Ethanol (cas ) MSDS
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1 Click http// for suppliers of this product Ethanol (cas ) MSDS IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING Product identifiers Product name Product Number Brand CAS-No. Ethanol Anonymous Relevant identified uses of the substance or mixture and uses advised against Identified uses Laboratory chemicals, Manufacture of substances HAZARDS IDENTIFICATION Classification of the substance or mixture Classification according to Regulation (EC) No 1272/2008 [EU-GHS/CLP] Flammable liquids (Category 2) Acute toxicity, Oral (Category 4) Specific target organ toxicity - single exposure (Category 2) Classification according to EU Directives 67/548/EEC or 1999/45/EC Highly flammable. Harmful by inhalation, in contact with skin and if swallowed. Harmful possible risk of irreversible effects through inhalation, in contact with skin and if swallowed. Label elements Labelling according Regulation (EC) No 1272/2008 [CLP] Pictogram Signal word Hazard statement(s) H225 H302 H371 Precautionary statement(s) P210 P260 Danger Highly flammable liquid and vapour. Harmful if swallowed. May cause damage to organs. Supplemental Hazard none Statements According to European Directive 67/548/EEC as amended. Hazard symbol(s) Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not breathe dust/ fume/ gas/ mist/ vapours/ spray. 2.3 R-phrase(s) R11 R20/21/22 R68/20/21/22 S-phrase(s) S16 S36/37 Other hazards - none Highly flammable. Harmful by inhalation, in contact with skin and if swallowed. Harmful possible risk of irreversible effects through inhalation, in contact with skin and if swallowed. Keep away from sources of ignition - No smoking. Wear suitable protective clothing and gloves COMPOSITION/INFORMATION ON INGREDIENTS Mixtures Synonyms Ethyl alcohol Ethyl alcohol, Reagent alcohol Formula Molecular Weight C2H6O 46,07 g/mol Component Classification Concentration
2 methanol CAS-No. EC-No. Index-No. 2-Propanol CAS-No. EC-No. Index-No X Flam. Liq. 2; Acute Tox. 3; STOT SE 1; H225, H301, H311, H331, H370 F, T, R11 - R23/24/25 - R39/23/24/ % Flam. Liq. 2; Eye Irrit. 2; STOT < 10 % SE 3; H225, H319, H336 F, Xi, R11 - R36 - R67 For the full text of the H-Statements and R-Phrases mentioned in this Section, see Section FIRST AID MEASURES Description of first aid measures General advice Consult a physician. Show this safety data sheet to the doctor in attendance. If inhaled If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician. In case of skin contact Wash off with soap and plenty of water. Take victim immediately to hospital. Consult a physician. In case of eye contact Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician. If swallowed Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician. Most important symptoms and effects, both acute and delayed To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated., Central nervous system depression, Gastrointestinal disturbance, Nausea, Dizziness, Headache, narcosis, May cause convulsions. Indication of any immediate medical attention and special treatment needed FIREFIGHTING MEASURES Extinguishing media Suitable extinguishing media Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide. Special hazards arising from the substance or mixture Carbon oxides Advice for firefighters Wear self contained breathing apparatus for fire fighting if necessary. Further information Use water spray to cool unopened containers. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures Use personal protective equipment. Avoid breathing vapors, mist or gas. Ensure adequate ventilation. Remove all sources of ignition. Evacuate personnel to safe areas. Beware of vapours accumulating to form explosive concentrations. Vapours can accumulate in low areas. Environmental precautions Prevent further leakage or spillage if safe to do so. Do not let product enter drains. Methods and materials for containment and cleaning up Contain spillage, and then collect with an electrically protected vacuum cleaner or by wet-brushing and place in container for disposal according to local regulations (see section 13). Reference to other sections For disposal see section 13. HANDLING AND STORAGE Precautions for safe handling Avoid contact with skin and eyes. Avoid inhalation of vapour or mist. Keep away from sources of ignition - No smoking.take measures to prevent the build up of electrostatic charge. Conditions for safe storage, including any incompatibilities Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Containers which are opened must be carefully resealed and kept upright to prevent leakage.
3 Moisture sensitive. Handle and store under inert gas. Specific end uses EXPOSURE CONTROLS/PERSONAL PROTECTION Control parameters Components with workplace control parameters Exposure controls Appropriate engineering controls Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and at the end of workday. Personal protective equipment Eye/face protection Face shield and safety glasses Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU). Skin protection Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique (without touching glove's outer surface) to avoid skin contact with this product. Dispose of contaminated gloves after use in accordance with applicable laws and good laboratory practices. Wash and dry hands. The selected protective gloves have to satisfy the specifications of EU Directive 89/686/EEC and the standard EN 374 derived from it. Body Protection Complete suit protecting against chemicals, Flame retardant antistatic protective clothing, The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace. Respiratory protection Where risk assessment shows air-purifying respirators are appropriate use a full-face respirator with multi-purpose combination (US) or type ABEK (EN 14387) respirator cartridges as a backup to engineering controls. If the respirator is the sole means of protection, use a full-face supplied air respirator. Use respirators and components tested and approved under appropriate government standards such as NIOSH (US) or CEN (EU) PHYSICAL AND CHEMICAL PROPERTIES Information on basic physical and chemical properties a) b) c) d) e) f) g) h) Appearance Odour Odour Threshold ph Melting point/freezing point Initial boiling point and boiling range Flash point Evaporation rate Form liquid Melting point/range -130 C 78 C at hpa 9 C - closed cup i) Flammability (solid, gas) j) k) l) Upper/lower flammability or explosive limits Vapour pressure Vapour density Upper explosion limit 24,5 %(V) Lower explosion limit 3,3 %(V) 59,5 hpa at 20 C m) Relative density 0,785 g/cm3 n) o) p) q) r) Water solubility Partition coefficient n- octanol/water Autoignition temperature Decomposition temperature Viscosity 362 C
4 s) Explosive properties t) Oxidizing properties 9.2 Other safety information STABILITY AND REACTIVITY Reactivity Chemical stability Possibility of hazardous reactions Conditions to avoid Heat, flames and sparks. Extremes of temperature and direct sunlight. Incompatible materials Aluminium, Acids, Oxidizing agents, Alkali metals, Halogenated compounds, Ammonia, Acid chlorides, Acid anhydrides, Reducing agents, Peroxides Hazardous decomposition products Other decomposition products - TOXICOLOGICAL INFORMATION Information on toxicological effects Acute toxicity Skin corrosion/irritation Serious eye damage/eye irritation Respiratory or skin sensitization Germ cell mutagenicity Carcinogenicity IARC 3 - Group 3 Not classifiable as to its carcinogenicity to humans (2-Propanol) Reproductive toxicity Specific target organ toxicity - single exposure Specific target organ toxicity - repeated exposure Aspiration hazard Potential health effects Inhalation Ingestion Skin Eyes Toxic if inhaled. Causes respiratory tract irritation. Toxic if swallowed. Toxic if absorbed through skin. Causes skin irritation. Causes serious eye irritation. Signs and Symptoms of Exposure To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated., Central nervous system depression, Gastrointestinal disturbance, Nausea, Dizziness, Headache, narcosis, May cause convulsions. Additional Information RTECS Not available ECOLOGICAL INFORMATION Toxicity Persistence and degradability Bioaccumulative potential
5 Mobility in soil Results of PBT and vpvb assessment Other adverse effects DISPOSAL CONSIDERATIONS Waste treatment methods Product Burn in a chemical incinerator equipped with an afterburner and scrubber but exert extra care in igniting as this material is highly flammable. Offer surplus and non-recyclable solutions to a licensed disposal company. Contaminated packaging Dispose of as unused product TRANSPORT INFORMATION UN number ADR/RID 1170 UN proper shipping name ADR/RID ETHYL ALCOHOL IMDG ETHANOL SOLUTION IATA Ethanol solution Transport hazard class(es) ADR/RID 3 Packaging group ADR/RID II Environmental hazards ADR/RID no Special precautions for user IMDG 1170 IMDG 3 IMDG II IMDG Marine pollutant no IATA 1170 IATA 3 IATA II IATA no REGULATORY INFORMATION This safety datasheet complies with the requirements of Regulation (EC) No. 1907/2006. Safety, health and environmental regulations/legislation specific for the substance or mixture Chemical Safety Assessment OTHER INFORMATION Text of H-code(s) and R-phrase(s) mentioned in Section 3 Acute Tox. Eye Irrit. Flam. Liq. H225 H301 H311 H319 H331 H336 H370 STOT SE F R11 R23/24/25 R36 T Xi R39/23/24/25 R67 Acute toxicity Eye irritation Flammable liquids Highly flammable liquid and vapour. Toxic if swallowed. Toxic in contact with skin. Causes serious eye irritation. Toxic if inhaled. May cause drowsiness or dizziness. Causes damage to organs. Specific target organ toxicity - single exposure Highly flammable Highly flammable. Toxic by inhalation, in contact with skin and if swallowed. Irritating to eyes. Toxic Irritant Toxic danger of very serious irreversible effects through inhalation, in contact with skin and if swallowed. Vapours may cause drowsiness and dizziness. Further information The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information this document is based on the resent state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any guarantee of the properties of the product. guidechem shall not be
6 held liable for any damage resulting from handling or from contact with the above product. See reverse side of invoice or packing slip for additional terms and conditions of sale.
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