1. Identification of the substance/mixture and of the company/undertaking

Transcription

1 Safety Data Sheet according to 1907/2006/EC, Article 31, amended by Regulation (EU) No. 453/2010 LACTIC ACID (80% CONCENTRATION) Date: 21/11/ Identification of the substance/mixture and of the company/undertaking 1.1 Product Identifier Trade Name: Lactic Acid (80% Concentration) INCI: Lactic Acid, Aqua Synonyms Names: 2-hydroxy propionic acid. Reach Registration Number (According to EU Reg 1907/2006): FEMA No.: - FDA No.: - CoE No.: - CAS-No.: EC No.: EINECS No.: Relevant identified uses of the substance or mixture and uses advised against 1.3 Details of the supplier of the safety data sheet Aromantic Ltd 17 Tytler Street Forres Moray IV36 1EL Tel: Fax: info@aromantic.co.uk 1.4 Emergency telephone number Health and Safety Executive (HSE) Chemicals Regulation Directorate 5S.1 Redgrave Court, Merton Road, Bootle, Merseyside. L20 7HS Telephone: biocidesenquiries@hse.gsi.gov.uk REACH and CLP UK CA Help Desk, Health and Safety Executive 1

2 2.3 Redgrave Court, Merton Road, L20 7HS Bootle, Merseyside 2. Hazards Identification 2.1 Classification of the substance or mixture Classification (1999/45) Classification (1999/45): Xi: Irritant. R38: Irritating to skin. R41: Risk of serious damage to eyes. Classification (EC 1272/2008): Eye Dam. 1 H318 Skin Irrit. 2 H Label elements Label in accordance with (EC) No 1272/2008: 2.3 Other hazards Signal Word: Danger. Contains: No additional data. Hazard Statements: H318 Causes serious eye damage. H315 Causes skin irritation. Precautionary Statements: P280 Wear protective gloves/eye goggles/face protection. P321 Specific treatment (see instructions on this label). P IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P : If skin irritation occurs: Get medical advice/attention. P362: Take off contaminated clothing and wash before reuse. Supplementary Precautionary Statements: P264 Wash hands thoroughly after handling. P302+P352 IF ON SKIN: wash with plenty of soap and water. P310 Immediately call a POISON CENTER or doctor/physician. PBT or vpvb according to Annex XIII: No additional data. Adverse physio-chemical properties: No additional data. Adverse effects on human health: No additional data. 3. Composition/Information on ingredients 3.1 Substances L (+) Lactic Acid 80% CAS No.: EC No.: Classification (EC 1272/2008): Eye Dam. 1 H318, Skin Irrit. 2 H315 Classification (67/548/EEC or 1999/45/EC): Xi, R38, R Mixtures 2

3 4. First Aid Measures 4.1 Description of first aid measures General Information: Show this Safety Data Sheet to the doctor in attendance. Inhalation: Provide rest, warmth and fresh air. Get medical attention if any discomfort continues. Ingestion: Drink plenty of water. Do not induce vomiting. Get medical attention immediately. Skin Contact: Remove contaminated clothing immediately and wash skin with soap and water. Get medical attention if any discomfort continues. Eye Contact: Immediately flush with water for up to 15 minutes. Remove any contact lenses and open eyes wide apart. Get medical attention if any discomfort continues. 4.2 Most important symptoms and effects, both acute and delayed 4.3 Indication of any immediate medical attention and special treatment needed 5. Fire Fighting Measures 5.1 Extinguishing media Extinguishing Media: Water spray, foam, dry powder or carbon dioxide. 5.2 Special hazards arising from the substance or mixture Specific Hazards: When heated, vapours/gases hazardous to health may be formed. 5.3 Advice for firefighters Special Fire Fighting Procedures: In the event of fire, cool any endangered containers with water spray. Protective Measures in Fire: Fire fighters should wear self-contaminated breathing apparatus and full protective equipment. 6. Accidental Release Measures 6.1 Personal precautions, protective equipment and emergency procedures Risk of contact: Wear protective gloves and goggles/face shield. 6.2 Environmental precautions Avoid discharge to the aquatic environment. 6.3 Methods and material for containment and cleaning up Neutralise small amounts with sodium bicarbonate or lime and flush to sewer with large amounts of water. Absorb spillage with suitable absorbent material. 3

4 6.4 Reference to other sections 7. Handling and Storage 7.1 Precautions for safe handling Usage Precautions: Avoid temperatures above 200 C. 7.2 Conditions for safe storage, including any incompatibilities Storage Precautions: Use container made up of: stainless steel. Suitable plastic material. Store in tightly closed original container in a dry and cool place. 7.3 Specific end use(s) 8. Exposure Controls/Personal Protection 8.1 Control parameters 8.2 Exposure controls Protective Equipment: Engineering Measures: - Respiratory Equipment: If spraying then suitable breathing equipment may be needed. Hand Protection: Use suitable protective gloves if risk of skin contact. Eye Protection: Wear splash proof eye goggles to prevent any possibility of eye contact. Other Protection: - Hygiene Measures: Wash promptly with soap and water if skin becomes contaminated. When using do not eat, drink or smoke. Isolate contaminated clothing and wash before reuse. 9. Physical and Chemical Properties 9.1 Information on basic physical and chemical properties Appearance: Liquid. Colour: Colourless to pale yellow. Odour: Characteristic. Relative Density: kg/m 3. Flash Point ( C): >112. Refractive Index: No additional data. Melting Point ( C): No additional data. Boiling Point ( C): 120. Vapour Pressure: mm Hg 25. Solubility in C: No additional data. Auto-ignition temperature ( C): No additional data. 9.2 Other information 4

5 10. Stability and Reactivity 10.1 Reactivity 10.2 Chemical stability Stable under normal temperature conditions and recommended use Possibility of hazardous reactions 10.4 Conditions to avoid Avoid temperatures above 200 C Incompatible materials Strong oxidising substances Hazardous decomposition products Thermal decomposition or combustion may liberate carbon oxides and other toxic gases or vapours. 11. Toxicological Information 11.1 Information on toxicological effects Acute Toxicity: Oral LD mg/kg Rat Dermal LD mg/kg Rabbit (Literature Values) Skin corrosion / irritation: No additional data. Serious eye damage / irritation: No additional data. Respiratory or skin sensitisation: No additional data. Germ Cell Mutagenicity: Did not show mutagenetic effects in animal experiments. Carcinogenicity: No known carcinogenic effects. Reproductive toxicity: No additional data. STOT-single exposure: No additional data. STOT-repeated exposure: No additional data. Aspiration hazard: No additional data. Photo-toxicity: No additional data. Other Information: No additional data. 12. Ecological Information 12.1 Toxicity LC50 48 hours 320 mg/l EC 50, 48 Hrs, Daphnia, mg/l 240 IC 50, 72 Hrs, Algae, mg/l Persistence and degradability Readily biodegradable Bioaccumulative potential Will not bio-accumulate. Partition coefficient not known. 5

6 12.4 Mobility in soil No additional data Results of PBT and vpvb assessment This substance is not considered to be persistent, bioaccumulating and toxic (PBT). It is not considered to be very persistent and very bioaccumulating (vpvb) Other adverse effects Precautions: No additional data. 13. Disposal Considerations 13.1 Waste treatment methods Disposal Methods: Dispose of waste and residues in accordance with local authority requirements. 14. Transport Information Warning Icon: The product is not covered by international regulation on the transport of dangerous goods (IMDG, IATA, ADR/RID) UN number UN No. Road: Not applicable. UN No. SEA: Not applicable. UN No. AIR: Not applicable UN proper shipping name Not applicable Transport hazard class(es) ADR Class: Not applicable. IMDG Class: Not applicable. Air Class: Not applicable Packing group IMDG Pack Gr.: Not applicable. Air Pack Gr.: Not applicable Environmental hazards 14.6 Special precautions for user Hazard No (ADR): Not applicable. Hazchem Code: Not applicable. EMS: Not applicable Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code 15. Regulatory Information 15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture 6

7 EU Directives: Regulation (EC) No 1907/2006 of the European Parliament and of the council of 18 December 2006 concerning the Registration, Evaluation, Authorisation and Restriction of Chemicals (REACH), establishing a European Chemicals Agency, amending Directive 1999/45/EC and repeating Council Regulation (EEC) No 793/93 and Commissioning Regulation (EC) No 1488/94 as well as Council Directive 76/769/EEC and commission Directives 91/155/EEC. 93/67/EEC, 93/105/EC and 2000/21/EC, including amendments. Regulation (EC) No 1272/2008 of the European Parliament and of the Council of 16 December 2008 on classification, labelling and packaging of substances and mixtures, amending and repealing Directives 67/548/EEC and 1999/45/EC, and amending Regulation (EC) No 1907/2006 with amendments. Statutory Instruments: - Approved Code of Practice: - Guidance Notes: Chemical safety assessment 16. Other Information Risk Phrases in Full: R38 Irritating to skin. R41 Risk of serious damage to eyes. Hazard Statements in Full: H318 Causes Serious eye damage. H315 Causes skin irritation. Other Information: - This information is based on our present knowledge. However, this shall not constitute a guarantee for any specific product features and shall not establish a legally valid contractual relationship. The information contained in this SDS is accurate to the best of our knowledge and has been obtained from a variety of sources. No liability can be accepted arising out of the use, application or processing of this product. It is the users responsibility to determine the safe conditions for the use of this product. Revision Date: Version: 2 7