SAFETY DATA SHEET. Creation Date 07-June-2010 Revision Date 19-January-2018 Revision Number Identification

Transcription

1 SAFETY DATA SHEET Creation Date 07-June-2010 Revision Number 3 Product Name Cat No. : 1. Identification Iron(II) acetate AC ; AC ; AC ; AC CAS-No Synonyms Ferrous acetate Recommended Use Uses advised against Laboratory chemicals. Not for food, drug, pesticide or biocidal product use Details of the supplier of the safety data sheet Company Importer/Distributor Fisher Scientific 112 Colonnade Road, Ottawa, ON K2E 7L6, Canada Tel: Acros Organics One Reagent Lane Fair Lawn, NJ Manufacturer Fisher Scientific One Reagent Lane Fair Lawn, NJ Tel: (201) Emergency Telephone Number For information US call: ACROS-01 / Europe call: Emergency Number US: / Europe: CHEMTREC Tel. No.US: / Europe: Classification WHMIS 2015 Classification 2. Hazard(s) identification Classified as hazardous under the Hazardous Products Regulations (SOR/ ) Skin Corrosion/irritation Category 2 Serious Eye Damage/Eye Irritation Category 2 Specific target organ toxicity (single exposure) Category 3 Target Organs - Respiratory system. Combustible Dusts Category 1 Label Elements Signal Word Warning Hazard Statements May form combustible dust concentrations in air Causes skin irritation Causes serious eye irritation May cause respiratory irritation Page 1 / 6

2 Precautionary Statements Prevention Keep container tightly closed Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking Avoid breathing dust/fume/gas/mist/vapors/spray Wash face, hands and any exposed skin thoroughly after handling Use only outdoors or in a well-ventilated area Wear protective gloves/protective clothing/eye protection/face protection Response In case of major fire and large quantities: Evacuate area. Fight fire remotely due to the risk of explosion IF ON SKIN: Wash with plenty of soap and water IF INHALED: Remove person to fresh air and keep comfortable for breathing IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing Call a POISON CENTER/ doctor if you feel unwell Take off contaminated clothing Storage Store in a well-ventilated place. Keep container tightly closed Store locked up Disposal Dispose of contents/container to an approved waste disposal plant 3. Composition/Information on Ingredients Component CAS-No Weight % Acetic acid, iron(2+) salt First-aid measures Eye Contact Skin Contact Inhalation Ingestion Most important symptoms/effects Notes to Physician Suitable Extinguishing Media Unsuitable Extinguishing Media Flash Point Method - Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Get medical attention. Wash off immediately with plenty of water for at least 15 minutes. Obtain medical attention. Move to fresh air. If not breathing, give artificial respiration. Obtain medical attention. Do not induce vomiting. Obtain medical attention.. Treat symptomatically 5. Fire-fighting measures Water spray. Carbon dioxide (CO 2). Dry chemical. Chemical foam. Page 2 / 6

3 Autoignition Temperature Explosion Limits Upper Lower Sensitivity to Mechanical Impact Sensitivity to Static Discharge Specific Hazards Arising from the Chemical Fine dust dispersed in air may ignite. Hazardous Combustion Products Carbon monoxide (CO) Carbon dioxide (CO2) Protective Equipment and Precautions for Firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. NFPA Health 2 Flammability 1 Instability 1 Physical hazards N/A Personal Precautions Environmental Precautions 6. Accidental release measures Ensure adequate ventilation. Use personal protective equipment as required. Avoid dust formation. Should not be released into the environment. Methods for Containment and Clean Sweep up or vacuum up spillage and collect in suitable container for disposal. Do not let Up this chemical enter the environment. Avoid dust formation. Handling Storage Exposure Guidelines 7. Handling and storage Ensure adequate ventilation. Wear personal protective equipment. Avoid contact with skin and eyes. Do not breathe dust. Do not ingest. Minimize dust generation and accumulation. Wash hands before breaks and immediately after handling the product. Keep in a dry, cool and well-ventilated place. Keep container tightly closed. Keep under nitrogen. 8. Exposure controls / personal protection Component Alberta British Ontario TWAEV Quebec ACGIH TLV OSHA PEL NIOSH IDLH Columbia Acetic acid, iron(2+) salt TWA: 1 mg/m 3 TWA: 1 mg/m 3 STEL: 2 mg/m 3 TWA: 1 mg/m 3 TWA: 1.0 mg/m 3 TWA: 1 mg/m 3 (Vacated) TWA: 1 mg/m 3 TWA: 1 mg/m 3 Legend ACGIH - American Conference of Governmental Industrial Hygienists OSHA - Occupational Safety and Health Administration NIOSH IDLH: The National Institute for Occupational Safety and Health Immediately Dangerous to Life or Health Engineering Measures Ensure adequate ventilation, especially in confined areas. Ensure that eyewash stations and safety showers are close to the workstation location. Wherever possible, engineering control measures such as the isolation or enclosure of the process, the introduction of process or equipment changes to minimise release or contact, and the use of properly designed ventilation systems, should be adopted to control hazardous materials at source Personal protective equipment Page 3 / 6

4 Eye Protection Hand Protection Goggles Protective gloves Glove material Breakthrough time Glove thickness Glove comments Nitrile rubber See manufacturers - Splash protection only recommendations Inspect gloves before use. observe the instructions regarding permeability and breakthrough time which are provided by the supplier of the gloves. (Refer to manufacturer/supplier for information) gloves are suitable for the task: Chemical compatability, Dexterity, Operational conditions, User susceptibility, e.g. sensitisation effects, also take into consideration the specific local conditions under which the product is used, such as the danger of cuts, abrasion. gloves with care avoiding skin contamination. Respiratory Protection No protective equipment is needed under normal use conditions. Recommended Filter type: Particulates filter conforming to EN 143 Environmental exposure controls. Hygiene Measures Handle in accordance with good industrial hygiene and safety practice. Keep away from food, drink and animal feeding stuffs. Do not eat, drink or smoke when using this product. Remove and wash contaminated clothing before re-use. Wash hands before breaks and at the end of workday. 9. Physical and chemical properties Physical State Powder Solid Appearance Light cream Odor Odor Threshold ph Melting Point/Range 190 C / 374 F Boiling Point/Range Flash Point Evaporation Rate Flammability (solid,gas) Flammability or explosive limits Upper Lower Vapor Pressure Vapor Density Specific Gravity Solubility Partition coefficient; n-octanol/water Autoignition Temperature Decomposition Temperature Viscosity Molecular Formula C4 H6 O4. Fe Molecular Weight Stability and reactivity Reactive Hazard Stability Conditions to Avoid None known, based on information available Stable under normal conditions. Moisture sensitive. Air sensitive. Exposure to air. Incompatible products. Exposure to moist air or water. Avoid dust formation. Page 4 / 6

5 Incompatible Materials Strong oxidizing agents Hazardous Decomposition Products Carbon monoxide (CO), Carbon dioxide (CO2) Hazardous Polymerization Hazardous Reactions Acute Toxicity Hazardous polymerization does not occur. None under normal processing. 11. Toxicological information Product Information No acute toxicity information is available for this product Component Information Toxicologically Synergistic Products Delayed and immediate effects as well as chronic effects from short and long-term exposure Irritation Sensitization Carcinogenicity Irritating to eyes, respiratory system and skin The table below indicates whether each agency has listed any ingredient as a carcinogen. Component CAS-No IARC NTP ACGIH OSHA Mexico Acetic acid, iron(2+) salt Not listed Not listed Not listed Not listed Not listed Mutagenic Effects Reproductive Effects Developmental Effects Teratogenicity STOT - single exposure STOT - repeated exposure Aspiration hazard Symptoms / effects,both acute and delayed Endocrine Disruptor Information Other Adverse Effects Ecotoxicity Do not empty into drains. Persistence and Degradability Bioaccumulation/ Accumulation Mobility Waste Disposal Methods... Respiratory system None known The toxicological properties have not been fully investigated. 12. Ecological information Disposal considerations Chemical waste generators must determine whether a discarded chemical is classified as a Page 5 / 6

6 hazardous waste. Chemical waste generators must also consult local, regional, and national hazardous waste regulations to ensure complete and accurate classification. DOT TDG IATA IMDG/IMO 14. Transport information 15. Regulatory information International Inventories Component DSL NDSL TSCA EINECS ELINCS NLP PICCS ENCS AICS IECSC KECL Acetic acid, iron(2+) salt - X X X - - X Canada SDS in compliance with provisions of information as set out in Canadian Standard - Part 4, Schedule 1 and 2 of the Hazardous Products Regulations (HPR) and meets the requirements of the HPR (Paragraph 13(1)(a) of the Hazardous Products Act (HPA)). Prepared By Creation Date Revision Date Print Date Revision Summary 16. Other information Regulatory Affairs Thermo Fisher Scientific EMSDS.RA@thermofisher.com 07-June January January-2018 This document has been updated to comply with the requirements of WHMIS 2015 to align with the Globally Harmonised System (GHS) for the Classification and Labelling of Chemicals. Disclaimer The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text End of SDS Page 6 / 6