Material Safety Data Sheet 66 HEAVY DUTY ALKALINE BATHROOM 1. Trade name of product Product use Code Date of issue Product and company identification Product dilution information Supplier's information 2. Physical state Emergency overview 66 HEAVY DUTY ALKALINE BATHROOM disinfectant Up to 12 oz/gal or 94 ml/l in water Ecolab Co. 515 Tomken Road Mississauga ON L4W 2X5 1-8-352-5326 91798 8-November-212 EMERGENCY HEALTH INFORMATION 1-8-328-26 Outside United States and Canada CALL 1-651-222-5352 (in USA) Hazards identification Routes of entry Skin contact, Eye contact, Inhalation, Ingestion Potential acute health effects Eyes Severely irritating to eyes. Skin Irritating to skin. Inhalation HARMFUL IF INHALED. Irritating to respiratory system. Ingestion Liquid. WARNING! CAUSES RESPIRATORY TRACT, EYE AND SKIN IRRITATION. HARMFUL IF INHALED. Avoid contact with eyes, skin and clothing. Avoid breathing vapours, spray or mists. Keep container closed. Use only with adequate ventilation. Wash thoroughly after handling. See toxicological information (Section 11) 3. Composition/information on ingredients Liquid. CAUTION! MAY CAUSE EYE IRRITATION. Avoid contact with eyes. Wash thoroughly after handling. Moderately irritating to eyes. Slightly irritating to the skin. Name CAS number % by weight TETRASODIUM EDTA 64-2-8 1-3 poly(oxy-1,2-ethanediyl),.alpha.-undecyl-.omega.-hydroxy- 34398-1-1 1-5 BENZALKONIUM CHLORIDE 68424-85-1 1-5 TRISODIUM EDTA 15-38-9 1-5 ALCOHOL 64-17-5.1-1 1/6
3. Composition/information on ingredients 8 November 212 Name CAS number % by weight TETRASODIUM EDTA 64-2-8.5-1.5 4. Eye contact Skin contact Inhalation Ingestion 5. First-aid measures In case of contact, immediately flush eyes with cool running water. Remove contact lenses and continue flushing with plenty of water for at least 15 minutes. Get medical attention. In case of contact, immediately flush skin with plenty of water. Remove contaminated clothing and shoes. Get medical attention if irritation persists. Wash clothing before reuse. Clean shoes thoroughly before reuse. If inhaled, remove to fresh air. If exposed person is not breathing, give artificial respiration or oxygen applied by trained personnel. Get medical attention. Get medical attention if symptoms occur. Fire-fighting measures Auto-ignition temperature Flammable limits Hazardous thermal decomposition products Special remarks on fire hazards Special remarks on explosion hazards Fire-fighting media and instructions Special protective equipment for fire-fighters 6. Personal precautions Environmental precautions Methods for cleaning up In case of contact, immediately flush eyes with plenty of water. Remove contact lenses and flush again. Get medical attention if irritation persists. Rinse with water for a few minutes. No special measures required. Treat symptomatically. Get medical attention if symptoms occur. Decomposition products may include the following materials carbon dioxide carbon monoxide nitrogen oxides metal oxide/oxides Accidental release measures Use an extinguishing agent suitable for the surrounding fire. Dyke area of fire to prevent runoff. In a fire or if heated, a pressure increase will occur and the container may burst. Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode. Use personal protective equipment as required. Avoid contact of large amounts of spilt material and runoff with soil and surface waterways. Use a water rinse for final clean-up. Use personal protective equipment as required. Avoid contact of large amounts of spilt material and runoff with soil and surface waterways. Use a water rinse for final clean-up. 2/6
7. Handling Storage 8. Engineering measures Handling and storage Avoid contact with eyes, skin and clothing. Avoid breathing vapours, spray or mists. Keep container closed. Use only with adequate ventilation. Wash thoroughly after handling. Keep out of reach of children. Store in a closed container. Do not store above the following temperature 5 C Exposure controls/personal protection Personal protection Eyes Wear eye protection. Hands Skin Respiratory Use only with adequate ventilation. If user operations generate dust, fumes, gas, vapour or mist, use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits. For prolonged or repeated handling, use the following type of gloves Impervious gloves. No protective equipment is needed under normal use conditions. Wear appropriate respirator when ventilation is inadequate and occupational exposure limits are exceeded. 8 November 212 Avoid contact with eyes. Wash thoroughly after handling. Keep out of reach of children. Store in a closed container. Good general ventilation should be sufficient to control worker exposure to airborne contaminants. Eye protection should be used when splashing may occur. No protective equipment is needed under normal use conditions. No protective equipment is needed under normal use conditions. No special protection is required. Occupational exposure limits TWA (8 hours) STEL (15 mins) Ceiling Ingredient List name ppm mg/m³ Other ppm mg/m³ Other ppm mg/m³ Other Notations ethanol US ACGIH 2/21 - - - 1 - - - - - AB 4/29 1 188 - - - - - - - BC 9/21 - - - 1 - - - - - ON 7/21 - - - 1 - - - - - QC 6/28 1 188 - - - - - - - 9. Physical and chemical properties Physical state Liquid. Flash point > 1 C Colour Red Odour Floral ph Boiling/condensation point Melting/freezing point 9 to 11 [Conc. (% w/w) 1%] Relative density 1.12 Vapour pressure Vapour density Odour threshold Liquid. > 1 C Red [Light] Floral [Slight] 8.5 to 1.5 [Conc. (% w/w) 1%] 3/6
9. Physical and chemical properties Evaporation rate Viscosity Dispersibility properties 8 November 212 Solubility LogKow 1. Easily soluble in the following materials cold water and hot water. Stability and reactivity Stability Conditions of instability Reactivity Hazardous decomposition products The product is stable. Under normal conditions of storage and use, hazardous polymerisation will not occur. Under normal conditions of storage and use, hazardous decomposition products should not be produced. Hazardous polymerisation Under normal conditions of storage and use, hazardous polymerisation will not occur. 11. Toxicity data Toxicological information Potential acute health effects Eyes Severely irritating to eyes. Skin Inhalation Ingestion Irritating to skin. HARMFUL IF INHALED. Irritating to respiratory system. Potential chronic health effects Carcinogenic effects Mutagenic effects Teratogenic effects Reproductive effects Sensitization to Product Synergistic products (toxicologically) Moderately irritating to eyes. Slightly irritating to the skin. Product/ingredient name Test Route Result Species acetic acid, (ethylenedinitrilo)tetra-, LD5 Oral 17 mg/kg Rat tetrasodium salt acetic acid, (ethylenedinitrilo)tetra-, LD5 Oral 215 mg/kg Mouse trisodium salt LD5 Oral 215 mg/kg Rat quaternary ammonium compounds, benzylc12-c16-alkyldimethyl, LD5 Dermal 334 mg/kg Rabbit chlorides LD5 Oral 344 mg/kg Rat poly(oxy-1,2-ethanediyl),.alpha.-undecyl- LD5 Dermal >2 mg/kg Rabbit.omega.-hydroxy- LD5 Oral 17 mg/kg Rat ethanol LD5 Dermal 158 mg/kg Rabbit 4/6
11. Toxicological information Other adverse effects Target organs 12. Ecological information Ecotoxicity 13. Waste disposal 14. Not reported Disposal considerations LD5 Oral 147 mg/kg Rat LC5 Inhalation 117 mg/l Rat Avoid disposal. Attempt to use product completely in accordance with intended use. Disposal should be in accordance with applicable regional, national and local laws and regulations. Transport information 8 November 212 Diluted product can be flushed to sanitary sewer. Discard empty container in trash. Certain shipping modes or package sizes may have exceptions from the transport regulations. The classification provided may not reflect those exceptions and may not apply to all shipping modes or package sizes. TDG TDG Classification IMO/IMDG IMO/IMDG Classification Not regulated. Not regulated. For transport in bulk, see shipping documents for specific transportation information. Not intended for transport. 15. WHMIS Regulatory information Not a WHMIS controlled material. DIN 2274973 Not controlled under WHMIS. DIN 2274973 Canada inventory All components are listed or exempted. This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations and the MSDS contains all the information required by the Controlled Products Regulations. 16. Other information Hazardous Material Information System (U.S.A.) Health * 2 Health * 1 Physical hazards Physical hazards 5/6
16. Other information 8 November 212 National Fire Protection Association (U.S.A.) Health 2 Instability/Reactivity Health 1 Instability/Reactivity Special Special Date of issue Responsible name 8-November-212 Regulatory Affairs 1-8-352-5326 Indicates information that has changed from previously issued version. Notice to reader The above information is believed to be correct with respect to the formula used to manufacture the product in the country of origin. As data, standards, and regulations change, and conditions of use and handling are beyond our control, NO WARRANTY, EXPRESS OR IMPLIED, IS MADE AS TO THE COMPLETENESS OR CONTINUING ACCURACY OF THIS INFORMATION. 6/6