipment and self-contained breathin apparatus (SCBA) with a full face-piece operated in positive pressure mode. 6. Accidental release measures Personal precautions Environmental precautions Lare spill No action shall be taken involvin any personal risk or without suitable trainin. Evacuate surroundin areas. Keep unnecessary and unprotected personnel from enterin. Do not touch or walk throuh spilt material. Avoid breathin vapour or mist. Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective equipment (see section 8). Avoid dispersal of spilt material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air). Stop leak if without risk. Move containers from spill area. Approach the release from upwind. Prevent entry into sewers, water courses, basements or confined areas. Wash spillaes into an effluent treatment plant or proceed as follows. Contain and collect spillae with non-combustible, absorbent material e.. sand, earth, vermiculite or diatomaceous earth and place in container for disposal accordin to local reulations (see section 13). Dispose of via a licensed waste disposal contractor. Contaminated absorbent material may pose the same hazard as the spilt product. Note see section 1 for emerency contact information and section 13 for waste disposal. Version 1 Pae 2/7
6. Small spill 7. Handlin Storae 8. Accidental release measures Handlin and storae Exposure controls Enineerin measures Hyiene measures Eyes Hands Respiratory Stop leak if without risk. Move containers from spill area. Dilute with water and mop up if water-soluble. Alternatively, or if water-insoluble, absorb with an inert dry material and place in an appropriate waste disposal container. Dispose of via a licensed waste disposal contractor. Put on appropriate personal protective equipment (see section 8). Eatin, drinkin and smokin should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eatin, drinkin and smokin. Persons with a history of asthma, alleries or chronic or recurrent respiratory disease should not be employed in any process in which this product is used. Do not et in eyes or on skin or clothin. Do not inest. Avoid breathin vapour or mist. Use only with adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Keep in the oriinal container or an approved alternative made from a compatible material, kept tihtly closed when not in use. Empty containers retain product residue and can be hazardous. Do not reuse container. Store in accordance with local reulations. Store in oriinal container protected from direct sunliht in a dry, cool and well-ventilated area, away from incompatible materials (see section 10) and food and drink. Keep container tihtly closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upriht to prevent leakae. Do not store in unlabelled containers. Use appropriate containment to avoid environmental contamination. Exposure controls/personal protection Occupational exposure limits Inredient name Exposure limits xylene Safe Work Australia (Australia, 8/2005). STEL 655 m/m³ 15 minute(s). STEL 150 ppm 15 minute(s). TWA 350 m/m³ 8 hour(s). TWA 80 ppm 8 hour(s). naphtha (petroleum), hydrodesulfurized heavy TRGS900 AGW (Germany, 12/2007). Schichtmittelwert 300 m/m³ 4,4 -methylenediphenyl diisocyanate Safe Work Australia (Australia, 8/2005). Skin sensitiser. STEL 0.07 m/m³ 15 minute(s). TWA 0.02 m/m³ 8 hour(s). Recommended monitorin procedures If this product contains inredients with exposure limits, personal, workplace atmosphere or bioloical monitorin may be required to determine the effectiveness of the ventilation or other control measures and/or the necessity to use respiratory protective equipment. Use only with adequate ventilation. If user operations enerate dust, fumes, as, vapour or mist, use process enclosures, local exhaust ventilation or other enineerin controls to keep worker exposure to airborne contaminants below any recommended or statutory limits. Wash hands, forearms and face thorouhly after handlin chemical products, before eatin, smokin and usin the lavatory and at the end of the workin period. Appropriate techniques should be used to remove potentially contaminated clothin. Wash contaminated clothin before reusin. Ensure that eyewash stations and safety showers are close to the workstation location. Safety eyewear complyin with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists or dusts. Chemical-resistant, impervious loves complyin with an approved standard should be worn at all times when handlin chemical products if a risk assessment indicates this is necessary. Use a properly fitted, air-purifyin or air-fed respirator complyin with an approved standard if a risk assessment indicates this is necessary. Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe workin limits of the selected respirator. Version 1 Pae 3/7
8. Skin Exposure controls/personal protection Environmental exposure controls 9. Physical state Colour Odour Density Flash point Viscosity Solubility 10. Stability Personal protective equipment for the body should be selected based on the task bein performed and the risks involved and should be approved by a specialist before handlin this product. Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection leislation. In some cases, fume scrubbers, filters or enineerin modifications to the process equipment will be necessary to reduce emissions to acceptable levels. Physical and chemical properties Conditions to avoid Materials to avoid Hazardous decomposition products 11. Liquid. [Paste.] Various. Stability and reactivity Characteristic. 1.26 /cm 3 [20 C (68 F)] Closed cup >100 C (>212 F) Dynamic Not applicable. Insoluble in the followin materials cold water. The product is stable. Toxicoloical information Potential acute health effects Inhalation Inestion Under normal conditions of storae and use, hazardous decomposition products should not be produced. May cause sensitisation by inhalation. No known sinificant effects or critical hazards. Skin contact No known sinificant effects or critical hazards. Eye contact No known sinificant effects or critical hazards. Acute toxicity Product/inredient name Result Species Dose Exposure xylene LD50 Dermal Rabbit >1700 m/k - LD50 Rat 2459 m/k - Intraperitoneal LD50 Mouse 1548 m/k - Intraperitoneal LD50 Oral Rat 4300 m/k - LD50 Oral Mouse 2119 m/k - LD50 Rat 1700 m/k - Subcutaneous LDLo Rabbit 129 m/k - Intravenous TDLo Dermal Mouse 4.21 ml/k - LC50 Inhalation Rat 5000 ppm 4 hours Gas. 4,4 -methylenediphenyl diisocyanate LD50 Oral Rat 9200 m/k - LD50 Oral Mouse 2200 m/k - Potential chronic health effects Chronic toxicity Carcinoenicity Mutaenicity Teratoenicity Not available. Not available. Not available. Not available. Not available. Version 1 Pae 4/7
11. Toxicoloical information Reproductive toxicity Chronic effects Carcinoenicity Mutaenicity Teratoenicity Developmental effects Fertility effects Over-exposure sins/symptoms Inhalation Inestion Skin Eyes Taret orans 12. Not available. Once sensitized, a severe alleric reaction may occur when subsequently exposed to very low levels. No known sinificant effects or critical hazards. No known sinificant effects or critical hazards. No known sinificant effects or critical hazards. No known sinificant effects or critical hazards. No known sinificant effects or critical hazards. Adverse symptoms may include the followin wheezin and breathin difficulties asthma Ecoloical information Environmental effects Aquatic ecotoxicity Contains material which may cause damae to the followin orans blood, kidneys, luns, liver, astrointestinal tract, upper respiratory tract, skin, central nervous system (CNS), eye, lens or cornea. No known sinificant effects or critical hazards. Product/inredient name Test Result Species xylene 8.5 ppm Marine water Crustaceans - Daerblade rass shrimp - Palaemonetes puio - Adult 13500 to 19200 u/l Fresh water 13500 to 15034 u/l Fresh water 13500 to 16100 u/l Fresh water 13400 u/l Fresh water 13300 to 16114 u/l Fresh water 12000 to 13762 u/l Fresh water 12000 to 16114 u/l Fresh water Fish - Rainbow trout,donaldson trout - Oncorhynchus mykiss - 0.9 Fish - Blueill - macrochirus - 0.9 Fish - Blueill - Fish - Fathead minnow - Pimephales promelas - 31 days - 18.4 mm - 0.077 Fish - Blueill - Fish - Blueill - Fish - Blueill - Exposure 48 hours 8600 Fish - Blueill - Version 1 Pae 5/7
12. Ecoloical information to 9591 u/l Fresh water 8500 u/l Marine water 8200 to 10032 u/l Fresh water 3300 to 4093 u/l Fresh water macrochirus - 0.9 Crustaceans - Daerblade rass shrimp - Palaemonetes puio Fish - Rainbow trout,donaldson trout - Oncorhynchus mykiss - 0.6 Fish - Rainbow trout,donaldson trout - Oncorhynchus mykiss - 0.6 48 hours Other ecoloical information Bioderadability Other adverse effects 13. Methods of disposal 14. Not available. Not available. Disposal considerations Transport information No known sinificant effects or critical hazards. The eneration of waste should be avoided or minimised wherever possible. Empty containers or liners may retain some product residues. This material and its container must be disposed of in a safe way. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal leislation and any reional local authority requirements. Avoid dispersal of spilt material and runoff and contact with soil, waterways, drains and sewers. ADG Not reulated. ADG Class Label No. ADR Not reulated. IMDG Not reulated. Marine pollutant IATA Not reulated. - No. 15. Reulatory information Standard for the Uniform Schedulin of Drus and Poisons 7 Control of Scheduled Carcinoenic Substances Inredient name Schedule No listed substance Australia inventory (AICS) Australia inventory (AICS) At least one component is not listed. Version 1 Pae 6/7
15. Reulatory information EU Classification R42 16. Other information Person who prepared the MSDS Date of previous issue Disclaimer Validated by Hunter on 23.07.2010. No previous validation. Indicates information that has chaned from previously issued version. Material Safety Data Sheets are updated frequently. Please ensure that you have a current copy. MSDS may be obtained from the followin website www.sika.co.nz The information contained in this Safety Data Sheet corresponds to our level of knowlede at the time of publication. All warranties are excluded. Our most current General Sales Conditions shall apply. Please consult the product data sheet prior to any use and processin. Version 1 Pae 7/7