Safety Data Sheet Scorp EC 1) Identification of Substance: Product name: Active Ingredient(s): ACVM Approval: EPA Approval: Distributed by: Emergency Number: National Poisons and Hazchem Information Centre 2) Hazards Identification: Scorp EC 100g/L haloxyfop-p as the methyl ester P7846 HSR008025 Adria Crop Protection P.O. Box 535, Kumeu 0841, Auckland Ph: 09-412-9817 Fax: 09-412-9807 www.adria.nz 0800 734 607 (24hr)3 0800 POISON (0800 764 766) HSNO Classifications: 3.1D, 6.1E(O), 6.1E (I), 6.3B, 6.4A, 6.9B, 9.1B, 9.3C Signal Word: Warning Hazard Statement Codes: H227 H303 H333 H316 H319 H371/H373 H411 H433 Combustible Liquid. May be harmful if swallowed. May be harmful if inhaled. Causes mild skin irritation. Causes serious eye irritation May cause organ damage through prolonged and repeated exposure. Toxic to aquatic life with long lasting effects. Harmful to terrestrial vertebrates. Prevention Statement Codes: P102 Keep out of reach of children. Page 1 of 5
P103 P210 P280 P264 P260 P270 P273 Read label before use. Keep away from heat, sparks, flames, and hot surfaces. No smoking. Wear protective gloves, protective clothing/eye protection/face protection. Wash body thoroughly after handling. Do not breath mist, vapours or spray. Do not eat, drink, or smoke when using this product. Avoid release to the environment. Response Statement Codes: P101 P370 + P378 P312/ P309+P311/P314 P304 + P312 P332 + P313 P305 + P351 + P338 P337 + P313 P391 If medical advice is needed, have product container or label at hand. In case of fire: use foam, dry chemical, or carbon dioxide to extinguish fires. DO NOT use a direct jet of water. IF exposed or if you feel unwell: Call a POISON CENTRE or doctor/physician. If INHALED: Call a POISON CENTRE or doctor/physician if you feel unwell. If skin irritation occurs: Get medical advice/attention. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. Collect spillage. Storage Statement codes: P403 + P235 Store in a well ventilated-place. Keep cool. 3) Composition Details: Chemical identity: Haloxyfop-P Chemical identity of ingredients: Ingredient: CAS No.: Content (%w/v) Haloxyfop-P-methyl 72619-32-0 10 % Page 2 of 5
4) First Aid Measures: General Information: Skin contact: Eye contact: Ingestion: Inhalation: Further Information: 5) Fire-Fighting Measures: Specific hazards: Extinguishing media and methods: Recommended protective clothing: Hazchem Code: IF ON SKIN: Wash with plenty of soap and water. If skin irritation or rash occurs: Get medical advice/attention. Take off contaminated clothing and wash before re-use IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. If swallowed do NOT induce vomiting. For advice, contact the National Poisons Centre on 0800 POISON (0800 764766) or a doctor immediately. Assure fresh air breathing. Rest. If breathing is difficult, give oxygen. If not breathing, give artificial respiration. Seek medical advice. Treatment: Treat according to symptoms (decontamination, vital functions). No known specific antidote. High temperature may liberate toxic gases. Nitrogen oxides. Halogens. Carbon monoxide. Carbon dioxide. Dry chemical extinguisher, foam, carbon dioxide (do not use direct jet of water). Wear SCBA and chemical-protective clothing. 3Z 6) Accidental Release Measures: Personal precautions: Environmental precautions: Use protective clothing as per section 8). Avoid contact with skin, eyes and clothing. Remove contaminated clothes and shoes immediately. Do not discharge into drains/surface waters/groundwater. Do not discharge into the subsoil/soil. Spill procedures: Wear appropriate protective clothing, refer to Section 8). Prevent material from entering waterways. Absorb spills with inert material and place in waste containers. Wash area with water and absorb with further inert material Disposal procedures: 7) Handling & Storage: Handling: Storage: Triple rinse container and add residue to spray tank. Return empty container to an AgRecovery collection point for disposal. Dispose of waste safely, according to local Council regulations. Use protective clothing. Refer to section 8. Avoid contact with skin and eyes. Ensure adequate ventilation Keep away from heat, sparks, flames, and hot surfaces. No smoking. Protect from sunlight. Protect against freezing. Page 3 of 5
8) Exposure Control / Personal Protection: Engineering measures: Respiratory protection: Eye protection: Hand protection: Other protective equipment: General Safety & Hygiene measures: 9) Physical & Chemical Properties: Form: Liquid Colour: Amber Odour: Characteristic Melting point/boiling point: > 100 C Density: ± 1 030 g/l Surface tension: ph: 7 8 Flash point: > 75 C Ignition Temperature: Not determined Explosive Limits: Not determined Viscosity: 10) Stability & Reactivity: Conditions to avoid: Materials to avoid: Hazardous reactions: 11) Toxicological Information: Acute oral toxicity: Acute inhalation toxicity: Acute dermal toxicity: Skin irritation: Wear respiratory protection if ventilation is inadequate. Particle filter with medium efficiency for solid and liquid particles. Safety goggles with side-shields. Suitable chemical resistant safety gloves (e.g. nitrile rubber (.4mm)). Body protection (chemical protection suit, boots) must be chosen depending on activity and possible exposure. Keep away from food, drink and animal feedstuffs. No eating, drinking or smoking during use. Wash hands and face before breaks and after work. Stable under normal storage conditions Vapours are flammable LD50 > 2 000 mg/kg LD50 > 4 000 mg/l (4 hrs) LD50 > 2 000 mg/kg Causes mild skin irritation. Eye irritation: Causes serious eye irritation Sensitisation: Not expected to cause sensitisation under normal use 12) Ecological Information: Acute fish toxicity: LC50 Rainbow trout > 50 mg/l Toxicity for daphnia: EC50 (48 hr) > 100 mg/l Toxicity to algae: EC50 (48 hr) > 47.2 mg/l Page 4 of 5
13) Disposal Considerations: Disposal: Triple rinse container and add residue to spray tank. Return empty container to an AgRecovery collection point for disposal. Empty container precautions: Avoid contamination of any water supply with chemical or empty container. 14) Transportation Information: Rail/road (RID/ADR): Sea (IMDG code): Air (ICAO/IATA): 15) Regulatory Information: Approved handlers: Tracking: ACVM controls: 16) Other Information ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (Haloxyfop-P) Class 9 Packing group III UN: 3082 Hazchem Code: 3Z This product must be under the care of an approved handler during use. No See www.foodsafety.govt.nz for registration conditions. For proper and safe use of this product, please refer to the approval conditions laid down on the product label. The data contained in this safety data sheet is based on our current knowledge and describes the product only with regard to safety requirements. The data does not describe the product s properties. Neither should any agreed property nor the suitability of the product for any specific purpose be deduced from the data contained in the safety data sheet. It is the responsibility of the recipient of the product to ensure any existing laws and legislation are observed. Page 5 of 5