SAFETY DATA SHEET BANNISH II Section 1. Chemical product and company identification Product name Recommended use and restrictions BANNISH II Laundry product Use only for the purpose on the product label. Product dilution information Not applicable Supplier's information Code Date of issue Section 2. Hazards identification GHS Classification GHS label elements Ecolab Inc.Textile Care Division 37 N. Wabasha Street St. Paul, MN 5512 1-8-553-8683 913986 13 Dec 213 EMERGENCY HEALTH INFORMATION 1-8-328-26 Outside United States and Canada CALL 1-651-222-5352 (in USA) SKIN CORROSION/IRRITATION - Category 2 SERIOUS EYE DAMAGE/ EYE IRRITATION - Category 2A Signal word Symbol Warning Hazard statements Causes serious eye irritation. Causes skin irritation. Precautionary statements Prevention Response Storage Disposal Other hazards Wear protective gloves. Wear eye or face protection. Wash hands thoroughly after handling. IF ON SKIN Wash with plenty of soap and water. Take off contaminated clothing. Wash contaminated clothing before reuse. If skin irritation occurs Get medical attention. IF IN EYES Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists Get medical attention. No other specific measures identified. See section 13 for waste disposal information. None known. Page 1/6
Section 3. Composition/information on ingredients Substance/mixture Mixture Hazardous ingredients Concentration Range (%) CAS number SODIUM THIOSULFATE 2-5 7772-98-7 Hazardous ingredients Concentration Range (%) CAS number Section 4. First aid measures Eye contact Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Get medical attention if irritation persists. Skin contact Take off contaminated clothing. Wash with plenty of soap and water. Get medical attention if irritation persists. Wash clothing before reuse. Clean shoes thoroughly before reuse. Inhalation No special measures required. Treat symptomatically. Ingestion Get medical attention if symptoms occur. Protection of firstaiders Notes to physician See toxicological information (section 11) Suitable fire extinguishing media Specific hazards arising from the chemical Hazardous thermal decomposition products Special protective equipment for fire-fighters No action shall be taken involving any personal risk or without suitable training. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Treat symptomatically. Contact poison treatment specialist immediately if large quantities have been ingested or inhaled. Section 5. Fire-fighting measures Specific fire-fighting methods Use water spray, fog or foam. In a fire or if heated, a pressure increase will occur and the container may burst. Decomposition products may include the following materials sulfur oxides metal oxide/oxides Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode. Page 2/6
Section 6. Accidental release measures Personal precautions Environmental precautions Methods for cleaning up Handling Storage Use personal protective equipment as required. Avoid contact of large amounts of spilled material and runoff with soil and surface waterways. Use a water rinse for final clean-up. Section 7. Handling and storage Control parameters Appropriate engineering controls Avoid contact with eyes, skin and clothing. Wash thoroughly after handling. Keep out of reach of children. Keep container tightly closed. Personal protection Eye protection Wear eye protection. Hand protection Skin protection Respiratory protection Hygiene measures Store between the following temperatures and 5 C Section 8. Exposure controls/personal protection Ingredient name None. Physical state Color Melting point Good general ventilation should be sufficient to control worker exposure to airborne contaminants. Use chemical-resistant, impervious gloves. No protective equipment is needed under normal use conditions. A respirator is not needed under normal and intended conditions of product use. Exposure limits Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period. Appropriate techniques should be used to remove potentially contaminated clothing. Wash contaminated clothing before reusing. Section 9. Physical and chemical properties Liquid. Colorless Odor ph Odorless 8.2 to 1.2 (1%) Flash point > 1 C Product does not support combustion. Explosion limits Flammability (solid, gas) Page 3/6
Section 9. Physical and chemical properties Boiling point Evaporation rate (butyl acetate = 1) Vapor pressure Vapor density Relative density Solubility Partition coefficient n-octanol/water Auto-ignition temperature Decomposition temperature Odor threshold Viscosity >1 C (>212 F) Stability Possibility of hazardous reactions Hazardous decomposition products 1.229 to 1.279 (Water = 1) Easily soluble in the following materials cold water and hot water. Dynamic (room temperature) 15 mpa s (15 cp) Kinematic (room temperature).1198326 cm 2 /s (11.98326 cst) Section 1. Stability and reactivity Conditions to avoid No specific data. Materials to avoid Route of exposure Ingestion Acute toxicity Eye contact Skin contact Inhalation Ingestion Toxicity data Product/ingredient name Section 11. Toxicological information Inhalation The product is stable. Under normal conditions of storage and use, hazardous reactions will not occur. Under normal conditions of storage and use, hazardous decomposition products should not be produced. Skin contact, Eye contact, Inhalation, Ingestion Symptoms Eye contact Adverse symptoms may include the following pain or irritation watering redness Skin contact Adverse symptoms may include the following irritation redness No specific data. No specific data. Causes serious eye irritation. Causes skin irritation. Page 4/6
Section 11. Toxicological information sodium thiosulfate Chronic toxicity Carcinogenicity Mutagenicity Teratogenicity Developmental effects Fertility effects Other adverse effects LC5 Inhalation Rat 5.5 mg/l Vapor LD5 Dermal Rabbit >2 mg/kg LD5 Oral Rat >5 mg/kg Section 12. Ecological information Ecotoxicity Aquatic and terrestrial toxicity Product/ingredient name Result Species Exposure sodium thiosulfate Acute LC5 24 mg/l Fish 96 hours Disposal methods Section 13. Disposal considerations Diluted product can be flushed to sanitary sewer. Discard empty container in trash. Section 14. Transport information Certain shipping modes or package sizes may have exceptions from the transport regulations. The classification provided may not reflect those exceptions and may not apply to all shipping modes or package sizes. DOT DOT Classification IMO/IMDG IMO/IMDG Classification Not intended for transport. Not regulated. Not regulated. For transport in bulk, see shipping documents for specific transportation information. Section 15. Regulatory information U.S. Federal regulations TSCA 8(b) inventory All components are listed or exempted. SARA 32/34/311/312 extremely hazardous substances No listed substance SARA 32/34 emergency planning and notification No listed substance SARA 313 Product name CAS number Concentration Form R - Reporting requirements No listed substance Page 5/6
Section 15. Regulatory information California Prop. 65 No listed substance Section 16. Other information Hazardous Material Information System (U.S.A.) Health Flammability Physical hazards * 2 National Fire Protection Association (U.S.A.) Flammability Health 2 Instability/Reactivity Special Date of issue Prepared by 13 Dec 213 Regulatory Affairs 1-8-352-5326 Notice to reader The above information is believed to be correct with respect to the formula used to manufacture the product in the country of origin. As data, standards, and regulations change, and conditions of use and handling are beyond our control, NO WARRANTY, EXPRESS OR IMPLIED, IS MADE AS TO THE COMPLETENESS OR CONTINUING ACCURACY OF THIS INFORMATION. Page 6/6