STERI-PEROX Sterile Pharmaceutical Clean Room Formula Sterile Hydrogen Peroxide at 3% and 6%
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1 1 STERI-PEROX Sterile Pharmaceutical Clean Room Formula Sterile Hydrogen Peroxide at 3% and 6% MATERIAL SAFETY DATA SHEET COMPLIES WITH OSHA HAZARD COMMUNICATION STANDARD 29 CFR (Complies with Commission Directive 91/155/EEC amended by 2001/58/EC)
2 2 STERI-PEROX MATERIAL SAFETY DATA SHEET COMPLIES WITH OSHA HAZARD COMMUNICATION STANDARD 29 CFR (Complies with Commission Directive 91/155/EEC amended by 2001/58/EC) I. Identification of Substance: Product Name: STERI-PEROX Sterile MSDS #: SP Description: Hydrogen peroxide and water formulated to 3% and 6% MSDS Information Manufacturer Information Emergency Telephone Information Date Prepared: November 6, 2002 Notify your Supervisor Prepared by: 15 Lee Boulevard Emergencies Chemtrec (800) Art Vellutato, Jr. Malvern, PA hour service V.P. Technical Support Operations TEL: (610) Reviewed by: Effective Date: November 6, 2002 Art Vellutato, Sr. Date Supercedes: 12/01/97 Technical Director II. Composition/Data on Components: Description: Brown Tinge Liquid with slightly pungent, irritating odor. Ingredients Concentration Cas # Hydrogen Peroxide 3.00% CAS# OR Hydrogen Peroxide 6.00% CAS# *****CHECK PERCENTAGE ON CONTAINER Other Ingredients: Purified Water CAS# None of the ingredients in this product are on the IARC, NTP, or OSHA carcinogen list. HIMIS RATING HEALTH 2 REACTIVITY 0 FLAMMABILITY 0 PERSONAL B HAZARD RATINGS: 0 = Minimal 1 = Slight 2 = Moderate 3 = Serious 4 = Extreme A = Safety Glasses B = Safety Glasses & Gloves
3 3 III. Hazards Identification: May cause irritation of the skin, eyes, or mucous membranes. Splashes in the eye can cause severe eye damage with ulceration of the cornea, and may cause eye damage. Skin exposure can result in irritation with discomfort or rash, bleaching of the skin and hair. Prolonged exposure may result in skin irritation., Inhalation of 3% formulated vapors can cause irritation of the nose and throat and possible irritation of the upper respiratory passages or non-specific discomfort such as nausea. Inhalation of a 6% formulation may cause irritation of the nose and throat and possible difficulty in breathing, shortness of breath. Ingestion at 3% and 6% may cause irritation of the gastrointestinal trace with upper abdominal pain, "heartburn", nausea, vomiting, and diarrhea, "coffee grounds" vomitus and "black tarry" stools may occur as a result of gastrointestinal tract bleeding. Gross overexposure include red blood cell destruction, or gas embolism. Gross over exposure by ingestion may be fatal. FOR EXTERNAL USE ONLY. Ingredients Concentration Worker Exposure Limit Hydrogen Peroxide 3.00% CAS# OR Hydrogen Peroxide 6.00% CAS# *****CHECK PERCENTAGE ON CONTAINER IV. First Aid Measures: EYE CONTACT: Immediately flush eyes with plenty of water for 15 minutes, Call a Physician. SKIN CONTACT: Remove contaminated clothing. Wash area with water for 15 minutes. If irritation persists Call of Physician. INGESTION: Do not induce vomiting, Give large quantities of water, Contact a Physician Immediately. INHALATION: If breathing problems develop, remove to fresh air. Call a Physician. Note to Physician: If swallowed, large amounts of oxygen may be released quickly. The distention of the stomach or esophagus may be injurious. Insertion of a gastric tube may be advisable. V. Firefighting Measures: Will not burn, but decomposition, caused by heat, releases flammable vapors. Strong Oxidizer, contact with clothing or combustibles may cause fire. Contact with organic liquids or vapors may cause immediate fire or explosion, especially if heated. To Extinguish: USE WATER ONLY. In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full facepiece operated in the pressure demand or other positive pressure mode.
4 4 VI. Accidental Release Measures: Spill Procedures: Absorb and containerize. Wash residual down with water and drain to approved chemical sewer or waste water treatment system. Contact the sanitary treatment facility in advance to assure ability to process wash-down material. Wash Disposal: Dispose of in accordance with all applicable federal, state and local regulations VII. Handling and Storage: STORAGE & HANDLING PRECAUTIONS: KEEP OUT OF REACH OF CHILDREN. Do not contaminate water, food, or feed. Do not reuse empty containers. Keep containers clean and closed. Store in a cool, well-ventilated dark area. Protect from freezing. Isolate from incompatible substances. Protect container from physical damage. Containers of this material may be hazardous when empty since they retain product residues (vapors, liquid); observe all warnings and precautions listed for the product. VIII. Exposure Control and Personal Protection: Hygienic Practices: Wear Safety Chemical Splash Goggles. Wear gloves. Wear appropriate protective garments not affected by hydrogen peroxide. Improper clothing can result in permeation and possible increased fire hazards. Use a respirator, NIOSH/MSHA approved where possibility of airborne solution is possible. Engineering Controls: Use general ventilation to minimize exposure to vapor or mist. Work Practices: Avoid eye and skin contact and inhalation of vapor or mist. Airborne Exposure Limits: -OSHA Permissible Exposure Limit (PEL): 1 ppm (TWA). -ACGIH Threshold Limit Value (TLV): 1 ppm (TWA), A3: Animal carcinogen. Ventilation System: A system of local and/or general exhaust is recommended to keep employee exposures below the Airborne Exposure Limits. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source, preventing dispersion of it into the general work area. Personal Respirators (NIOSH Approved): Not expected to require personal respirator usage. If the exposure limit is exceeded, wear a supplied air, fullfacepiece respirator, airlined hood, or full-facepiece self-contained breathing apparatus. This substance has unknown warning properties. Skin Protection: Wear protective gloves and clean body-covering clothing. Eye Protection:
5 5 Use chemical safety goggles and/or a full face shield where splashing is possible. Maintain eye wash fountain and quick-drench facilities in work area. KEEP OUT OF REACH OF CHILDREN. RESPIRATORY PROTECTION: General ventilation is normally adequate. Protect breathing system with an appropriate respirator if spraying causes exposure to mists. GLOVES: Required for exposure to the concentrate when diluting or for long exposures to end-use dilutions. Persons sensitive to cleaning chemicals should always wear gloves. EYE PROTECTION: Use Safety Glasses when diluting concentrates or when splashing or spraying of diluted product into the eyes is likely. OTHER PROTECTIVE CLOTHING OR EQUIPMENT: Not normally necessary for routine handling. WORK/HYGIENE PRACTICES: Wash hands after using. Do not get into eyes, on skin, or clothing. May be harmful if swallowed. Protect food and drink from contamination by product. VENTILATION: Local Exhaust: Normally Sufficient Mechanical (General): Not Normally Needed NOTE: The information herein is presented in good faith and believed to be accurate as of the effective date shown above. However, no warranty, expressed or implied is given. It is the responsibility of the user to comply with all Federal, State and Local laws and regulations. IX. Physical and Chemical Properties: Boiling Point: 103 o F(39 o C) Decomposes: 00 o C Solubility in water: Complete Appearance: Clear, colorless solution. Odor: Odorless. Solubility: Infinitely soluble. Specific Gravity: ca. 1.0 ph: No information found. % Volatiles by 21C (70F): 100 Boiling Point: ca. 100C (ca. 212F) Melting Point: ca. 0C (ca. 32F) Vapor Density (Air=1): No information found. Vapor Pressure (mm Hg): No information found. Evaporation Rate (BuAc=1): No information found. (FOR OTHER SPECIFICATIONS SEE Certificate of Analysis)
6 6 X. Stability and Reactivity: Unstable with heat or contamination. Liberation of Oxygen Gas. Use extreme caution when attempting any reactions because of fire and explosion potential. Conduct initial experiments in small scale and protect personnel appropriately as reactions are unpredictable and may be delayed. Stable under normal use and storage conditions. Strong oxidizing agent. Reacts with other chemicals. Prolonged contact with metals may cause pitting or decoloration. SEEK PROFESSIONAL ASSISTANCE FOR REACTIVITY. XI. Toxicological Information: For Hydrogen peroxide: Investigated as a tumorigen and mutagen. No LD50/LC50 information found relating to normal routes of occupational exposure. Cancer Lists NTP Carcinogen Ingredient Known Anticipated IARC Category Hydrogen Peroxide ( ) No No 3 Water ( ) No No None XII. Ecological Information: Consult local authorities pertaining to the release of material to the environment. XIII. Disposal Considerations: WASTE DISPOSAL METHOD: Dispose of product by using in accordance with label directions or in accordance with local, state, and federal regulations. This product is NOT considered a RCRA Hazardous Waste as identified in Federal Regulations 40 CFR 261. XIV. Transport Information: U.S. DOT Hazard Class: U.S. DOT Proper Shipper Name: Hydrogen Peroxide at 3% or 6%. Not Restricted per 49CRF (c)(12)(iv). XV. Regulations: PLEASE CONSULT YOUR STATE AND LOCAL AUTHORITY FOR INGREDIENTS LISTED AS PERTAINING TO REPORTING REQUIREMENTS FOR HAZARDOUS SUBSTANCE LIST. No special regulation other than transportation and disposal (see section VII and section IX). Conform to Federal, State and Local Regulations for disposal. Follow usage instructions on container.
7 7 XVI. Other Information: NOTE: The information herein is presented in good faith and believed to be accurate as of the effective date shown above. However, no warranty, expressed or implied is given. It is the responsibility of the user to comply with all Federal, State and Local laws and regulations.
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