MATERIAL SAFETY DATA SHEET

Transcription

1 MATERIAL SAFETY DATA SHEET OXIQUIM request the client or who receives the present Material Safety Data Sheet to read carefully so that he knows and understand the dangers associated with the product. It is convenient that the reader consults reference works or experts in the product in order to understand and to use the information contained in the present MSDS. Assure the correct manipulation of the substance, you should: 1.- Communicate yours employees, agents and contractors or any other person that can use this material, the information contained in this as well as any other relative information to the risks and measures of security. 2.- Give a copy to each one of their clients for this product, and 3.- Provide this same information to each one of their clients for this product, besides requesting to their clients that notify to their employees, clients and other users of the product with this information. MATERIAL SAFETY DATA SHEET Revision date: January 2007 Section 1: Identification of the product and of the supplier Name of the product : BICLOR 20 Code of the product : Supplier : OXIQUIM Limache 3117, Viña del Mar, Chile. Phone : Fax: Phones Emergency : Quilicura: Coronel: Cell Phone Emergency 1: Cell Phone Emergency 2: Cituc (Chemical Emergency): Section 2: Composición/Ingredientes Name chemical (IUPAC) : Dioxide of chlorine Chemical formula : Cl O2 Synonyms : Alcida; Peroxide of chlorine; Oxide of chlorine. Chemical family : Oxides of chlorine. No. CA : No. GNU : 3093 BICLOR20(ingles) Página 1 de 6

2 Section 3: Identification of risks Marks in label : CORROSIVE Classification risks of the chemical product: Health: 2 Flammability: 1 Reactivity: 2 a) Dangers for the health of people: Irritates the skin and the mucous ones. Can cause damages to the breathing system in the event of a repeated exposure. Effects of a sharp overexposure (for once): Inhalation : Can cause irritation in the breathing roads and damage in the lungs, if the exposure is repeated. Contact with the skin : When being prolonged the exposure it can cause chemical burns. Contact with the eyes : Can have damage to the cornea in the event of a direct contact. Ingestion : Can have irritation and burns in the digestive tract, including stomach and bowels. Can have nauseas and vomits. Effects of a chronic overexposure (long term): When repeating the exposure damage it can take place in the lungs. Problems like the asthma and other breathing illnesses are increased. Doctors that will be increased with the exposure to the product condition: people with chronic illnesses to the lungs should not be exposed to the product. b) Dangers for the environment: Nocive for the aquatic life when entering in natural waters. c) Special Dangers of the product: The biggest danger in the product is given by its corrosiveness. Section 4: Measures first aids In the event of accidental contact with the product, to come from agreement with: Inhalation : Move away the person outdoors. Help to the breathing. If it is necessary, a doctor consult, because it can have slowed effects. Contact with the skin : Wash the part affected with great quantity of water current. If the irritation persists, a doctor consult. Contact with the eyes : Wash immediately with big quantities of water current. To the brevity a doctor consults. Ingestion : Give to drink the one affected of 2 to 4 glasses of water or milk. Don't induce the vomits. Immediately a doctor consult. Notes for the medical dealer: a specific antidote doesn't exist. Be about agreement with the present symptoms. BICLOR20(ingles) Página 2 de 6

3 Section 5: Measures fight against the fire Extinction agents : The product is not flammable. Special procedures to combat the fire: Refrigerate the exposed containers to fire. If the containers warm, they can remove vapors that increase the pressure in the same. Personal Protection to attack the fire: is not needed, product is not flammable. Section 6: Measures to control spills or flights Emergency measures to take if there is spill of the material: Makes pool to control the spill and to stop enter of the product in sewers and courses of water. Pick up the product in drums of plastic for their ulterior disposition. Team of personal Protection to attack the Emergency: Uses suit of protection chemical type B, taking the caution of sealing the contact between suit and boots. Protect the breathing roads with breathing trumpet and filters for chlorine. Cautions to take to avoid damages to the atmosphere: it Avoids the entrance of the product in drainages and courses of water. Methods of cleaning : The last residuals can leave to drainages after an intense dilution. Method of elimination of waste: Reduces the waste with such agents as bisulfitos or solutions of ferrous salt. Delution whit water the final product will be brackish water. Section 7: Manipulation and Storage Technical recommendations: Use the product in ventilated places. The vapors of product attack the wood of the structures. Cautions to take : Will use the containers in another product, assure a good laundry before. Appearances of dioxide can still react with violence with other products. Recommendations have more than enough sure, specific manipulation: Only takes out of the container the quantity that will use in the day. Always use the recommended personal protection. Storage conditions: Maintains the product indoors and far from reducers agents. If the containers warm, scent them to liberate the products of decomposition. Recommended packings and not appropriate: The polyethylene drums are adapted. It is not recommended the metallic drums, unless they are protected inside with some plastic. BICLOR20(ingles) Página 3 de 6

4 Section 8: Control environmental exposición/protección Measures to reduce the exposure possibility: always use the recommended personal protection. Only take out of the container the necessary product for the immediate use. Assure good ventilation of the work place. Parameters for control: permissible Limits: for the dioxide of chlorine gas the limits are: Pondered: 0,08 ppm or 0,22 mg/m3 Absolute: 0,83 mg/m3. Breathing protection : Use breathing aparatus with filters for chlorine. Protection gloves : PVC or neopreno of long fist. Protection of the view : Use glasses of chemical protection against possible splashes. Other protection teams: Use protection PVC to protect the body, and neopreno boots. Ventilation : Assure good ventilation in the place of manipulation of the product. Section 9: Physical and chemical Properties Physical state : Liquid. Appearance and odor : Yellow greenish, with characteristic odor. Concentration : 20%. ph : Not date available. Temperature of decomposition: Not date available. Inflammation point : Not flammable. Autoignición temperature: Not flammable. Explosive properties : Can explode in contact with reducers and strong bases, such as hidróxide of potassium. Fire dangers or explosion: he doesn't have, to be a watery solution. Pressure of vapor at 20ºC: Not date available. Density of vapor : Not date available. Density at 20ºC : 1,35-1,4 g/cc. Solubility in water and other solvents: Completely soluble in water. Section 10: Stability and reactivity Stability : Stable to normal temperatures. Condition that they should be avoided: Avoids to heat the containers, for how much accelerates the decomposition. Incompatibility (materials that should be avoided): Avoids contamination heavy metals, agents reducers, compound organic, ether, ammonia and acids. Dangerous products of decomposition: vapors clorine take place. Dangerous products of combustion: is not applicable. Dangerous polymerization: won't take place. BICLOR20(ingles) Página 4 de 6

5 Section 11: Toxicological Information Sharp toxicity : Irritating strong of the skin and mucous. Chronic toxicity or of long term: Increases the illnesses lung preexistentes. Local effects : Irritating of the skin and the mucous ones. Sensitization : Not available information. Section 12: Ecological Information Uncertainty : In the medium term breaks down. Persistencia/Degradabilidad: Degradable in medium term until chlorides and oxygen. Bio-accumulation : Date not available. Effects on the atmosphere: Is dangerous still in small concentrations for the aquatic life. Section 13: Considerations have more than enough final disposition Method of elimination of the product in the residuals: Reduces the waste with such agents as bisulfitos or solutions of ferrous salt. Delution whit water. The final product will be brackish water. Elimination of polluted envases/embalajes: They can be correspondents to drains, since the residuals will break down in the medium term. Section 14: Information on it transports N Ch 2190, marks : CORROSIVE No. GNU : Section 15: Effective Norms Applicable international norms: IMO / NU: Class 8 / Applicable national norms: N Ch 382; NCh 2190; D.S It marks in label : CORROSIVE BICLOR20(ingles) Página 5 de 6

6 Section 16: Other informations There is not. The data consigned in this Material Safety Data Sheet were obtained of reliable sources. However. The opinions expressed in this form are those of qualified professionals of OXIQUIM. The information that surrenders in this paper is at the moment the acquaintance on the matter. Considering that the use of this information and of the products it is outside of the control of OXIQUIM., the company doesn't assume responsibility some for this concept. To determine the conditions of sure for use the product is the user's obligation. JYG / BICLOR20(ingles) Página 6 de 6