Guidance on risks and precautions to be considered for bulk liquid loading and unloading operations in road transport

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Guidance on risks and precautions to be considered for bulk liquid loading and unloading operations in road transport ISSUE 1 NOVEMBER 2009

2 Guidance on risks and precautions to be considered for bulk liquid loading and unloading operations in road transport

TABLE OF CONTENTS TABLE OF CONTENTS Introduction 4 Objective and Scope 4 1. Different types of loading and unloading schemes 5 1.1. Loading schemes 1.2. Unloading schemes 2. Recommended schemes for products with certain hazards 6 3. Operational risks associated with each scheme 7 4. Precautions 8 4.1. General precautions 4.2. precautions, specific for each scheme APPENDIX 1: Illustration of the different loading schemes 10 APPENDIX 2: Illustration of the different unloading schemes 14 Contacts 19 Cefic/ECTA Guidelines 3

INTRODUCTION / OBJECTIVE AND SCOPE INTRODUCTION Continuous efforts to enhance safety during transport of chemicals and the associated handlings are part of the overall aim to improve the safety performance of both the chemical industry and the transport industry. Analysis of accident statistics indicates that a substantial number of transport related incidents happen during loading and unloading operations. It is therefore essential that proper use is being made of appropriate equipment during these operations. This Guidance should be considered as complementing the Behaviour Based Safety (BBS) Guidelines for the safe loading and unloading of road freight vehicles, issued by Cefic and ECTA in March 2007 (2nd issue), which concentrate on clarifying the roles and responsibilities of the different parties involved. Reference is also made to guidelines for specific products such as styrene, chlorinated solvents, etc, which can be found on http://www.cefic.be/en/ transport-and-logistics-guidelines-on-transport-of-specific-chemicals.html. This Guidance is of a voluntary nature and individual companies may decide to apply the Guidance in full or partly in accordance with their own judgment and taking into account the specific circumstances and requirements. Applicable national and international regulations, in particular Chapters 4.2 and 4.3 of ADR should always be complied with as they take precedence over the recommendations made in the present Guidance. OBJECTIVE AND SCOPE The objective of the present Guidance is to provide recommendations on the risks and precautions to be considered during the loading and unloading of chemicals, whereby particular attention is given to different loading and unloading schemes that may require specific precautions. The present Guidance is therefore providing illustrations of these different loading/unloading schemes and identifies the product related hazards and operational risks associated with these schemes. It also provides recommendations on general precautions as well as on precautions, specific to certain schemes, to be taken during loading and unloading operations. This Guidance should help in selecting an appropriate loading/unloading scheme and in taking the necessary safety precautions. It offers both general and more scheme-specific advice, which can be used in training sessions etc. The scope of this Guidance is limited to equipment used for the loading and unloading of bulk liquids in tank transport operations. This Guidance does however not aim to provide an exhaustive overview of all existing transport equipment or loading/unloading schemes and of all possible risks and precautions that may need to be considered. 4 Guidance on risks and precautions to be considered for bulk liquid loading and unloading operations in road transport

LOADING/UNLOADING SCHEMES 1 DIFFERENT TYPES OF LOADING AND UNLOADING SCHEMES 1.1 Loading Schemes The following loading schemes are being considered in this Guidance (see also illustrations in APPENDIX 1: L1 Top loading through open manhole L2 Top loading through dome with cone and with vapour recovery L3 Top loading with dip tube and with vapour recovery L4 Top loading with dip tube and with inert gas blanketing L5 Bottom loading with open manhole L6 Bottom loading with closed manhole and with vapour recovery L7 Bottom loading with closed manhole and with blanketing 1.2 Unloading Schemes The following unloading schemes are being considered in this Guidance (see also illustrations in APPENDIX 2: U1 Bottom unloading by pump with open manhole U2 Bottom unloading by gravity with open manhole U3 Bottom unloading by compressed air or inert gas U4 Bottom unloading by pump with closed manhole and with intake of air U5 Bottom unloading by gravity with closed manhole and with vapour return U6 Bottom unloading by pump with closed manhole and with vapour return U7 Bottom unloading by pump with closed manhole and with inert gas U8 Top unloading by pump with closed manhole and with vapour return CEFIC/ECTA GUIDELINES 5

Recommended schemes 2 RECOMMENDED SCHEMES FOR PRODUCTS WITH CERTAIN HAZARDS A number of hazard categories of products are listed in the first column of Table 1. For each of these categories the Table indicates the recommended loading/unloading schemes. If a product exhibits more than one hazard a loading/unloading scheme should be selected that is recommended for each hazard. Table 1 Product hazards Smelly or toxic by inhalation products Loading/unloading scheme L1 L2 L3 L4 L5 L6 L7 U1 U2 U3 U4 U5 U6 U7 U8 Hot or corrosive products Products with low flashpoint (<23 C) or with flashpoint lower than the loading temperature Products for which an extended release of 1 vapour creates an hazard Products for which a short release of vapour (when opening manlid) creates an hazard (1) only unloading with inert gas, not with air 6 Guidance on risks and precautions to be considered for bulk liquid loading and unloading operations in road transport

Operational risks 3 OPERATIONAL RISKS ASSOCIATED WITH EACH LOADING AND UNLOADING SCHEME The main risks that may occur during loading/unloading operations are listed in the first column of Table 2. For each loading/unloading scheme the risks that require particular attention have been marked with an. Table 2 Operational risks Loading/unloading scheme L1 L2 L3 L4 L5 L6 L7 u1 U2 U3 U4 U5 U6 U7 U8 Overpressure tank Overpressure hoses Underpressure (tank collapse) Product residue (previous load) Overfilling 1 1 1 1 1 Leaks through open bottom valve Leaks through manlid Leaking hose Load repartition (multi-compartment tank) Run-away of loading arm/hose Dropping object in manhole Distance tank to truck (avoid using long hoses) Leaks through connections below liquid level Residues of inert gas, left after discharge, which may suffocate (N 2 ) 1 extra attention should be given CEFIC/ECTA GUIDELINES 7

PRECAUTIONS 4 PRECAUTIONS Two different types of precautions should be taken during loading and unloading operations: General precautions that apply to all loading and unloading schemes e.g. use hoses compatible with the product Specific precautions that apply only for a number of loading or unloading schemes e.g. use of dry couplings 4.1 General precautions Table 3 provides a non-exhaustive list of general precautions that apply to all loading and unloading schemes. Reference is made to ADR and the Cefic/ECTA Guidelines for the Safe Loading and Unloading of Road Freight Vehicles, where appropriate. Table 3 General precautions Comments Ensure compatibility of tank and none equipment with product Empty hoses after operation none Prevent unintentional movements of vehicles See BBS Loading/Unloading 1.2.2.3 see ADR (2009) 8.3.7 Only open valves after see BBS Loading/Unloading 1.2.2.14 Ensure safe conditions for access to top use should be made of either the safety gantry of of tank and for working at height the site, or of a safety handrail or of a safety harness, or top valves should be operated remotely Take preventive measures to avoid see ADR (2009) 8.5 S2 (3) for provisions on static electricity earthing and CENELEC Technical report clc/tr 50404 Electrostatics - Code of practice for the avoidance of hazards due to static electricity Ensure tightness of all valves and dome covers The proper closure of valves should be controlled visually Use liquids lines with appropriate diameter (DN 80) Recommended equipment specification Ensure correct connection of couplings see BBS Loading/Unloading 1.2.2.12 e.g. bolts in all holes Use hoses tested for pressure applied see BBS Loading/Unloading 1.2.2.12 Use hoses compatible with product see BBS Loading/Unloading 1.2.2.12 Check tank capacity to avoid overfilling see BBS Loading/Unloading 1.2.2.9 Check correct line-up of valves before see BBS Loading/Unloading 1.2.2.12 starting loading/unloading 8 Guidance on risks and precautions to be considered for bulk liquid loading and unloading operations in road transport

PRECAUTIONS 4.2 Precautions, specific for each scheme Table 4 lists a number of precautions that should be taken and indicates to which schemes they are applicable. Table 4 Specific precautions L1 L2 L3 L4 L5 L6 L7 u1 U2 U3 U4 U5 U6 U7 U8 Carry out pre-loading test on tightness (1) Use vapour lines with appropriate diameter (DN 50) (2) Use compressed air or N 2 lines with appropriate diameter (DN 25) (2) (3) Use personal respiratory protection device Safety devices, if present, not to be used for coping with pressure variations during loading/unloading operations (only fit for coping with temperature variations during transport) Bottom valve to be opened as last operation for products with high melting point Ensure that maximum vapour/air/ N2 pressure does not exceed working pressure of tank Release pressure after discharge or loading Use dry couplings (4) Notes (1) Tank pressure test and/or valve vacuum test (avoiding test conditions however that may render the valve defective) are recommended (particularly important for smelly products) (2) Recommended equipment specification in order to avoid a vacuum situation in the storage tank/vehicle configuration with the use of closed circuits (3) Only N 2 should be used with products having a flashpoint below 60 C (4) Recommended for product-dedicated vehicles (particularly important for smelly products) CEFIC/ECTA GUIDELINES 9

APPENDIX 1 APPENDIX 1 ILLUSTRATION OF THE DIFFERENT LOADING SCHEMES (cross section) Vapour Loading Scheme L1 Top loading through open manhole 10 Guidance on risks and precautions to be considered for bulk liquid loading and unloading operations in road transport

APPENDIX 1 Vapour Loading Scheme L2 Top loading through dome with cone and with vapour recovery Vapour Loading Scheme L3 Top loading with dip tube and with vapour recovery CEFIC/ECTA GUIDELINES 11

APPENDIX 1 Inert gas (N ) 2 Loading Scheme L4 Top loading with dip tube and with inert gas blanketing Vapour Loading Scheme L5 Bottom loading with open manhole 12 Guidance on risks and precautions to be considered for bulk liquid loading and unloading operations in road transport

APPENDIX 1 Vapour Loading Scheme L6 Bottom loading with closed manhole and with vapour recovery Inert gas (N ) 2 Loading Scheme L7 Bottom loading with closed manhole and with blanketing CEFIC/ECTA GUIDELINES 13

APPENDIX 2 APPENDIX 2 ILLUSTRATION OF THE DIFFERENT UNLOADING SCHEMES (cross section) Vapour Air P Unloading Scheme U1 Bottom unloading by pump with open manhole 14 Guidance on risks and precautions to be considered for bulk liquid loading and unloading operations in road transport

APPENDIX 2 Vapour Air Unloading Scheme U2 Bottom unloading by gravity with open manhole Air / IG (N ) 2 Unloading Scheme U3 Bottom unloading by compressed air or inert gas CEFIC/ECTA GUIDELINES 15

APPENDIX 2 Air Unloading Scheme U4 Bottom unloading by pump with closed manhole and with intake of air P Vapour Unloading Scheme U5 Bottom unloading by gravity with closed manhole and with vapour return 16 Guidance on risks and precautions to be considered for bulk liquid loading and unloading operations in road transport

APPENDIX 2 Vapour P Unloading Scheme U6 Bottom unloading by pump with closed manhole and with vapour return Inert gas P Unloading Scheme U7 Bottom unloading by pump with closed manhole and with inert gas CEFIC/ECTA GUIDELINES 17

APPENDIX 2 P Vapour Unloading Scheme U8 Top unloading by pump with closed manhole and with vapour return 18 Guidance on risks and precautions to be considered for bulk liquid loading and unloading operations in road transport

CONTACTS Contacts The following persons participated in the development of these Guidelines: Andrew Baird (Suttons) andrew_baird@suttons-group.co.uk Harald Blaise (Arkema) harald.blaise@arkemagroup.com Roger Gloor (Bertschi) roger.gloor@bertschi.com Bertrand Gyselynck (Total) bertrand.gyselynck@total.com Filip Jonckheere (Cefic) fjo@cefic.be Alain Loots (Den Hartogh) aloots@denhartogh.com Carlo Meregaglia (Mapei) c.meregaglia@mapei.it Murad Orhan (BASF) murad.orhan@basf.com Rose-Marie Pype (ECTA) rose-marie.pype@epca.be Luc Renier (Dow) lrenier@dow.com Thomas Thodt (Evonik) thomas.thodt@evonik.com Paul Wauters (Wauters Tanktransport) paul.wauters@wauterstt.be Graham Wood (ITCO) grahamwood95@btinternet.com DISCLAIMER This document is intended for information only and sets out recommendations on risks and precautions to be considered during the loading and unloading of bulk chemicals of tanks and tankcontainers. The information contained in this Guidance is provided in good faith and, while it is accurate as far as the authors are aware, no representations or warranties are made about its completeness. It is not intended to be a comprehensive guide to all detailed aspects of this issue. No responsibility will be assumed by the participating associations, Cefic and ECTA, in relation to the information contained in this Guidance. Cefic/ECTA Guidelines 19

CEFIC AISBL - EUROPEAN CHEMICAL INDUSTRY COUNCIL Avenue E. van Nieuwenhuyselaan 4 1160 Brussels - Belgium T +32 2 676 72 11 F +32 2 676 73 00 www.cefic.org EUROPEAN CHEMICAL TRANSPORT ASSOCIATION - AISBL Avenue de Tervurenlaan 270 1150 Brussels - Belgium T +32 2 741 86 67 F +32 2 741 86 82 www.ecta.be