MATERIAL SAFETY DATA SHEET

Transcription

1 MATERIAL SAFETY DATA SHEET Print Date 27Jun2013 Revision date 27Jun2013 Revision Number 3 common name Product Code Trade name Product Class 1. PRODUCT AND COMPANY IDENTIFICATION SERIES 350 PART A G350CLEARA TANK ARMOR CLEAR BASE EPOXY RESIN Manufacturer Emergency Telephone TNEMEC Company, Inc. 123 West 23rd Avenue North Kansas City, MO (INFOTRAC) TNEMEC REGULATORY DEPT: Hazards Identification EMERGENCY OVERVIEW WARNING Irritating to eyes Irritating to skin Irritating to respiratory system MAY CAUSE ALLERGIC SKIN REACTION; EFFECTS MAY BE PERMANENT. Potential Health Effects Principle Routes of Exposure ACUTE EFFECTS EYES skin inhalation INGESTION inhalation, Skin Contact, Eye Contact. Irritating to eyes. Irritating to skin. May cause sensitization by skin contact. Irritating to respiratory system. Irritating to mucous membranes. MAY BE HARMFUL IF SWALLOWED. Chronic Effects Avoid repeated exposure Repeated contact may cause allergic reactions in very susceptible persons See Section 11 for additional Toxicological information. Aggravated Medical Conditions Interactive effects Potential Environmental Effects Target organ effects Skin disorders. Gastrointestinal tract. Respiratory disorders.. See Section 12 for additional Ecological Information. EYES, Gastrointestinal tract, skin, respiratory system Page 1 / 6

2 G350CLEARA TANK ARMOR CLEAR BASE Revision date 27Jun Composition/information on Ingredients Hazardous Components component EPOXY RESIN (LER) EPOXY RESIN CASNo Weight % First aid measures Eye contact: Skin contact: Ingestion: INHALATION: Immediately flush with plenty of water. After initial flushing, remove any contact lenses and continue flushing for at least 15 minutes. If symptoms persist, call a physician Wash off immediately with soap and plenty of water removing all contaminated clothes and shoes. If symptoms persist, call a physician Do not induce vomiting without medical advice Rinse mouth Never give anything by mouth to an unconscious person Call a physician immediately If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention immediately. 5. Firefighting measures Flammable properties Suitable Extinguishing Media Combustible material. Powdered material may form explosive dustair mixtures. Water Dry chemical Carbon dioxide (CO2) Foam Contact with water may cause violent frothing. Hazardous Decomposition Products Thermal decomposition can lead to release of irritating gases and vapours. Carbon dioxide (CO2). Carbon monoxide. Aldehydes. Phenolics. Oxides of carbon, hydrocarbons. Specific hazards arising from the chemical Keep product and empty container away from heat and sources of ignition. In the event of fire and/or explosion do not breathe fumes. Protective equipment and precautions for firefighters As in any fire, wear selfcontained breathing apparatus pressuredemand, MSHA/NIOSH (approved or equivalent) and full protective gear. 6. Accidental release measures Personal precautions Environmental Precautions Methods for cleaning up Ensure adequate ventilation. Remove all sources of ignition. Use personal protective equipment. Prevent further leakage or spillage if safe to do so. Soak up with inert absorbent material (e.g. sand, silica gel, acid binder, universal binder, sawdust). OTHER INFORMATION not applicable Page 2 / 6

3 G350CLEARA TANK ARMOR CLEAR BASE Revision date 27Jun Handling and Storage Handling Handle in accordance with good industrial hygiene and safety practice Wear personal protective equipment. Do not eat, drink or smoke when using this product Wash thoroughly after handling Remove and wash contaminated clothing before reuse. Avoid dust formation in confined areas. Keep away from heat, sparks and open flame. No smoking. To avoid ignition of vapours by static electricity discharge, all metal parts of the equipment must be grounded. Storage Protect from sunlight and store in wellventilated place. Keep away from heat, sparks and flame 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Engineering measures Ensure adequate ventilation, especially in confined areas Personal protective equipment Skin Protection Long sleeved clothing, Impervious gloves Eye/face Protection Tightly fitting safety goggles Respiratory protection Use only with adequate ventilation. Do not breathe dust, vapors or spray mist. Ensure fresh air entry during application and drying. If you experience eye watering, headache or dizziness or if air monitoring demonstrates vapor/mist levels are above applicable limits, wear an appropriate, properly fitted respirator (NIOSH approved) during and after application. Follow respirator manufacturer's directions for respirator use. General Hygiene Considerations Handle in accordance with good industrial hygiene and safety practice. Avoid breathing dust created by cutting, sanding, or grinding. 9. Physical and Chemical Properties Flash Point not applicable Boiling range Upper explosion limit Lower explosion limit Evaporation Rate vapor pressure Vapor Density Specific gravity g/cm3 density lbs/gal volatile organic compounds (VOC) content.000 lbs/gal Volatile by weight.0000 % Volatile by volume.0000 % 10. Stability and Reactivity Chemical stability Incompatible products Hazardous polymerization may occur at high temperatures Acids. Strong oxidizing agents. Bases. Amines. Conditions to Avoid Possibility of Hazardous Reactions Heat, flames and sparks. Amines. Heating may cause polymerization 11. Toxicological Information Acute Toxicity Component Information Page 3 / 6

4 G350CLEARA TANK ARMOR CLEAR BASE Revision date 27Jun2013 irritation corrosivity sensitization Chronic Toxicity carcinogenicity. May cause sensitization of susceptible persons. The table below indicates whether each agency has listed any ingredient as a carcinogen. Mutegenicity Reproductive Effects Developmental Effects Teratogenicity Target organ effects Endocrine Disruptor Information Component EPOXY RESIN (LER) ( ).... EYES, Gastrointestinal tract, skin, respiratory system. EU Endocrine Disrupters EU Endocrine Disruptors Candidate List Evaluated Substances Group III Chemical Japan Endocrine Disruptor Information 12. Ecological Information ecotoxicity Harmful to aquatic organisms, may cause longterm adverse effects in the aquatic environment. 13. Disposal Considerations Waste disposal methods Contaminated packaging In accordance with local and national regulations. Empty containers should be taken for local recycling, recovery or waste disposal. 14. Transport Information DOT Proper Shipping Name Ground Transportation Only. Call TNEMEC Traffic Department for other modes of Transportation. NOT REGULATED 15. Regulatory information International Inventories TSCA DSL/NDSL EINECS/ELINCS China ENCS KECL PICCS AICS Does not comply United States of America Federal Regulations SARA 313 Page 4 / 6

5 G350CLEARA TANK ARMOR CLEAR BASE Revision date 27Jun2013 SARA 311/312 Hazardous Categorization Chronic Health Hazard Acute health hazard Fire hazard Sudden release of pressure hazard Reactive Hazard No Yes Yes No No CERCLA United States of America State Regulations California Prop. 65 This product contains the following Proposition 65 chemicals: California SCAQMD Rule 443 Contains Photochemically Reactive Solvent State RighttoKnow Other international regulations CANADA This product has been classified according to the hazard criteria of the CPR and the MSDS contains all of the information required by the CPR. WHMIS Classification D2B Toxic materials 16. Other information Revision date Revision note HMIS (Hazardous Material Information System) HEALTH 2 27Jun2013 flammability 1 reactivity 1 Disclaimer For specific information regarding occupational safety and health standards, please refer to the Code of Federal Regulations, Title 29, Part To the best of our knowledge, the information contained herein is accurate. However, neither the Tnemec Company or any of its subsidiaries assume any liability whatsoever for the accuracy of completeness of the information contained herein. Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown health hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards which exist. Page 5 / 6

6 G350CLEARA TANK ARMOR CLEAR BASE Revision date 27Jun2013 End of MSDS Page 6 / 6

7 MATERIAL SAFETY DATA SHEET Print Date 10Jul2013 Revision date 10Jul2013 Revision Number 4 common name Product Code Trade name Product Class 1. PRODUCT AND COMPANY IDENTIFICATION SERIES 350, PART B G B AMINE PAINT Manufacturer Emergency Telephone Tnemec Company, Inc Corporate Drive, Kansas City, MO (INFOTRAC) TNEMEC REGULATORY DEPT: Hazards Identification EMERGENCY OVERVIEW DANGER HARMFUL IF INHALED Causes skin and eye burns HARMFUL OR FATAL IF SWALLOWED MAY AFFECT THE BRAIN OR NERVOUS SYSTEM CAUSING DIZZINESS, HEADACHE OR NAUSEA MAY CAUSE EYE, SKIN, NOSE, THROAT AND RESPIRATORY TRACT IRRITATION MAY CAUSE ALLERGIC SKIN REACTION; EFFECTS MAY BE PERMANENT. Potential Health Effects Principle Routes of Exposure ACUTE EFFECTS EYES skin inhalation INGESTION Eye Contact, inhalation, Skin Contact. Causes burns. Causes burns. May cause sensitization by skin contact. Irritating to respiratory system. Respirable crystalline silica (quartz) can cause silicosis, a fibrosis (scarring) of the lungs. MAY BE HARMFUL IF SWALLOWED. Chronic Effects NOTICE: Reports have associated repeated and prolonged occupational overexposure to solvents with permanent brain and nervous system damage. Intentional misuse by deliberately concentrating and inhaling the contents may be harmful or fatal. Cancer hazard. Contains crystalline silica which can cause cancer. (Risk of cancer depends on duration and level of exposure). See Section 11 for additional Toxicological information. Aggravated Medical Conditions Interactive effects Potential Environmental Effects Skin disorders. Respiratory disorders.. See Section 12 for additional Ecological Information. Page 1 / 7

8 G B Revision date 10Jul2013 Target organ effects Central Vascular System (CVS), EYES, Lungs, respiratory system, skin 3. Composition/information on Ingredients Hazardous Components component CASNo Weight % CRYSTALLINE SILICA (QUARTZ) BENZYL ALCOHOL DIETHYLENE TRIAMINE Trade secret 5 10 PROPRIETARY PIGMENT 1 5 MODIFIED ALIPHATIC AMINE HEXAMETHYLENEDIAMINE ALUMINUM HYDROXIDE ZIRCONIUM OXIDE First aid measures Eye contact: Skin contact: Ingestion: INHALATION: Rinse thoroughly with plenty of water for at least 15 minutes. Wash off immediately with soap and plenty of water If swallowed, do not induce vomiting. Get medical attention immediately. Move to fresh air. Oxygen or artificial respiration if needed 5. Firefighting measures Flammable properties Suitable Extinguishing Media. Use extinguishing measures that are appropriate to local circumstances and the surrounding environment Contact with water may cause violent frothing. Use: Carbon dioxide (CO2) Foam Dry chemical Hazardous Decomposition Products Oxides of carbon, hydrocarbons. Oxides of nitrogen. Aldehydes. Specific hazards arising from the chemical Thermal decomposition can lead to release of irritating gases and vapours. In the event of fire and/or explosion do not breathe fumes. Protective equipment and precautions for firefighters Use water spray to cool unopened containers. In the event of fire, wear selfcontained breathing apparatus. Keep away from heat/sparks/open flames/hot surfaces. MAY CAUSE HEAT AND PRESSURE BUILDUP IN CLOSED CONTAINERS. 6. Accidental release measures Personal precautions Environmental Precautions Avoid contact with skin, eyes and clothing. Use personal protective equipment. Remove all sources of ignition. Prevent further leakage or spillage if safe to do so. Do not flush into surface water or sanitary sewer system. Page 2 / 7

9 G B Revision date 10Jul2013 Methods for cleaning up If spilled, contain spilled material and remove with inert absorbent. Dispose of contaminated absorbent, container and unused contents in accordance with local, state and federal regulations. OTHER INFORMATION not applicable 7. Handling and Storage Handling Close container after each use. Avoid contact with skin, eyes and clothing. Do not eat, drink or smoke when using this product If splashes are likely to occur, wear goggles. Wear protective gloves/clothing. Do not burn, or use a cutting torch on, the empty drum. When used in a mixture, read the labels and safety data sheets of all components. Wash thoroughly after handling Storage Prevent buildup of vapors by opening all windows and doors to achieve cross ventilation. 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Exposure guidelines component ACGIH TLV OSHA PEL Quebec TWAEV CRYSTALLINE SILICA TWA: mg/m 3 TWA: 0.1 mg/m 3 TWA: 0.1 mg/m 3 (QUARTZ) DIETHYLENE TRIAMINE TWA: 1 ppm TWA: 1 ppm TWA: 4 TWA: 1 ppm TWA: 4.2 Skin mg/m 3 mg/m 3 Skin Ontario TWAEV Mexico OEL (TWA) TWA: 0.10 mg/m 3 TWA: 0.1 mg/m 3 TWA: 1 ppm Skin TWA: 1 ppm TWA: 4.2 mg/m 3 TWA: 10 mg/m 3 TWA: 0.5 ppm Trade secret TWA: 10 mg/m 3 TWA: 10 mg/m 3 TWA: 10 mg/m 3 TWA: 10 mg/m 3 TWA: 15 mg/m 3 STEL: 20 mg/m 3 PROPRIETARY PIGMENT TWA: 10 mg/m 3 TWA: 5 mg/m 3 HEXAMETHYLENEDIAMIN TWA: 0.5 ppm TWA: 0.5 ppm TWA: E 2.3 mg/m 3 ALUMINUM HYDROXIDE TWA: 1 mg/m 3 TWA: 1 mg/m 3 ZIRCONIUM OXIDE TWA: 5 mg/m 3 TWA: 5 mg/m 3 STEL: 10 mg/m 3 TWA: 5 mg/m 3 STEL: 10 mg/m 3 TWA: 5 mg/m 3 STEL: 10 mg/m 3 Engineering measures Ensure adequate ventilation, especially in confined areas Personal protective equipment Skin Protection Eye/face Protection Respiratory protection Lightweight protective clothing, Apron, Impervious gloves Goggles If splashes are likely to occur, wear faceshield. Use only with adequate ventilation. Do not breathe dust, vapors or spray mist. Ensure fresh air entry during application and drying. If you experience eye watering, headache or dizziness or if air monitoring demonstrates vapor/mist levels are above applicable limits, wear an appropriate, properly fitted respirator (NIOSH approved) during and after application. Follow respirator manufacturer's directions for respirator use. General Hygiene Considerations Handle in accordance with good industrial hygiene and safety practice. Avoid breathing dust created by cutting, sanding, or grinding. 9. Physical and Chemical Properties Flash Point not applicable Boiling range.0 Upper explosion limit Lower explosion limit Evaporation Rate vapor pressure Page 3 / 7

10 G B Revision date 10Jul2013 Vapor Density Specific gravity g/cm3 density lbs/gal volatile organic compounds (VOC) content.374 lbs/gal Volatile by weight % Volatile by volume % 10. Stability and Reactivity Chemical stability Incompatible products Stable Conditions to Avoid Heat, flames and sparks. Epoxy constituents. Strong oxidizing agents. Acids. Possibility of Hazardous None under normal processing Bases. Reactions 11. Toxicological Information Acute Toxicity Component Information component LD50 Oral LD50 Dermal LC50 Inhalation CRYSTALLINE SILICA (QUARTZ) 500 mg/kg ( Rat ) BENZYL ALCOHOL 1230 mg/kg ( Rat ) 2 g/kg ( Rabbit ) 8.8 mg/l ( Rat ) 4 h DIETHYLENE TRIAMINE 819 mg/kg ( Rat ) 672 mg/kg ( Rabbit ) Trade secret mg/kg ( Rat ) MODIFIED ALIPHATIC AMINE 1000 mg/kg ( Rat ) 1280 mg/kg ( Rat ) HEXAMETHYLENEDIAMINE 750 mg/kg ( Rat ) 1110 mg/kg ( Rabbit ) ALUMINUM HYDROXIDE 5000 mg/kg ( Rat ) irritation corrosivity. sensitization. Chronic Toxicity carcinogenicity The table below indicates whether each agency has listed any ingredient as a carcinogen. component ACGIH IARC NTP OSHA Mexico CRYSTALLINE SILICA A2 Group 1 Known X (QUARTZ) Trade secret Group 2B X Mutegenicity Reproductive Effects Developmental Effects Teratogenicity Target organ effects Endocrine Disruptor Information.... Central Vascular System (CVS), EYES, Lungs, respiratory system, skin. 12. Ecological Information ecotoxicity component Toxicity to algae Toxicity to fish Toxicity to Microorganisms Toxicity to daphnia Page 4 / 7

11 G B Revision date 10Jul2013 BENZYL ALCOHOL DIETHYLENE TRIAMINE HEXAMETHYLENEDIAMIN E EC50 = 35 mg/l 3 h EC50 = 1164 mg/l 72 h EC50 = mg/l 96 h EC50 = 592 mg/l 96 h EC50 = 15 mg/l 72 h EC50 = 14.8 mg/l 96 h LC50= 10 mg/l Lepomis macrochirus 96 h LC50= 460 mg/l Pimephales promelas 96 h LC50= 1014 mg/l Poecilia reticulata 96 h LC50= 248 mg/l Poecilia reticulata 96 h LC50= 430 mg/l Leuciscus idus 96 h LC50= 1825 mg/l Pimephales promelas 96 h LC50= 62 mg/l Leuciscus idus 96 h LC50> 56 mg/l Lepomis macrochirus 96 h EC50 = 63.7 mg/l 5 min EC50 = 63.7 mg/l 15 min EC50 = 71.4 mg/l 30 min EC50 = 50 mg/l 5 min EC50 = 2000 mg/l 1 h EC50 = 96 mg/l 17 h EC50 = 23 mg/l 48 h EC50 = 16 mg/l 48 h EC50 = 37 mg/l 24 h EC50 = 23.4 mg/l 48 h 13. Disposal Considerations Waste disposal methods Contaminated packaging Keep container tightly closed. If spilled, contain spilled material and remove with inert absorbent. Dispose of contaminated absorbent, container and unused contents in accordance with local, state and federal regulations. Empty containers should be taken for local recycling, recovery or waste disposal. 14. Transport Information DOT Proper Shipping Name Ground Transportation Only. Call TNEMEC Traffic Department for other modes of Transportation. UN3066,PAINT,8,PGII,ERG Regulatory information International Inventories TSCA DSL/NDSL EINECS/ELINCS China ENCS KECL PICCS AICS Does not comply Does not comply Does not comply Does not comply Does not comply The following chemical(s) are listed as HAP under the U.S. Clean Air Act, Section 12 (40 CFR 61): United States of America Federal Regulations SARA 313 SARA 311/312 Hazardous Categorization Chronic Health Hazard Acute health hazard Fire hazard Sudden release of pressure hazard Reactive Hazard Yes Yes No No No Page 5 / 7

12 G B Revision date 10Jul2013 CERCLA United States of America State Regulations California Prop. 65 This product contains the following Proposition 65 chemicals: component CASNo California Prop. 65 CRYSTALLINE SILICA (QUARTZ) Carcinogen Trade secret Carcinogen California SCAQMD Rule 443 Contains Photochemically Reactive Solvent State RighttoKnow component CRYSTALLINE SILICA (QUARTZ) BENZYL ALCOHOL HEXAMETHYLENEDIAMIN E ZIRCONIUM OXIDE Other international regulations CANADA X This product has been classified according to the hazard criteria of the CPR and the MSDS contains all of the information required by the CPR. WHMIS Classification D2B Toxic materials E Corrosive material Massachusetts New Jersey Pennsylvania Illinois Rhode Island X X X X X DIETHYLENE TRIAMINE X X X Trade secret X X X X X X Legend NPRI National Pollutant Release Inventory 16. Other information Revision date Revision note HMIS (Hazardous Material Information System) 10Jul2013 HEALTH 3* flammability 1 reactivity 1 Page 6 / 7

13 G B Revision date 10Jul2013 Disclaimer For specific information regarding occupational safety and health standards, please refer to the Code of Federal Regulations, Title 29, Part To the best of our knowledge, the information contained herein is accurate. However, neither the Tnemec Company or any of its subsidiaries assume any liability whatsoever for the accuracy of completeness of the information contained herein. Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown health hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards which exist. End of MSDS Page 7 / 7