Date of issue:24/03/2017 Revision date: : Version: 1.0 SECTION 1: Identification : Product identifier and chemical identity Product name : ISOPON BPO FOR CARTRIDGE (BPOBFC-R-AU) Other means of identification : P38/CART Company identification : U-POL AUSTRALIA PTY LIMITED Unit A, 16-20 Cassola Place Penrith, NSW 2750 - Australia T 02 4731 2655 - F 02 4731 2611 technical.depatment@u-pol.com - www.u-pol.com.au Emergency telephone number : + (61) - 290372994 SECTION 2: Hazards identification 2.1. Classification of the hazardous chemical Classification (GHS-AU) Skin Sens. 1 H317 Aquatic Acute 1 H400 Aquatic Chronic 3 H412 2.2. Label elements Hazard pictograms (GHS-AU) : Signal word (GHS-AU) Contains Hazard statements (GHS-AU) Precautionary statements (GHS-AU) Exclamation mark : Warning Environment : dibenzoyl peroxide, benzoyl peroxide : H317 - May cause an allergic skin reaction H400 - Very toxic to aquatic life : P102 - Keep out of reach of children P261 - Avoid breathing fume, vapours P280 - Wear eye protection, protective gloves, protective clothing P302+P352 - IF ON SKIN: Wash with plenty of soap and water P312 - Call a POISON CENTER or doctor/physician if you feel unwell P501 - Dispose of contents/container to hazardous or special waste collection point, in accordance with local, regional, national and/or international regulation 2.3. Other hazards SECTION 3: Composition/information on ingredients Name CAS No Compound type % dibenzoyl peroxide, benzoyl peroxide 94-36-0 5-23 SECTION 4: First aid measures 4.1. Description of first aid measures First-aid measures after inhalation First-aid measures after skin contact First-aid measures after eye contact First-aid measures after ingestion 4.2. Symptoms caused by exposure Symptoms/injuries after skin contact : Remove person to fresh air and keep comfortable for breathing. : Wash skin with plenty of water. Take off contaminated clothing. If skin irritation or rash occurs: Get medical advice/attention. : Rinse eyes with water as a precaution. : Call a poison center or a doctor if you feel unwell. : May cause an allergic skin reaction. 24/03/2017 EN (English) SDS ID: BPOBFC-R-AU 1/6
4.3. Indication of any immediate medical attention and special treatment needed Other medical advice or treatment : Treat symptomatically. SECTION 5: Fire-fighting measures 5.1. Extinguishing media Suitable extinguishing media : Water spray. Dry powder. Foam. Carbon dioxide. 5.2. Special hazards arising from the substance or mixture General measures : Remove ignition sources. 5.3. Special protective equipment and precautions for fire-fighters Protection during firefighting Hazchemcode : Do not attempt to take action without suitable protective equipment. Self-contained breathing apparatus. Complete protective clothing. : EZ SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures General measures : Remove ignition sources. 6.1.1. For non-emergency personnel Protective equipment Emergency procedures 6.1.2. For emergency responders Protective equipment : Safety glasses. Protective clothing. Gloves. : Ventilate spillage area. Avoid contact with skin and eyes. Avoid breathing fume, vapours. : Do not attempt to take action without suitable protective equipment. For further information refer to section 8: "Exposure controls/personal protection". 6.2. Environmental precautions Avoid release to the environment. 6.3. Methods and material for containment and cleaning up For containment Methods for cleaning up : Collect spillage. : Take up liquid spill into absorbent material. SECTION 7: Handling and storage, including how the chemical may be safely used 7.1. Precautions for safe handling Precautions for safe handling Hygiene measures 7.2. Conditions for safe storage, including any incompatibilities Storage conditions Storage temperature : < 25 C Storage area Special rules on packaging : Ensure good ventilation of the work station. Avoid contact with skin and eyes. Avoid breathing fume, vapours. Wear personal protective equipment. : Contaminated work clothing should not be allowed out of the workplace. Wash contaminated clothing before reuse. Do not eat, drink or smoke when using this product. Always wash hands after handling the product. : Store in a well-ventilated place. Keep cool. : Store in a well-ventilated place. : Keep only in original container. SECTION 8: Exposure controls/personal protection 8.1. Control parameters - exposure standards dibenzoyl peroxide, benzoyl peroxide (94-36-0) Australia Local name Benzoyl peroxide Australia TWA (mg/m³) 5 mg/m³ Exposure limit values for the other components 8.2. Monitoring 8.3. Appropriate engineering controls Appropriate engineering controls : Ensure good ventilation of the work station. 24/03/2017 EN (English) 2/6
8.4. Personal protective equipment Personal protective equipment Materials for protective clothing Hand protection Eye protection Skin and body protection Respiratory protection : Gloves. Protective clothing. Safety glasses. : Impermeable clothing : Protective gloves : Safety glasses : Wear suitable protective clothing : In case of insufficient ventilation, wear suitable respiratory equipment Environmental exposure controls : Avoid release to the environment. 9.1. SECTION 9: Physical and chemical properties Physical state : Liquid Appearance : Colour Odour Odour threshold ph Relative evaporation rate (butylacetate=1) Melting point / Freezing point Boiling point Flash point Auto-ignition temperature Flammability (solid, gas) Vapour pressure Relative density Density Solubility Log Pow Viscosity Explosive properties Explosive limits Minimum ignition energy : Beige. : Melting point : Not applicable : Density : 1.6-1.7 g/cm³ SADT : 50 C VOC content - Regulatory 10.1. SECTION 10: Stability and reactivity Reactivity Chemical stability Possibility of hazardous reactions : The product is non-reactive under normal conditions of use, storage and transport.the product is non-reactive under normal conditions of use, storage and transport : Stable under normal conditions. : No dangerous reactions known under normal conditions of use. Conditions to avoid : None under recommended storage and handling conditions (see section 7). Hazardous decomposition products 11.1. SECTION 11: Toxicological information Acute toxicity (oral) Acute toxicity (dermal) Acute toxicity (inhalation) : Under normal conditions of storage and use, hazardous decomposition products should not be produced. Skin corrosion/irritation Serious eye damage/irritation 24/03/2017 EN (English) 3/6
Respiratory or skin sensitisation Germ cell mutagenicity Carcinogenicity Reproductive toxicity STOT-single exposure STOT-repeated exposure Aspiration hazard ISOPON BPO FOR CARTRIDGE (BPOBFC-R-AU) Density SECTION 12: Ecological information : May cause an allergic skin reaction. 1.6-1.7 g/cm³ According to the National Code of Practice for the Preparation of Material s mandatory. Information relevant for GHS classification is available on request 12.1. Ecotoxicity Ecology - general Acute aquatic toxicity Chronic aquatic toxicity, Environmental classification information is not : Very toxic to aquatic life. Harmful to aquatic life with long lasting effects. : Very toxic to aquatic life. : Harmful to aquatic life with long lasting effects. 12.2. Persistence and degradability 12.3. Bioaccumulative potential 12.4. Mobility in soil 12.5. Other adverse effects Ozone Other adverse effects : ISOPON BPO FOR CARTRIDGE (BPOBFC-R-AU) Fluorinated greenhouse gases False dibenzoyl peroxide, benzoyl peroxide (94-36-0) Fluorinated greenhouse gases False SECTION 13: Disposal considerations Waste treatment methods : Dispose of contents/container in accordance with licensed collector s sorting instructions. SECTION 14: Transport information 14.1. UN number UN-No. (ADG) : 3082 UN-No. (IMDG) : 3082 UN-No. (IATA) : 3082 14.2. Proper Shipping Name - Addition Proper Shipping Name (ADG) : ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, Proper Shipping Name (IMDG) : ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. Proper Shipping Name (IATA) : Environmentally hazardous substance, liquid, n.o.s. 14.3. Transport hazard class(es) ADG Transport hazard class(es) (ADG) : 9 Danger labels (ADG) : 9 : IMDG 24/03/2017 EN (English) 4/6
Transport hazard class(es) (IMDG) : 9 Danger labels (IMDG) : 9 : IATA Transport hazard class(es) (IATA) : 9 Hazard labels (IATA) : 9 : 14.4. Packing group Packing group (ADG) Packing group (IMDG) Packing group (IATA) 14.5. Environmental hazards Marine pollutant Dangerous for the environment 14.6. Special precautions for user Specific storage requirement Shock sensitivity 14.7. Additional information Other information : III : III : III : Yes : Yes : No supplementary information available Transport by road and rail UN-No. (ADG) : 3082 Special provision (ADG) Limited quantities (ADG) Packing instructions (ADG) Special packing provisions (ADG) Portable tank and bulk container instructions (ADG) Portable tank and bulk container special provisions (ADG) Transport by sea : 274, 331, 335, AU01 : 5l : IBC03, P001, LP01 : PP1 : T4 : TP1, TP29 UN-No. (IMDG) : 3082 Special provisions (IMDG) : 274, 335, 969 Limited quantities (IMDG) : 5 L Excepted quantities (IMDG) : E1 Packing instructions (IMDG) : P001, LP01 Special packing provisions (IMDG) : PP1 IBC packing instructions (IMDG) : IBC03 Tank instructions (IMDG) : T4 Tank special provisions (IMDG) : TP2, TP29 EmS-No. (Fire) : F-A - FIRE SCHEDULE Alfa - GENERAL FIRE SCHEDULE EmS-No. (Spillage) : S-F - SPILLAGE SCHEDULE Foxtrot - WATER-SOLUBLE MARINE POLLUTANTS Stowage category (IMDG) : A Air transport 24/03/2017 EN (English) 5/6
UN-No. (IATA) : 3082 PCA Excepted quantities (IATA) PCA Limited quantities (IATA) PCA limited quantity max net quantity (IATA) : E1 : Y964 : 30kgG PCA packing instructions (IATA) : 964 PCA max net quantity (IATA) : 450L CAO packing instructions (IATA) : 964 CAO max net quantity (IATA) Special provisions (IATA) ERG code (IATA) 14.8. Hazchem or Emergency Action Code Hazchemcode SECTION 15: Regulatory information : 450L : A97, A158, A197 : 9L : EZ 15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture Listed on the AICS (Australian Inventory of Chemical Substances) Relevant Poisons Schedule number : Schedule 5 15.2. International agreements SECTION 16: Any other relevant information Classification: Skin Sens. 1 Aquatic Acute 1 Aquatic Chronic 3 : Listed on the AICS (Australian Inventory of Chemical Substances) H317 H400 H412 Full text of H-statements: Aquatic Acute 1 Hazardous to the aquatic environment Acute Hazard, Category 1 Aquatic Chronic 3 Hazardous to the aquatic environment Chronic Hazard, Category 3 Eye Irrit. 2 Serious eye damage/eye irritation, Category 2 Org. Perox. B Organic Peroxides, Type B Skin Sens. 1 Sensitisation Skin, Category 1 H241 H317 H319 H400 H412 Heating may cause a fire or explosion May cause an allergic skin reaction Causes serious eye irritation Very toxic to aquatic life Harmful to aquatic life with long lasting effects SDS Australia U-POL For professional use only. The information contained within this (SDS) is believed to be correct as of the date issued however it is subject to change from time to time. It does not purport to be all inclusive or exhaustive and shall only be used as a guide. U-POL makes no warranties, expressed or implied, including but not limited to, any implied warranty of fitness for a given purpose or usage. It is the Buyers responsibility to ensure the suitability of the products for their own use and to check the information is up to date. U-POL cannot be held responsible for the suitability of use for any of its products, considering the wide range of factors such as application, substrates and handling methods. Since these conditions of use are outside of our control, the company shall not be held liable for any damage resulting from handling or from contact with the product detailed. Moreover, addition of reducers, hardeners or other additives over and above U-POL s recommendations for use, may substantially alter the composition and hazards of the product. U-POL data sheets are available via the U-POL website at WWW.U-POL.COM. 24/03/2017 EN (English) 6/6