Material Safety Data Sheet
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- Blaise Todd Marsh
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1 Material Safety Data Sheet NFPA HMIS Personal Protective Equipment 1 0 Health Hazard Fire Hazard 1 0 See Section 15. Section 1. Chemical Product and Company Identification Common Name/ Trade Name Manufacturer Commercial Name(s) Synonym Chemical Name Ethyl chloride SPECTRUM CHEMICAL MFG. CORP. 122 S. SAN PEDRO STREET GARDENA, CA 9028 Chloroethane Catalog Number(s). CAS# RTECS TSCA CI# ET KH IN CASE OF EMERGENCY CHEMTREC (2hr) Page Number: 1 TSCA 8(b) inventory: Ethyl chloride Chemical Family Chemical Formula Supplier C2H5Cl SPECTRUM CHEMICAL MFG. CORP. 122 S. SAN PEDRO STREET GARDENA, CA 9028 CALL (310) Section 2.Composition and Information on Ingredients Name CAS # Exposure Limits TWA (mg/m 3 ) STEL (mg/m 3 ) CEIL (mg/m 3 ) % by Weight 1) Ethyl chloride Toxicological Data on Ingredients Ethyl chloride: GAS (LC50): Acute: 80 ppm hour(s) [Rat]. Section 3. Hazards Identification Potential Acute Health Effects Potential Chronic Health Effects Extremely hazardous in case of inhalation. Very hazardous in case of eye contact (irritant). Slightly hazardous in case of skin contact (irritant), of ingestion. Severe over-exposure can result in death. Inflammation of the eye is characterized by redness, watering, and itching. Extremely hazardous in case of inhalation. Very hazardous in case of eye contact (irritant). Slightly hazardous in case of skin contact (irritant), of ingestion. CARCINOGENIC EFFECTS: MUTAGENIC EFFECTS: TERATOGENIC EFFECTS: DEVELOPMENTAL TOXICITY: The substance is toxic to blood, kidneys, lungs, the nervous system, liver, mucous membranes. Repeated or prolonged exposure to the substance can produce target organs damage. Repeated exposure to an
2 Ethyl chloride Page Number: 2 Section. First Aid Measures highly toxic material may produce general deterioration of health by an accumulation in one or many human organs. Eye Contact Skin Contact Serious Skin Contact Check for and remove any contact lenses. Immediately flush eyes with running water for at least 15 minutes, keeping eyelids open. Cold water may be used. Do not use an eye ointment. Seek medical attention. After contact with skin, wash immediately with plenty of water. Gently and thoroughly wash the contaminated skin with running water and non-abrasive soap. Be particularly careful to clean folds, crevices, creases and groin. Cover the irritated skin with an emollient. If irritation persists, seek medical attention. Wash contaminated clothing before reusing. Inhalation Allow the victim to rest in a well ventilated area. Seek immediate medical attention. Serious Inhalation Ingestion Serious Ingestion If fumes are still suspected to be present, the rescuer should wear an appropriate mask or a self-contained breathing apparatus. Evacuate the victim to a safe area as soon as possible. If the victim is breathing, check for unusual breath odors. Loosen tight clothing such as a collar, tie, belt or waistband. If breathing is difficult, administer oxygen. If the victim is not breathing, perform mouth-to-mouth resuscitation. Maintain an open airway. WARNING: It may be hazardous to the person providing aid to give mouth-to-mouth resuscitation when the inhaled material is toxic, infectious or corrosive. Seek immediate medical attention. Since the product is a gas and that it is mostly probable that it will be inhaled more than ingested, please consider first to look at the preventive measures in case of inhalation. Section 5. Fire and Explosion Data Flammability of the Product Auto-Ignition Temperature Flash Points Flammable Limits Products of Combustion Fire Hazards in Presence of Various Substances Flammable. 519 C (966.2 F) CLOSED CUP: -50 C (-58 F). OPEN CUP: -3 C (-5. F). LOWER: 3.6% UPPER: 15.% These products are carbon oxides (CO, CO2). Flammable in presence of open flames and sparks. Explosion Hazards in Presence of Various Substances Risks of explosion of the product in presence of mechanical impact: Risks of explosion of the product in presence of static discharge: Fire Fighting Media and Instructions Fire Hazards Explosion Hazards Toxic gas. Flammable gas. SMALL FIRE: Use DRY chemical powder. LARGE FIRE: Use water spray, fog or foam. Do not use water jet. Move containing vessels from fire area if without risk. Cool containing vessels with flooding quantities of water until well after fire is out. Cool containing vessels with water jet in order to prevent pressure build-up, autoignition or explosion. Do not extinguish a leaking gas flame unless leak can be stopped. Extinguish secondary fire. Handle damaged cylinders with extreme care. Use extinguishing media suitable for surrounding materials.
3 Ethyl chloride Page Number: 3 Section 6. Accidental Release Measures Small Spill Large Spill Try to stop the gaseous leak by taping the container with an appropriate material (tape, stretched plastic). Toxic gas. Flammable gas. Let evaporate. If possible, turn leaking container so that gas escapes rather than liquid. Do not touch spilled material. Do not direct water at spill or source. Use water spray curtain to divert vapor drift. Use water spray to reduce vapors. Prevent entry into sewers, basements or confined areas. Eliminate all ignition sources. Be careful that the product is not present at a concentration level above TLV. Check TLV on the MSDS and with local authorities. Section 7. Handling and Storage Precautions Storage Keep locked up Keep away from heat. Keep away from sources of ignition. Empty containers pose a fire risk, evaporate the residue under a fume hood. Ground all equipment containing material. Do not ingest. Do not breathe gas/fumes/ vapour/spray. Avoid contact with eyes In case of insufficient ventilation, wear suitable respiratory equipment If you feel unwell, seek medical attention and show the label when possible. Keep container tightly closed and in a well-ventilated place. Compressed gases should be stored in a separate safety storage cabinet or room. Section 8. Exposure Controls/Personal Protection Engineering Controls Ventilation is normally required when handling or using this product. Personal Protection Personal Protection in Case of a Large Spill Exposure Limits Splash goggles. Lab coat. Vapor respirator. Be sure to use an approved/certified respirator or equivalent. Gloves. Splash goggles. Full suit. Vapor respirator. Boots. Gloves. A self contained breathing apparatus should be used to avoid inhalation of the product. Suggested protective clothing might not be sufficient; consult a specialist BEFORE handling this product. TWA: 1000 (ppm) TWA: 2600 (mg/m 3 ) Consult local authorities for acceptable exposure limits. Section 9. Physical and Chemical Properties Physical state and appearance Gas. Odor Ethereal. Molecular Weight ph (1% soln/water) 6.51 g/mole Taste Color Burning. Colorless. Boiling Point 12.3 C (5.1 F) Melting Point C ( F) Critical Temperature Specific Gravity 0.9 (Water = 1) Vapor Pressure 106 mm of Hg (@ 20 C) Vapor Density 2.22 (Air = 1) Volatility Odor Threshold.2 ppm Water/Oil Dist. Coeff. Ionicity (in Water) Dispersion Properties
4 Ethyl chloride Page Number: Solubility Very slightly soluble in cold water. Section 10. Stability and Data Stability Instability Temperature Conditions of Instability Incompatibility with various substances Corrosivity The product is stable. Non-corrosive in presence of glass. Corrosivity Polymerization No. Section 11. Toxicological Information Routes of Entry Toxicity to Animals Chronic Effects on Humans Other Toxic Effects on Humans Toxicity to Animals Chronic Effects on Humans other Toxic Effects on Humans Eye contact. Inhalation. WARNING: THE LC50 VALUES HEREUNDER ARE ESTIMATED ON THE BASIS OF A -HOUR EXPOSURE. Acute toxicity of the gas (LC50): 80 ppm hour(s) [Rat]. The substance is toxic to blood, kidneys, lungs, the nervous system, liver, mucous membranes. Extremely hazardous in case of inhalation. Slightly hazardous in case of skin contact (irritant), of ingestion. Section 12. Ecological Information Ecotoxicity BOD5 and COD Products of Biodegradation Toxicity of the Products of Biodegradation the Products of Biodegradation Possibly hazardous short term degradation products are not likely. However, long term degradation products may arise. The products of degradation are more toxic.
5 Ethyl chloride Page Number: 5 Section 13. Disposal Considerations Waste Disposal Section 1. Transport Information DOT Classification Identification CLASS 2.1: Flammable gas. : Ethyl chloride : UN1037 PG: Special Provisions for Transport DOT 2 Section 15. Other Regulatory Information and Pictograms Federal and State Regulations California Proposition 65 Warnings Other Regulations California prop. 65: This product contains the following ingredients for which the State of California has found to cause cancer, birth defects or other reproductive harm, which would require a warning under the statute: Ethyl chloride California prop. 65: This product contains the following ingredients for which the State of California has found to cause cancer which would require a warning under the statute: Ethyl chloride Pennsylvania RTK: Ethyl chloride Massachusetts RTK: Ethyl chloride TSCA 8(b) inventory: Ethyl chloride SARA 313 toxic chemical notification and release reporting: Ethyl chloride CERCLA: Hazardous substances.: Ethyl chloride California prop. 65: This product contains the following ingredients for which the State of California has found to cause cancer which would require a warning under the statute: Ethyl chloride OSHA: Hazardous by definition of Hazard Communication Standard (29 CFR ). Other Classifications WHMIS (Canada) DSCL (EEC) CLASS A: Compressed gas. CLASS B-1: Flammable gas. R26- Very toxic by inhalation. R1- Risk of serious damage to eyes. HMIS (U.S.A.) Health Hazard Fire Hazard Personal Protection 1 0 h National Fire Protection Association (U.S.A.) Health 1 0 Flammability Specific hazard WHMIS (Canada) DSCL (Europe)
6 Ethyl chloride Page Number: 6 TDG (Canada) 2 ADR (Europe) 2 Protective Equipment Gloves. Lab coat. Vapor respirator. Be sure to use an approved/certified respirator or equivalent. Wear appropriate respirator when ventilation is inadequate. Splash goggles. Section 16. Other Information MSDS Code References Other Special Considerations E3316 Validated by Sonia Owen on 8/11/2006. Verified by Sonia Owen. Printed 9/12/2006. CALL (310) Notice to Reader All chemicals may pose unknown hazards and should be used with caution. This Material Safety Data Sheet (MSDS) applies only to the material as packaged. If this product is combined with other materials, deteriorates, or becomes contaminated, it may pose hazards not mentioned in this MSDS. It shall be the user's responsibility to develop proper methods of handling and personal protection based on the actual conditions of use. While this MSDS is based on technical data judged to be reliable, Spectrum Quality Products, Inc. assumes no responsibility for the completeness or accuracy of the information contained herein.
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