Material Safety Data Sheet

Transcription

1 Material Safety Data Sheet NFPA HMIS Personal Protective Equipment 3 0 Health Hazard Fire Hazard 3 0 See Section 5. Section. Chemical Product and Company Identification Common Name/ Trade Name Manufacturer Commercial Name(s) Synonym Chemical Name Thiourea SPECTRUM CHEMICAL MFG. CORP S. SAN PEDRO STREET GARDENA, CA Thiocarbamide Catalog Number(s). CAS# RTECS TSCA CI# T040, T YU IN CASE OF EMERGENCY CHEMTREC (24hr) Page Number: TSCA 8(b) inventory: Thiourea Chemical Family Chemical Formula Supplier NH2CSNH2 SPECTRUM CHEMICAL MFG. CORP S. SAN PEDRO STREET GARDENA, CA CALL (30) Section 2.Composition and Information on Ingredients Name CAS # Exposure Limits TWA (mg/m 3 ) STEL (mg/m 3 ) CEIL (mg/m 3 ) % by Weight ) Thiourea Toxicological Data on Ingredients Thiourea: ORAL (LD50): Acute: 25 mg/kg [Rat]. Section 3. Hazards Identification Potential Acute Health Effects Potential Chronic Health Effects Very hazardous in case of ingestion. Hazardous in case of skin contact (irritant), of eye contact (irritant), of inhalation. Slightly hazardous in case of skin contact (permeator). Severe over-exposure can result in death. CARCINOGENIC EFFECTS: MUTAGENIC EFFECTS: TERATOGENIC EFFECTS: DEVELOPMENTAL TOXICITY: The substance is toxic to lungs, mucous membranes. Repeated or prolonged exposure to the substance can produce target organs damage. Repeated exposure to an highly toxic material may produce general deterioration of health by an accumulation in one or many human organs.

2 Thiourea Page Number: 2 Section 4. First Aid Measures Eye Contact Skin Contact Serious Skin Contact Inhalation Check for and remove any contact lenses. Immediately flush eyes with running water for at least 5 minutes, keeping eyelids open. Cold water may be used. Do not use an eye ointment. Seek medical attention. After contact with skin, wash immediately with plenty of water. Gently and thoroughly wash the contaminated skin with running water and non-abrasive soap. Be particularly careful to clean folds, crevices, creases and groin. Cold water may be used. Cover the irritated skin with an emollient. If irritation persists, seek medical attention. Wash contaminated clothing before reusing. Wash with a disinfectant soap and cover the contaminated skin with an anti-bacterial cream. Seek immediate medical attention. Allow the victim to rest in a well ventilated area. Seek immediate medical attention. Serious Inhalation Ingestion Serious Ingestion Evacuate the victim to a safe area as soon as possible. Loosen tight clothing such as a collar, tie, belt or waistband. If breathing is difficult, administer oxygen. If the victim is not breathing, perform mouth-to-mouth resuscitation. Seek medical attention. Do not induce vomiting. Examine the lips and mouth to ascertain whether the tissues are damaged, a possible indication that the toxic material was ingested; the absence of such signs, however, is not conclusive. Loosen tight clothing such as a collar, tie, belt or waistband. If the victim is not breathing, perform mouth-to-mouth resuscitation. Seek immediate medical attention. Section 5. Fire and Explosion Data Flammability of the Product Auto-Ignition Temperature Flash Points Flammable Limits Products of Combustion Fire Hazards in Presence of Various Substances May be combustible at high temperature. These products are carbon oxides (CO, CO2), nitrogen oxides (NO, NO2...), sulfur oxides (SO2, SO3...). Explosion Hazards in Presence of Various Substances Risks of explosion of the product in presence of mechanical impact: Risks of explosion of the product in presence of static discharge: Fire Fighting Media and Instructions Fire Hazards Explosion Hazards SMALL FIRE: Use DRY chemical powder. LARGE FIRE: Use water spray, fog or foam. Do not use water jet. Section 6. Accidental Release Measures Small Spill Large Spill Use appropriate tools to put the spilled solid in a convenient waste disposal container. Use a shovel to put the material into a convenient waste disposal container.

3 Thiourea Page Number: 3 Section 7. Handling and Storage Precautions Storage Keep locked up Keep away from heat. Keep away from sources of ignition. Empty containers pose a fire risk, evaporate the residue under a fume hood. Ground all equipment containing material. Do not ingest. Do not breathe dust. Wear suitable protective clothing In case of insufficient ventilation, wear suitable respiratory equipment If ingested, seek medical advice immediately and show the container or the label. Avoid contact with skin and eyes Keep container dry. Keep in a cool place. Ground all equipment containing material. Keep container tightly closed. Keep in a cool, well-ventilated place. Highly toxic or infectious materials should be stored in a separate locked safety storage cabinet or room. Section 8. Exposure Controls/Personal Protection Engineering Controls Personal Protection Personal Protection in Case of a Large Spill Exposure Limits Use process enclosures, local exhaust ventilation, or other engineering controls to keep airborne levels below recommended exposure limits. If user operations generate dust, fume or mist, use ventilation to keep exposure to airborne contaminants below the exposure limit. Splash goggles. Lab coat. Dust respirator. Be sure to use an approved/certified respirator or equivalent. Gloves. Splash goggles. Full suit. Dust respirator. Boots. Gloves. A self contained breathing apparatus should be used to avoid inhalation of the product. Suggested protective clothing might not be sufficient; consult a specialist BEFORE handling this product. Section 9. Physical and Chemical Properties Physical state and appearance Solid. Odor Molecular Weight ph (% soln/water) 76.2 g/mole Taste Color Boiling Point Decomposes. Melting Point 77 C (350.6 F) Critical Temperature Specific Gravity.4 (Water = ) Vapor Pressure Not applicable. Vapor Density Volatility Odor Threshold Water/Oil Dist. Coeff. Ionicity (in Water) Dispersion Properties See solubility in water. Solubility Partially soluble in cold water.

4 Thiourea Page Number: 4 Section 0. Stability and Data Stability Instability Temperature Conditions of Instability Incompatibility with various substances Corrosivity The product is stable. Non-corrosive in presence of glass. Corrosivity Polymerization No. Section. Toxicological Information Routes of Entry Toxicity to Animals Chronic Effects on Humans Other Toxic Effects on Humans Toxicity to Animals Chronic Effects on Humans other Toxic Effects on Humans Eye contact. Inhalation. Ingestion. Acute oral toxicity (LD50): 25 mg/kg [Rat]. The substance is toxic to lungs, mucous membranes. Very hazardous in case of ingestion. Hazardous in case of skin contact (irritant), of inhalation. Slightly hazardous in case of skin contact (permeator). Passes through the placental barrier in animal. Section 2. Ecological Information Ecotoxicity BOD5 and COD Products of Biodegradation Toxicity of the Products of Biodegradation the Products of Biodegradation Possibly hazardous short term degradation products are not likely. However, long term degradation products may arise. The products of degradation are more toxic.

5 Thiourea Page Number: 5 Section 3. Disposal Considerations Waste Disposal Section 4. Transport Information DOT Classification Identification CLASS 6.: Poisonous material. : Toxic solid, organic, n.o.s. (Thiourea) : UN28 PG: III Special Provisions for Transport DOT HARMFUL STOW AWAY FROM FOODSTUFFS 6 Section 5. Other Regulatory Information and Pictograms Federal and State Regulations California Proposition 65 Warnings Other Regulations California prop. 65: This product contains the following ingredients for which the State of California has found to cause cancer, birth defects or other reproductive harm, which would require a warning under the statute: Thiourea California prop. 65: This product contains the following ingredients for which the State of California has found to cause cancer which would require a warning under the statute: Thiourea Pennsylvania RTK: Thiourea Massachusetts RTK: Thiourea TSCA 8(b) inventory: Thiourea SARA 33 toxic chemical notification and release reporting: Thiourea CERCLA: Hazardous substances.: Thiourea California prop. 65: This product contains the following ingredients for which the State of California has found to cause cancer which would require a warning under the statute: Thiourea OSHA: Hazardous by definition of Hazard Communication Standard (29 CFR ). Other Classifications WHMIS (Canada) DSCL (EEC) CLASS D-B: Material causing immediate and serious toxic effects (TOXIC). CLASS D-2A: Material causing other toxic effects (VERY TOXIC). R25- Toxic if swallowed. R36/38- Irritating to eyes and skin. HMIS (U.S.A.) Health Hazard Fire Hazard Personal Protection 3 0 E National Fire Protection Association (U.S.A.) Health 3 0 Flammability Specific hazard WHMIS (Canada) DSCL (Europe)

6 Thiourea Page Number: 6 TDG (Canada) 6 ADR (Europe) Protective Equipment Gloves. Lab coat. Dust respirator. Be sure to use an approved/certified respirator or equivalent. Wear appropriate respirator when ventilation is inadequate. Splash goggles. Section 6. Other Information MSDS Code References Other Special Considerations T3470 Validated by Sonia Owen on /20/2003. Verified by Sonia Owen. Printed 8/26/2004. CALL (30) Notice to Reader All chemicals may pose unknown hazards and should be used with caution. This Material Safety Data Sheet (MSDS) applies only to the material as packaged. If this product is combined with other materials, deteriorates, or becomes contaminated, it may pose hazards not mentioned in this MSDS. It shall be the user's responsibility to develop proper methods of handling and personal protection based on the actual conditions of use. While this MSDS is based on technical data judged to be reliable, Spectrum Quality Products, Inc. assumes no responsibility for the completeness or accuracy of the information contained herein.