SAFETY DATA SHEET Aerosol Glass Cleaner

Transcription

1 Revision Date 06/05/2014 Revision 17 Supersedes date 11/11/2013 SAFETY DATA SHEET Aerosol Glass Cleaner SECTION 1: IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING 1.1. Product identifier Product name Product No. REACH Registration notes Aerosol Glass Cleaner SIM34, , , , SIM34A, SAPP0701A, SAPP0030A, SAPP0102A This is a MIXTURE; no registration information contained in this document. Holts are classed as Downstream User Relevant identified uses of the substance or mixture and uses advised against Identified uses Car maintenance product. Glass cleaner Details of the supplier of the safety data sheet Supplier Contact Person Manufacturer Holt Lloyd International Ltd Barton Dock Road Stretford Manchester M32 0YQ - England, UK +44 (0) FAX +44 (0) A Holts Car Care Product Regulatory Affairs Contact address: info@holtsauto.com Holt Lloyd International Ltd Barton Dock Road Stretford Manchester M32 0YQ - England, UK +44 (0) FAX +44 (0) A Holts Car Care Product Emergency telephone number UK (0) Office hrs = hrs Out of office hours Tel: National Emergency Telephone Number SECTION 2: HAZARDS IDENTIFICATION 2.1. Classification of the substance or mixture Physical and Chemical Hazards Flam. Aerosol 1 - H222+H229 Human health Not classified. Environment Not classified. Classification (1999/45/EEC) F+;R12. The Full Text for all R-Phrases and Hazard Statements are Displayed in Section Label elements 1 / 8

2 Detergent Labelling: Aerosol Glass Cleaner < 5% anionic surfactants Label In Accordance With (EC) No. 1272/2008 Signal Word Hazard Statements Precautionary Statements Danger H222+H229 P102 P101 P210 P211 P251 Extremely flammable aerosol. Pressurised container: May burst if heated. Keep out of reach of children. If medical advice is needed, have product container or label at hand. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not spray on an open flame or other ignition source. Pressurized container: Do not pierce or burn, even after use. P Protect from sunlight. Do not expose to temperatures exceeding 50 C/122 F. P501 Dispose of contents/container in accordance with local regulations Other hazards SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS 3.2. Mixtures 2-BUTOXYETHANOL 1-5% CAS-No.: EC No.: Acute Tox. 4 - H302 Acute Tox. 4 - H312 Acute Tox. 4 - H332 Skin Irrit. 2 - H315 Eye Irrit. 2 - H319 Classification (67/548/EEC) Xn;R20/21/22 Xi;R36/38 BUTANE 1-5% CAS-No.: EC No.: Flam. Gas 1 - H220 Classification (67/548/EEC) F+;R12 ISOBUTANE 1-5% CAS-No.: EC No.: Flam. Gas 1 - H220 Classification (67/548/EEC) F+;R12 2 / 8

3 ETHANEDIOL < 1% CAS-No.: EC No.: Acute Tox. 4 - H302 Classification (67/548/EEC) Xn;R22 The Full Text for all R-Phrases and Hazard Statements are Displayed in Section 16. REACH Registration notes This is a MIXTURE; no registration information contained in this document. Holts are classed as Downstream User. SECTION 4: FIRST AID MEASURES 4.1. Description of first aid measures General information Move the exposed person to fresh air at once. Get medical attention if any discomfort continues. Inhalation Move the exposed person to fresh air at once. Get medical attention if any discomfort continues. Ingestion NEVER MAKE AN UNCONSCIOUS PERSON VOMIT OR DRINK FLUIDS! Rinse mouth thoroughly. Drink plenty of water. Get medical attention if any discomfort continues. Skin contact Remove affected person from source of contamination. Get medical attention if irritation persists after washing. Eye contact Make sure to remove any contact lenses from the eyes before rinsing. Promptly wash eyes with plenty of water while lifting the eye lids. Continue to rinse for at least 15 minutes. Get medical attention if any discomfort continues Most important symptoms and effects, both acute and delayed General information The severity of the symptoms described will vary dependant of the concentration and the length of exposure. Inhalation Drowsiness, dizziness, disorientation, vertigo. Ingestion Due to the physical nature of this material it is unlikely that swallowing will occur. Skin contact No specific symptoms noted. Prolonged skin contact may cause redness and irritation. Eye contact No specific symptoms noted. May cause temporary eye irritation Indication of any immediate medical attention and special treatment needed Treat Symptomatically. SECTION 5: FIREFIGHTING MEASURES 5.1. Extinguishing media Extinguishing media Alcohol resistant foam. Carbon dioxide (CO2). Dry chemicals, sand, dolomite etc Special hazards arising from the substance or mixture Hazardous combustion products Thermal decomposition or combustion may liberate carbon oxides and other toxic gases or vapours. Unusual Fire & Explosion Hazards Extremely flammable. May explode in a fire. If heated, volume and pressure increases strongly, resulting in explosion of container. Specific hazards Fire creates: Carbon dioxide (CO2). Carbon monoxide (CO). 3 / 8

4 5.3. Advice for firefighters Special Fire Fighting Procedures Keep run-off water out of sewers and water sources. Dike for water control. Protective equipment for fire-fighters Wear full protective clothing. SECTION 6: ACCIDENTAL RELEASE MEASURES 6.1. Personal precautions, protective equipment and emergency procedures Wear protective clothing as described in Section 8 of this safety data sheet Environmental precautions Not relevant considering the small amounts used Methods and material for containment and cleaning up Stop leak if possible without risk. Absorb in vermiculite, dry sand or earth and place into containers. Flush with plenty of water to clean spillage area. Do not contaminate water sources or sewer Reference to other sections Wear protective clothing as described in Section 8 of this safety data sheet. See section 11 for additional information on health hazards. For waste disposal, see section 13. SECTION 7: HANDLING AND STORAGE 7.1. Precautions for safe handling Avoid spilling, skin and eye contact Conditions for safe storage, including any incompatibilities Store in tightly closed original container in a dry, cool and well-ventilated place. Keep in original container. Storage Class Flammable liquid storage Specific end use(s) The identified uses for this product are detailed in Section 1.2. SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1. Control parameters Name STD TWA - 8 Hrs STEL - 15 Min Notes 2-BUTOXYETHANOL WEL 25 ppm(sk) 120 mg/m3 50 ppm(sk) BUTANE ETHANEDIOL ISOBUTANE WEL 600 ppm 1450 mg/m3 750 ppm 1810 mg/m3 WEL 10 mg/m3(sk) 104 mg/m3(sk) OES 800 ppm 800 ppm WEL = Workplace Exposure Limit. Ingredient Comments WEL = Workplace Exposure Limits Ingredient Comments WEL = Workplace Exposure Limits ETHANEDIOL (CAS: ) 8.2. Exposure controls Protective equipment 4 / 8

5 Engineering measures Provide adequate general and local exhaust ventilation. Hand protection Use suitable protective gloves if risk of skin contact. Rubber gloves are recommended. EN374 Eye protection If risk of splashing, wear safety goggles or face shield. Other Protection Wear appropriate clothing to prevent any possibility of skin contact. Hygiene measures DO NOT SMOKE IN WORK AREA! Wash hands at the end of each work shift and before eating, smoking and using the toilet. Wash promptly if skin becomes wet or contaminated. Promptly remove any clothing that becomes contaminated. Use appropriate skin cream to prevent drying of skin. When using do not eat, drink or smoke. SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES 9.1. Information on basic physical and chemical properties Appearance Liquid Colour Colourless. Odour Characteristic. Solubility Miscible with water Alcohol Relative density ph-value, Conc. Solution 9.0 Flash point ( C) <1C 9.2. Other information SECTION 10: STABILITY AND REACTIVITY Reactivity No specific reactivity hazards associated with this product Chemical stability Stable under normal temperature conditions Possibility of hazardous reactions Not relevant Hazardous Polymerisation May polymerise. Polymerisation Description Avoid heat Conditions to avoid Avoid excessive heat for prolonged periods of time. Avoid heat, flames and other sources of ignition. Avoid contact with: Strong oxidising agents Incompatible materials Materials To Avoid No specific, or groups of materials are likely to react to produce a hazardous situation Hazardous decomposition products Fire creates: Carbon monoxide (CO). Carbon dioxide (CO2). 5 / 8

6 SECTION 11: TOXICOLOGICAL INFORMATION Aerosol Glass Cleaner Information on toxicological effects Toxicological information No information available. Inhalation High concentration of mist may be irritating to the upper respiratory tract. Ingestion May cause discomfort if swallowed. Skin contact Prolonged or repeated exposure may cause severe irritation. Eye contact Repeated exposure may cause chronic eye irritation. Route of entry Inhalation. Skin and/or eye contact. SECTION 12: ECOLOGICAL INFORMATION Ecotoxicity The product is not expected to be hazardous to the environment Toxicity Persistence and degradability Bioaccumulative potential Bioaccumulative potential The product does not contain any substances expected to be bioaccumulating Mobility in soil Mobility: The product contains volatile organic compounds (VOC) which will evaporate easily from all surfaces Results of PBT and vpvb assessment This product does not contain any PBT or vpvb substances Other adverse effects None known. SECTION 13: DISPOSAL CONSIDERATIONS Waste treatment methods Dispose of waste and residues in accordance with local authority requirements. SECTION 14: TRANSPORT INFORMATION UN number UN No. (ADR/RID/ADN) 1950 UN No. (IMDG) 1950 UN No. (ICAO) / 8

7 14.2. UN proper shipping name Proper Shipping Name AEROSOLS Transport hazard class(es) ADR/RID/ADN Class 2 ADR/RID/ADN Class Class 2: Gases ADR Label No. 2.1 IMDG Class 2.1 ICAO Class/Division 2.1 Transport Labels FLAMMABLE GAS Packing group ADR/RID/ADN Packing group IMDG Packing group ICAO Packing group N/A N/A N/A Environmental hazards Environmentally Hazardous Substance/Marine Pollutant No Special precautions for user EMS F-D, S-U Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code SECTION 15: REGULATORY INFORMATION Safety, health and environmental regulations/legislation specific for the substance or mixture Statutory Instruments The Chemicals (Hazard Information and Packaging for Supply) Regulations 2009 (S.I 2009 No. 716). EU Legislation Dangerous Substance Directive 67/548/EEC. Dangerous Preparations Directive 1999/45/EC. Regulation (EC) No 1907/2006 of the European Parliament and of the Council of 18 December 2006 concerning the Registration, Evaluation, Authorisation and Restriction of Chemicals (REACH), establishing a European Chemicals Agency, amending Directive 1999/45/EC and repealing Council Regulation (EEC) No 793/93 and Commission Regulation (EC) No 1488/94 as well as Council Directive 76/769/EEC and Commission Directives 91/155/EEC, 93/67/EEC, 93/105/EC and 2000/21/EC, including amendments. Aerosol Dispensers Directive 2008/47/EC (2008/47/EC) National Regulations The Chemicals (Hazard Information and Packaging for Supply) Regulations No The Aerosol Dispensers (EEC Requirements) (Amendment) Regulations 1996 (S.I 1996 No. 2421). Authorisations (Title VII Regulation 1907/2006) No specific authorisations are noted for this product. Restrictions (Title VIII Regulation 1907/2006) No specific restrictions of use are noted for this product. Water hazard classification WGK 1 7 / 8

8 15.2. Chemical Safety Assessment No chemical safety assessment has been carried out. SECTION 16: OTHER INFORMATION Revision Date 06/05/2014 Revision 17 Supersedes date 11/11/2013 SDS No Safety Data Sheet Status Approved. Date November 2006 Risk Phrases In Full R12 Extremely flammable. R20/21/22 Harmful by inhalation, in contact with skin and if swallowed. R22 Harmful if swallowed. R36/38 Irritating to eyes and skin. Hazard Statements In Full H220 Extremely flammable gas. H222+H229 Extremely flammable aerosol. Pressurised container: May burst if heated. H302 Harmful if swallowed. H312 Harmful in contact with skin. H315 Causes skin irritation. H319 Causes serious eye irritation. H332 Harmful if inhaled. Disclaimer This information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process. Such information is, to the best of the company's knowledge and belief, accurate and reliable as of the date indicated. However, no warranty guarantee or representation is made to its accuracy, reliability or completeness. It is the user's responsibility to satisfy himself as to the suitability of such information for his own particular use. 8 / 8