Amdro Noxall Vegetation Killer Concentrate Safety Data Sheet Section 1: Identification Product identifier Product Name Amdro Noxall Vegetation Killer Concentrate Synonyms 100515657; EPA Reg. No.: 228-713-90098; UPC #: 8-13576-00668-6 Product Description Clear amber liquid. Relevant identified uses of the substance or mixture and uses advised against Recommended use Non selective herbicide. Restrictions on use Avoid contact with eyes and skin. Use in well ventilated area. KEEP OUT OF THE REACH OF CHILDREN. Details of the supplier of the safety data sheet Manufacturer Central Garden & Pet Company, Garden Division Emergency telephone number Manufacturer 1-800-265-0761 1000 Parkwood Circle, Suite 700 Atlanta, GA 30339 United States Manufacturer (Transportation) 1-800-424-9300 - CHEMTREC Manufacturer (Transportation) 1-703-527-3887 - CHEMTREC - Outside US Collect Calls Accepted Section 2: Hazard Identification United States (US) According to OSHA 29 CFR 1910.1200 HCS Classification of the substance or mixture Serious Eye Damage 1 - H318 Label elements DANGER Hazard statements Causes serious eye damage - H318 Precautionary statements Prevention Wear eye/face protection - P280 Response IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, Page 1 of 7
if present and easy to do. Continue rinsing. - P305+P351+P338 Immediately call a POISON CENTER or doctor/physician. - P310 Other hazards Under United States Regulations (29 CFR 1910.1200 - Hazard Communication Standard), this product is considered hazardous. Section 3 - Composition/Information on Ingredients Substances Mixtures Material does not meet the criteria of a substance. Composition Chemical Name Identifiers % Glyphosate CAS:1071-83-6 5.03% Imazapyr CAS:81510-83-0 0.089% Isopropylamine 70% CAS:75-31-0 8.4% Other ingredients NDA 86.481% Section 4: First-Aid Measures Description of first aid measures Inhalation IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a physician if symptoms occur. Skin IF ON SKIN: Wash with plenty of soap and water. Eye IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CONTROL center or doctor. Ingestion IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. Most important symptoms and effects, both acute and delayed Causes serious eye damage. Refer to Section 11 - Toxicological Information. Indication of any immediate medical attention and special treatment needed Notes to Physician Treat symptomatically and supportively. Section 5: Fire-Fighting Measures Extinguishing media Suitable Extinguishing Media Use water, foam, carbon dioxide, or dry chemical. Unsuitable Extinguishing None known. Media Firefighting Procedures Do not breathe gas/fumes/vapor/spray. Do not use direct stream of water. A direct stream of water may spread fire. Page 2 of 7
Special hazards arising from the substance or mixture Unusual Fire and Explosion Hazards Hazardous Combustion Products Advice for firefighters No data available Hydrogen chloride, nitrogen oxides, carbon oxides. Wear positive pressure self-contained breathing apparatus (SCBA). Section 6 - Accidental Release Measures Personal precautions, protective equipment and emergency procedures Personal Precautions Ventilate enclosed areas. Avoid contact with skin, eyes, and clothing. Emergency Procedures Do not allow runoff into water, storm drains or drainage ditches. Ventilate closed spaces before entering. Environmental precautions Material is toxic to plants. Prevent material from entering public sewer systems or any waterways. Do not flush to drain. Large spills to soil or similar surfaces may necessitate removal of topsoil. The affected area should be removed and placed in an appropriate container for disposal. Methods and material for containment and cleaning up Containment/Clean-up Measures Section 7 - Handling and Storage Absorb spills with an inert material, clay granules or other inert absorbent material and put in container for disposal. Precautions for safe handling Handling Use good safety and industrial hygiene practices. Avoid contact with skin or eyes. Wash thoroughly with soap and water after handling. See product label for additional information. Handle and open container with care. Conditions for safe storage, including any incompatibilities Storage Store in cool, dry, secure place. Keep out of reach of children. Keep from freezing. Incompatible Materials or Ignition Sources Strong acids, strong bases, and oxidizing agents. Section 8 - Exposure Controls/Personal Protection Control parameters Exposure Limits/Guidelines No data available. Isopropylamine 70% (75-31-0) Exposure Limits/Guidelines Result ACGIH OSHA TWAs 5 ppm TWA 5 ppm TWA; 12 mg/m3 TWA STELs 10 ppm STEL Not established Exposure Limits Supplemental ACGIH Isopropylamine 70% (75-31-0): TLV Basis - Critical Effects: (eye damage; upper respiratory tract irritation) Exposure controls Engineering Use adequate ventilation to remove vapors (fumes, dust etc) Page 3 of 7
Measures/Controls Personal Protective Equipment Pictograms Respiratory In case of insufficient ventilation, wear suitable respiratory equipment. Eye/Face Wear chemical splash safety goggles. Hands Wear appropriate gloves. Skin/Body If prolonged exposure is anticipated, it is recommended for handlers to wear appropriate clothing to prevent skin contact. Environmental Exposure Refer to Section 13 - Disposal Considerations. Controls Section 9 - Physical and Chemical Properties Information on Physical and Chemical Properties Material Description Physical Form Liquid Appearance/Description Clear amber liquid. Color Clear amber. Odor Slight Odor Threshold No data available Physical and Chemical Properties No data available General Properties Boiling Point 212 F(100 C) Melting Point 32 F(0 C) Decomposition Temperature No data available ph 6.06 Specific Gravity/Relative Density 1.015 Water=1 Bulk Density 8.63 lbs/gal Water Solubility Volatility Soluble Viscosity 1.14 Centipoise (cps, cp) or mpas Vapor Pressure No data available Vapor Density No data available Evaporation Rate No data available VOC (Wt.) 0 VOC (Vol.) Flammability 0 Flash Point No data available UEL No data available LEL No data available Autoignition No data available Flammability (solid, gas) No data available Environmental Octanol/Water Partition coefficient No data available Section 10: Stability and Reactivity Reactivity Chemical stability Possibility of hazardous reactions Non-reactive under normal handling and storage conditions. Stable under normal temperatures and pressures. Hazardous polymerization will not occur. Page 4 of 7
Conditions to avoid Incompatible materials Hazardous decomposition products Avoid contact with metals such as mild steel and aluminum. Heat, strong acids, strong bases and oxidizing agents. Thermal decomposition may produce toxic gases which may include: hydrogen chloride, nitrogen oxides, carbon oxides. Section 11 - Toxicological Information Information on toxicological effects GHS Properties Acute toxicity Aspiration Hazard Carcinogenicity Germ Cell Mutagenicity Skin corrosion/irritation Skin sensitization STOT-RE STOT-SE Toxicity for Reproduction Respiratory sensitization Classification Acute Toxicity - Dermal - Classification criteria not met; Acute Toxicity - Inhalation - Classification criteria not met; Acute Toxicity - Oral - Classification criteria not met Serious eye damage/irritation Serious Eye Damage 1 Medical Conditions Aggravated by Exposure Potential Health Effects Inhalation Acute (Immediate) May cause irritation. Skin Acute (Immediate) May cause skin irritation. Eye Acute (Immediate) Causes serious eye damage. Ingestion Acute (Immediate) No data available Inhalation of product may aggravate existing chronic respiratory problems such as asthma, emphysema or bronchitis. Skin contact may aggravate existing skin disease. Page 5 of 7
Section 12 - Ecological Information Toxicity Persistence and degradability Bioaccumulative potential Mobility in Soil Other adverse effects No data available No data available. No data available. No data available. No studies have been found. Section 13 - Disposal Considerations Waste treatment methods Product waste Dispose of content and/or container in accordance with local, regional, national, and/or international regulations. NEVER place unused product down any indoor (including toilet) or outdoor (including sewer) drain. Packaging waste Dispose of content and/or container in accordance with local, regional, national, and/or international regulations. Section 14 - Transport Information UN number UN proper shipping name Transport hazard class (es) Packing group Environmental hazards DOT N/A Not regulated N/A N/A N/A IMO/IMDG N/A Not regulated N/A N/A N/A IATA/ICAO N/A Not regulated N/A N/A N/A Special precautions for user None specified. Transport in bulk according No data available to Annex II of MARPOL 73/78 and the IBC Code Other information IMO/IMDG No data available Key to abbreviations N/A = Not applicable. IATA/ICAO No data available Section 15 - Regulatory Information Safety, health and environmental regulations/legislation specific for the substance or mixture SARA Hazard Classifications Acute Page 6 of 7
FIFRA Pesticide Labeling This chemical is a pesticide product registered by the United States Environmental Protection Agency and is subject to certain labeling requirements under federal pesticide law. These requirements differ from the classification criteria and hazard information required for safety data sheets (SDS), and for workplace labels of nonpesticide chemicals. The hazard information required on the pesticide label is reproduced below. The pesticide label also includes other important information, including directions for use. CAUTION Precautionary Statements Hazards to Humans and Domestic Animals HAZARDS TO HUMANS AND DOMESTIC ANIMALS - CAUTION: Causes moderate eye irritation. Avoid contact with eyes or clothing. Wash thoroughly with soap and water after handling and before eating, drinking, chewing gum, using tobacco or using the toilet. People and pets may enter treated areas after spray has dried. First Aid IF IN EYES Hold eye open and rinse slowly and gently with water for 15-20 minutes. Remove contact lenses, if present, after the first 5 minutes, then continue rinsing eye. Call a poison control center or doctor for further treatment advice. Environmental Hazards Do not apply directly to any body of water. Do not contaminate water when disposing of equipment wash waters or rinsate. Inventory Component CAS TSCA Imazapyr 81510-83-0 No Glyphosate 1071-83-6 No Isopropylamine 70% 75-31-0 Yes Section 16 - Other Information Revision Summary Date MSDS No. Changes 23/December/2014 Last Revision Date 16/December/2014 Preparation Date 16/December/2014 Disclaimer/Statement of Liability Section 3 changed. Changes include Added: Isopropylamine (75-31-0) Section 11 changed. Changes include Added:Potential Health Effects/Eye - Acute The information and statements herein are believed to be reliable but are not to be construed as a warranty or representation for which we assume legal responsibility. Users should undertake sufficient verification and testing to determine the suitability for their own particular purpose of any information or products referred to herein. NO WARRANTY OF FITNESS FOR A PARTICULAR PURPOSE IS MADE. Page 7 of 7