AAP AHS CONDITIONER RED Version 1.0 Revision Date 29/11/2016 Print Date 29/11/2016

Transcription

1 SECTION 1. PRODUCT AND COMPANY IDENTIFICATION Material name Material number Supplier's details (Australia) Company Address Telephone : : V23001 : VELOCITY VEHICLE CARE (A.B.N ) : Tottenham Pde, Tottenham, VIC, Australia : (9am -5 pm, Mon-Fri) Supplier's details (New Zealand) Company : VELOCITY VEHICLE CARE NZ Address : 3 London Street, Hamilton Telephone : Local (9am -5 pm, Mon-Fri) Emergency telephone numbers (24 Hours) Australia: Poison Information Centre Tel New Zealand (If calling from outside of NZ) NZ Poisons Centre : Recommended use of the chemical and restrictions on use Recommended use : Vehicle care carwash detergent SECTION 2. HAZARDS IDENTIFICATION Emergency Overview Appearance Colour Odour liquid dark red slight Classification Classification according to the Globally Harmonised System for the Classification and Labelling of Chemicals (GHS), as adopted for industrial chemicals in Australia. This product is Hazardous according to the Hazardous Substances (Classification) Regulations GHS HSNO Skin corrosion : Category 1B 8.2B Serious Eye Damage : Category 1 8.3A Page: 1 of 11

2 GHS label elements Hazard pictograms Signal word Hazard statements : Danger : H314 Causes severe skin burns and eye damage. Precautionary statements Prevention: P261 Avoid breathing dust/ fume/ gas/ mist/ vapours/ spray. P264 Wash skin thoroughly after handling. P280 Wear protective gloves/ protective clothing/ eye protection/ face protection. P285 In case of inadequate ventilation wear respiratory protection. Response: P301 + P330 + P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. P303 + P361 + P353 IF ON SKIN (or hair): Remove/ Take off immediately all contaminated clothing. Rinse skin with water/ shower. P304 + P340 + P310 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. Immediately call a POISON CENTER or doctor/ physician. P305 + P351 + P338 + P310 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER/doctor. P363 Wash contaminated clothing before reuse. Storage: P405 Store locked up. Disposal: Dispose of contents/container in accordance with local regulation. Page: 2 of 11

3 Australian Dangerous Goods Code and New Zealand NZS 5433:2007: UN2586, ALKYLSULPHONIC ACIDS, LIQUID, 8, III.. SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS Substance / Mixture : Mixture Hazardous components Chemical name CAS-No. Concentration [%] Benzenesulfonic acid, C10-16-alkyl derivs >= 10 - < 20 Alcohols, C10-16, ethoxylated, sulfates, >= 1 - < 5 sodium salts (2-methoxymethylethoxy)propanol (Mixture >= 1 - < 5 of isomers) Amines, tallow alkyl, ethoxylated >= 1 - < 5 ethanol >= 1 - < 5 citric acid >= 1 - < 5 The exact percentages of disclosed substances are withheld as trade secrets SECTION 4. FIRST AID MEASURES General advice If inhaled : Move out of dangerous area. Consult a physician. Show this safety data sheet to the doctor in attendance. Do not leave the victim unattended. : Move to fresh air. If unconscious place in recovery position and seek medical advice. If symptoms persist, call a physician. In case of skin contact In case of eye contact If swallowed : Immediate medical treatment is necessary as untreated wounds from corrosion of the skin heal slowly and with difficulty. If on skin, rinse well with water. If on clothes, remove clothes : Small amounts splashed into eyes can cause irreversible tissue damage and blindness. In the case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Continue rinsing eyes during transport to hospital. Remove contact lenses. Protect unharmed eye. Keep eye wide open while rinsing. If eye irritation persists, consult a specialist. : Keep respiratory tract clear. Do NOT induce vomiting. Do not give milk or alcoholic beverages. Never give anything by mouth to an unconscious person. Page: 3 of 11

4 If symptoms persist, call a physician. Take victim immediately to hospital. SECTION 5. FIREFIGHTING MEASURES Suitable extinguishing media Unsuitable extinguishing media Specific hazards during firefighting : Dry chemical Alcohol-resistant Foam Carbon dioxide (CO2) Water spray : High volume water jet : Do not allow run-off from fire fighting to enter drains or water courses. Hazardous combustion products Specific extinguishing methods : Carbon dioxide (CO2) Carbon monoxide Smoke Nitrogen oxides (NOx) : Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Further information : Collect contaminated fire extinguishing water separately. This must not be discharged into drains. Fire residues and contaminated fire extinguishing water must be disposed of in accordance with local regulations. For safety reasons in case of fire, cans should be stored separately in closed containments. Use a water spray to cool fully closed containers. Special protective equipment : Wear self-contained breathing apparatus for firefighting if for firefighters necessary. SECTION 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures Environmental precautions : Use appropriate personal protective equipment. Ensure adequate ventilation. : Prevent product from entering drains. Prevent further leakage or spillage if safe to do so. If the product contaminates rivers and lakes or drains inform respective authorities. Page: 4 of 11

5 Methods and materials for containment and cleaning up : Contain spillage, Neutralize with chalk, alkali solution or ammonia.and then collect with non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite) and place in container for disposal according to local / national regulations (see section 13). SECTION 7. HANDLING AND STORAGE Advice on safe handling Conditions for safe storage Materials to avoid : Avoid formation of aerosol. Do not breathe vapours/dust. Avoid contact with skin and eyes. For personal protection see section 8. Smoking, eating and drinking should be prohibited in the application area. Provide sufficient air exchange and/or exhaust in work rooms. To avoid spills during handling keep bottle on a metal tray. Dispose of rinse water in accordance with local and national regulations. : Keep container tightly closed in a dry and well-ventilated place. Containers which are opened must be carefully resealed and kept upright to prevent leakage. Observe label precautions. Electrical installations / working materials must comply with the technological safety standards. : Keep away from oxidizing agents and strongly acid or alkaline materials. SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Components with workplace control parameters Components (2- methoxymethylethoxy)propanol (Mixture of isomers) aka Dipropylene glycol methyl ether CAS- No. Value type (Form of exposure) TWA TWA STEL Control parameters / Permissible concentration Basis 50 ppm 308 mg/m 3 AUS SWA 100 ppm 606 mg/m3 NZ WES 150 ppm 909 mg/m 3 NZ WES Page: 5 of 11

6 Components CAS-No. Value type (Form of exposure) Ethyl alcohol TWA TWA Control Basis parameters / Permissible concentration 1000 ppm 1880 mg/m 3 AUS SWA 1000 ppm NZ WES 1880 mg/m 3 sulphuric acid TWA 1 mg/m 3 AUS SWA STEL 3 mg/m 3 AUS SWA TWA 1 mg/m 3 NZ WES Engineering measures : effective ventilation in all processing areas Personal protective equipment Respiratory protection : In the case of vapour formation use a respirator with an approved filter. Hand protection Remarks Eye protection Skin and body protection Protective measures Hygiene measures : The suitability for a specific workplace should be discussed with the producers of the protective gloves. : Eye wash bottle with pure water Tightly fitting safety goggles Wear face-shield and protective suit for abnormal processing problems. : Impervious clothing Choose body protection according to the amount and concentration of the dangerous substance at the work place. : Wear suitable protective equipment. Avoid contact with skin. When using do not eat, drink or smoke. : When using do not eat or drink. When using do not smoke. Wash hands before breaks and at the end of workday. SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES Page: 6 of 11

7 Appearance : liquid Colour : dark red Odour : slight Odour Threshold : ph : <1.1 Melting point/freezing point : Boiling point : > 100 C Flash point : >100 C Evaporation rate : Upper explosion limit : Lower explosion limit : Vapour pressure : Relative vapour density : Relative density : Density : g/cm 3 Solubility(ies) Water solubility : Soluble Solubility in other solvents : Not applicable Partition coefficient: n- octanol/water Auto-ignition temperature Thermal decomposition : : not determined : SECTION 10. STABILITY AND REACTIVITY Reactivity Chemical stability Possibility of hazardous reactions Conditions to avoid Incompatible materials Hazardous decomposition products : Stable : Stable under normal conditions. : No decomposition if stored and applied as directed. : no data available. : Oxidizing agents : Sulfur dioxide Carbon dioxide (CO2) Carbon monoxide Metal oxides SECTION 11. TOXICOLOGICAL INFORMATION Potential Health Effects Page: 7 of 11

8 Acute toxicity Acute oral toxicity Acute inhalation toxicity Acute dermal toxicity : Acute toxicity estimate : 3,014 mg/kg Method: Calculation method : Acute toxicity estimate : > 40 mg/l Exposure time: 4 h Test atmosphere: vapour Method: Calculation method : Acute toxicity estimate : > 5,000 mg/kg Method: Calculation method Components: ethanol: Acute oral toxicity Acute inhalation toxicity citric acid: Acute oral toxicity Acute dermal toxicity : LD50 Oral Rat: 7,060 mg/kg : LC50 Rat: mg/l Exposure time: 4 h : LD50 Oral Rat: 5,400 mg/kg : LD50 Dermal Rabbit: > 2,000 mg/kg Skin corrosion/irritation Remarks: Extremely corrosive and destructive to tissue. Serious eye damage/eye irritation Remarks: May cause irreversible eye damage. Respiratory or skin sensitisation Germ cell mutagenicity Carcinogenicity Reproductive toxicity Benzenesulfonic acid, C10-16-alkyl derivs.: Page: 8 of 11

9 Alcohols, C10-16, ethoxylated, sulfates, sodium salts: (2-methoxymethylethoxy)propanol (Mixture of isomers): Amines, tallow alkyl, ethoxylated: ethanol: citric acid: STOT - single exposure STOT - repeated exposure Aspiration toxicity Further information Remarks: no data available SECTION 12. ECOLOGICAL INFORMATION Ecotoxicity Persistence and degradability Bioaccumulative potential Partition coefficient: n- octanol/water Mobility in soil Other adverse effects Additional ecological : Remarks: :. SECTION 13. DISPOSAL CONSIDERATIONS Disposal methods Waste from residues : The product should not be allowed to enter drains, water courses or the soil. Do not contaminate ponds, waterways or ditches with chemical or used container. Dispose of in accordance with local regulations. Page: 9 of 11

10 Contaminated packaging : Empty remaining contents. Dispose of as unused product. Do not re-use empty containers. Do not burn, or use a cutting torch on, the empty drum. SECTION 14. TRANSPORT INFORMATION Transportation Regulation: Australian Dangerous Goods Code and New Zealand NZS 5433:2007: UN2586, ALKYLSULPHONIC ACIDS, LIQUID, 8, III Transportation Regulation: IMDG (Vessel): UN2586, ALKYLSULPHONIC ACIDS, LIQUID, 8, III Transportation Regulation: IATA (Cargo Air): UN2586, ALKYLSULPHONIC ACIDS, LIQUID, 8, III Transportation Regulation: IATA (Passenger Air): UN2586, ALKYLSULPHONIC ACIDS, LIQUID, 8, III The product as delivered to the customer conforms to packaging requirements for shipment by road under US Department of Transportation (DOT) regulations. Additional transportation classifications noted above are for reference only, and not a certification or warranty of the suitability of the packaging for shipment under these alternative transport regulations. SECTION 15. REGULATORY INFORMATION The components of this product are reported in the following inventories: USA Canada Australia New Zealand On TSCA Inventory This product contains the following components listed on the Canadian NDSL. All other components are on the Canadian DSL. on AICS Inventory on NZIoC Group Standard Approval: Cleaning Products (Corrosive) Group Standard HSR For information on the country notification status for other regions please contact the manufacturer s regulatory group. Page: 10 of 11

11 AAP SAFETY DATA SHEET AHS CONDITIONER RED SECTION 16. OTHER INFORMATION We believe the statements, technical information and recommendations contained herein are reliable, but they are given without warranty or guarantee of any kind. The information in this document applies to this specific material as supplied. It may not be valid for this material if it is used in combination with any other materials. Users should make their own investigations to determine the suitability and applicability of the information for their particular purposes. This SDS has been prepared by the Compliance Services organization supporting this manufacturer, supplier or distributor. Page: 11 of 11