SAFETY DATA SHEET. Creation Date 12-April-2010 Revision Date 23-April-2018 Revision Number Identification

Transcription

1 SAFETY DATA SHEET Creation Date 12-April-2010 Revision Number 4 Product Name Cat No. : 1. Identification 2-Chloro-2-methylpropane AC ; AC ; AC ; AC CAS-No Synonyms tert-butyl chloride Recommended Use Uses advised against Laboratory chemicals. Food, drug, pesticide or biocidal product use Details of the supplier of the safety data sheet Company Importer/Distributor Fisher Scientific 112 Colonnade Road, Ottawa, ON K2E 7L6, Canada Tel: Acros Organics One Reagent Lane Fair Lawn, NJ Manufacturer Fisher Scientific One Reagent Lane Fair Lawn, NJ Tel: (201) Emergency Telephone Number For information US call: ACROS-01 / Europe call: Emergency Number US: / Europe: CHEMTREC Tel. No.US: / Europe: Classification WHMIS 2015 Classification 2. Hazard(s) identification Classified as hazardous under the Hazardous Products Regulations (SOR/ ) Flammable liquids Category 2 Label Elements Signal Word Danger Hazard Statements Highly flammable liquid and vapor Page 1 / 6

2 Precautionary Statements Prevention Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking Keep container tightly closed Ground/bond container and receiving equipment Use explosion-proof electrical/ventilating/lighting/equipment Use only non-sparking tools Take precautionary measures against static discharges Wear protective gloves/protective clothing/eye protection/face protection Response IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/ shower In case of fire: Use dry sand, dry chemical or alcohol-resistant foam to extinguish Storage Store in a well-ventilated place. Keep cool Disposal Dispose of contents/container to an approved waste disposal plant 3. Composition/Information on Ingredients Component CAS-No Weight % tert-butyl chloride >95 4. First-aid measures General Advice Eye Contact Skin Contact Inhalation Ingestion Most important symptoms/effects Notes to Physician Suitable Extinguishing Media Unsuitable Extinguishing Media If symptoms persist, call a physician. Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Get medical attention. Wash off immediately with plenty of water for at least 15 minutes. If skin irritation persists, call a physician. Move to fresh air. If not breathing, give artificial respiration. Get medical attention if symptoms occur. Clean mouth with water and drink afterwards plenty of water. None reasonably foreseeable. Treat symptomatically 5. Fire-fighting measures Water spray. Carbon dioxide (CO 2). Dry chemical. Chemical foam. Cool closed containers exposed to fire with water spray. Flash Point -27 C / F Method - Autoignition Temperature 540 C / 1004 F Explosion Limits Upper 10.1% Lower 1.8% Sensitivity to Mechanical Impact Page 2 / 6

3 Sensitivity to Static Discharge Specific Hazards Arising from the Chemical Vapors may form explosive mixtures with air. Vapors may travel to source of ignition and flash back. Extremely flammable. Containers may explode when heated. Vapors may form explosive mixtures with air. Hazardous Combustion Products Hydrogen chloride gas Carbon monoxide (CO) Carbon dioxide (CO2) Protective Equipment and Precautions for Firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. NFPA Health 0 Flammability 3 Instability 0 Physical hazards N/A Personal Precautions Environmental Precautions 6. Accidental release measures Use personal protective equipment. Ensure adequate ventilation. Remove all sources of ignition. Take precautionary measures against static discharges. Should not be released into the environment. Methods for Containment and Clean Keep in suitable, closed containers for disposal. Soak up with inert absorbent material. Up Remove all sources of ignition. Use spark-proof tools and explosion-proof equipment. Handling Storage Exposure Guidelines 7. Handling and storage Wear personal protective equipment. Ensure adequate ventilation. Do not get in eyes, on skin, or on clothing. Avoid ingestion and inhalation. Keep away from open flames, hot surfaces and sources of ignition. Use only non-sparking tools. To avoid ignition of vapors by static electricity discharge, all metal parts of the equipment must be grounded. Take precautionary measures against static discharges. Keep away from heat and sources of ignition. Keep container tightly closed in a dry and well-ventilated place. 8. Exposure controls / personal protection This product does not contain any hazardous materials with occupational exposure limitsestablished by the region specific regulatory bodies. Engineering Measures Use explosion-proof electrical/ventilating/lighting/equipment. Ensure adequate ventilation, especially in confined areas. Wherever possible, engineering control measures such as the isolation or enclosure of the process, the introduction of process or equipment changes to minimise release or contact, and the use of properly designed ventilation systems, should be adopted to control hazardous materials at source Personal protective equipment Eye Protection Hand Protection Goggles Protective gloves Glove material Breakthrough time Glove thickness Glove comments Viton (R) See manufacturers - Splash protection only recommendations Inspect gloves before use. observe the instructions regarding permeability and breakthrough time which are provided by the supplier of the gloves. (Refer to manufacturer/supplier for information) gloves are suitable for the task: Chemical compatability, Dexterity, Operational conditions, User susceptibility, e.g. sensitisation effects, also take into consideration the specific local conditions under which the product is used, such as the danger of cuts, abrasion. gloves with care avoiding skin contamination. Page 3 / 6

4 Respiratory Protection When workers are facing concentrations above the exposure limit they must use appropriate certified respirators. Follow the OSHA respirator regulations found in 29 CFR or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced. To protect the wearer, respiratory protective equipment must be the correct fit and be used and maintained properly Recommended Filter type: low boiling organic solvent Type AX Brown conforming to EN371 When RPE is used a face piece Fit Test should be conducted Environmental exposure controls. Hygiene Measures Handle in accordance with good industrial hygiene and safety practice. Keep away from food, drink and animal feeding stuffs. Do not eat, drink or smoke when using this product. Remove and wash contaminated clothing before re-use. Wash hands before breaks and at the end of workday. 9. Physical and chemical properties Physical State Liquid Appearance Colorless Odor Slight Odor Threshold ph Melting Point/Range -25 C / -13 F Boiling Point/Range C / mmhg Flash Point -27 C / F Evaporation Rate Flammability (solid,gas) Not applicable Flammability or explosive limits Upper 10.1% Lower 1.8% Vapor Pressure C Vapor Density Specific Gravity Solubility Insoluble in water Partition coefficient; n-octanol/water No data available Autoignition Temperature 540 C / 1004 F Decomposition Temperature Viscosity C Molecular Formula C4 H9 Cl Molecular Weight Surface tension 54.3 C 10. Stability and reactivity Reactive Hazard Stability Conditions to Avoid Incompatible Materials None known, based on information available Stable under recommended storage conditions. Keep away from open flames, hot surfaces and sources of ignition. Incompatible products. Strong oxidizing agents Hazardous Decomposition Products Hydrogen chloride gas, Carbon monoxide (CO), Carbon dioxide (CO2) Hazardous Polymerization Hazardous Reactions Hazardous polymerization does not occur. None under normal processing. Page 4 / 6

5 Acute Toxicity 11. Toxicological information Product Information Component Information Component LD50 Oral LD50 Dermal LC50 Inhalation tert-butyl chloride 2900 mg/kg rat Not listed Not listed Toxicologically Synergistic Products Delayed and immediate effects as well as chronic effects from short and long-term exposure Irritation Sensitization Carcinogenicity The table below indicates whether each agency has listed any ingredient as a carcinogen. Component CAS-No IARC NTP ACGIH OSHA Mexico tert-butyl chloride Not listed Not listed Not listed Not listed Not listed Mutagenic Effects Reproductive Effects Developmental Effects Teratogenicity STOT - single exposure STOT - repeated exposure Aspiration hazard Symptoms / effects,both acute and delayed Endocrine Disruptor Information Other Adverse Effects Ecotoxicity Do not empty into drains..... None known None known The toxicological properties have not been fully investigated. 12. Ecological information Component Freshwater Algae Freshwater Fish Microtox Water Flea tert-butyl chloride EC50: 625 mg/l/24 h LC50: 350 mg/l/48 h (Leuciscus idus melanotus) Not listed Not listed Persistence and Degradability Persistence is unlikely based on information available. Bioaccumulation/ Accumulation Mobility. Will likely be mobile in the environment due to its volatility. Component log Pow tert-butyl chloride 2,45 Waste Disposal Methods 13. Disposal considerations Chemical waste generators must determine whether a discarded chemical is classified as a hazardous waste. Chemical waste generators must also consult local, regional, and Page 5 / 6

6 DOT TDG IATA IMDG/IMO national hazardous waste regulations to ensure complete and accurate classification. 14. Transport information 15. Regulatory information All of the components in the product are on the following Inventory lists: X = listed International Inventories Component DSL NDSL TSCA EINECS ELINCS NLP PICCS ENCS AICS IECSC KECL tert-butyl chloride X - X X X X X - Canada SDS in compliance with provisions of information as set out in Canadian Standard - Part 4, Schedule 1 and 2 of the Hazardous Products Regulations (HPR) and meets the requirements of the HPR (Paragraph 13(1)(a) of the Hazardous Products Act (HPA)). Prepared By Creation Date Revision Date Print Date Revision Summary 16. Other information Regulatory Affairs Thermo Fisher Scientific EMSDS.RA@thermofisher.com 12-April April April-2018 This document has been updated to comply with the requirements of WHMIS 2015 to align with the Globally Harmonised System (GHS) for the Classification and Labelling of Chemicals. Disclaimer The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text End of SDS Page 6 / 6