The following information is based on the characteristics and toxicological testings of this product.

Transcription

1 LG Chem Material Safety Data Sheet LGflex BET SECTION 1 CHEMICAL PRODUCT AND COMPANY IDENTIFICATION MANUFACTURER : Acrylates/Plasticizers Division of LG Twin Towers 20, Yeouido-dong, Yeongdeungpo-gu, Seoul, Korea Telephone Number : Plant location: Plasticizer Team Ulsan plant, 388 Mangyang-ri, Onyang-myon, Ulju-gun, Ulsan, Korea Telephone Number : TRADE NAMES/SYNONYMS : LGflex BET CHEMICAL FAMILY : Esters CREATION DATE: April 9, 2001 REVISION DATE: Oct. 25, 2007 SECTION 2 COMPOSITION, INFORMATION ON INGREDIENTS COMPONENT(CAS Numbers) CHEMICAL NAME CAS No. WEIGHT % Hexanoic acid, 2-ethyl, mixed triesters with % benzoic acid and trimethylopropane SECTION 3 HAZARDS IDENTIFICATION The following information is based on the characteristics and toxicological testings of this product. NFPA RATINGS (SCALE 0-4): Health 1; Flammability 1; Reactivity 0 (0-Least, 1-Slight, 2-Moderate, 3-High, 4-Extreme) EMERGENCY OVERVIEW COLOR: slightly yellowish liquid. ODOR: faint odor. Keep container tightly closed. Wash thoroughly after handling. Use only with adequate ventilation. POTENTIAL HEALTH EFFECTS INHALATION SHORT TERM EXPOSURE: Expected to be low hazard for recommended handling. SKIN CONTACT SHORT TERM EXPOSURE: Non-irritant. LONG TERM EXPOSURE: Not adverse chronic effects expected. EYE CONTACT Page1

2 SHORT TERM EXPOSURE: Non-irritant. INGESTION SHORT TERM EXPOSURE: This product is not toxic. CARCINOGEN STATUS: No components of this product are listed by IARC NTP, ACGIH or OSHA as carcinogens. SECTION 4 FIRST AID MEASURES INHALATION: If symptomatic, remove from exposure area to fresh air immediately and keep a rest. Get medical attention immediately. SKIN CONTACT: Flush with large amounts of water and soap. If irritation develops, get medical attention. EYE CONTACT: Flush eyes with large amounts of water until no evidence of chemicals remains. If irritation persists, get medical attention. INGESTION: No specific first aid measures are required because this material is not expected to be harmful if swallowed. Do not induce vomiting without medical advice. Give the person one or two glasses of water and get medical advice. Do not give anything by mouth to an unconscious person. SECTION 5 FIRE FIGHTING MEASURES GENERAL HAZARD: Low hazard. Liquid may burn upon heating to temperature at or above the flash point. FIRE FIGHTING: Use water spray to cool fire exposed surfaces and to protect personnel. Isolate "fuel" supply from fire. Use foam, dry chemical, or water spray to extinguish fire. FLASH POINT: 446 (230 ) (COC) AUTOIGNITION TEMPERATURE : (454 ) (ASTM D 2155) LOWER/UPPER FLAMMABLE LIMIT: N/A FLAMMABILITY CLASS (OSHA): Not applicable. HAZARDOUS COMBUSTION PRODUCTS: Thermal decomposition products may include carbon oxides. SECTION 6 ACCIDENTAL RELEASE MEASURES OCCUPATIONAL RELEASE Stop leak if you can do it without risk. Small spills: Absorb with sand or other non-combustible material and place into appropriate container for disposal. Keep unnecessary people away, isolate hazard area and deny entry. Page2

3 SECTION 7 HANDLING AND STORAGE Keep container closed. Avoid breathing mist. Avoid contact with eyes, skin and clothing. Wash thoroughly after handling. Handle and open containers with care. Store in a cool, well ventilated place away from incompatible materials. Do Not handle or store near an open flame, heat or other sources of ignition. Protect material from direct sunlight. SECTION 8 EXPOSURE CONTROLS, PERSONAL PROTECTION EXPOSURE LIMITS: No occupational exposure limit established. EXPOSURE CONTROLS: Ventilation should be provided to control worker exposures and prevent health risk VENTILATION: Whenever possible, engineering controls should be used to minimize the need for personal protective equipment. PERSONAL PROTECTION: For open systems where contact is likely, wear safty glasses with side shield, long sleeves, and chemical resistant gloves. Where overexposure by inhalation may occur, an approved respiratory may be required. SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES APPEARANCE AND ODOR : slightly yellowish liquid with faint odor BOILING POINT: (346.3 ) FREEZING POINT: (-41 ) VAPOR PRESSURE: < (37.8 ) VAPOR DENSITY (air=1): N/A SPECIFIC GRAVITY (water=1): 68 (20 ) VOLATILITY: < 0.1% (Korean Standard Method ) WATER SOLUBILITY: insoluble PH: N/A ODOR THRESHOLD: N/A EVAPORATION RATE: N/A VISCOSITY: (20 ) SOLVENT SOLUBILITY: Soluble: alcohol, acetone, ether. SECTION 10 STABILITY AND RECTIVITY REACTIVITY: Stable at normal temperatures and pressure. HAZARDOUS POLYMERAIZATION: Will not occur. CONDITIONS TO AVOID: None MATERIALS TO AVOID: Oxidizing agent, High temperature, Open flames. Page3

4 HAZARDOUS DECOMPOSITION PRODUCTS: None. SECTION 11 TOXICOLOGICAL INFORMATION The following toxicological information is based on the animal testing data for this product. ACUTE ORAL TOXICITY - LD50: > 2,000mg/kg b.w. ACUTE SKIN IRRITATION/CORROSION: Non-irritant. ACUTE EYE IRRITATION/CORROSION: Non-irritant. GENOTOXICITY - Ames test: Negative. - Chromosomal aberration test (CHL) in vitro : Negative. - Mouse micronuclei test in vivo : Negative 28 Days Repeated Dose Oral Toxicity - No Observed Adverse Effect Level (NOAEL) 1,000 mg/kg/day (female), 500mg/kg/day (male) ESTROGENICITY : This product is considered to be non-estrogenic substance, in the immature rat. SECTION 12 ECOLOGICAL INFORMATION ACUTE AQUATIC TOXICITY: N/A ORGANIC READILY DEGRADABILITY (28 days): 18% (by BOD) (OECD test guideline No. 301C) BIOACCUMULATION: N/A Log Pow: 3.99 SECTION 13 DISPOSAL CONSIDERATIONS Dispose in accordance with all applicable regulations. Containers that cannot be cleaned should be disposed of in the same manner as the contents. SECTION 14 TRANSPORT INFORMATION Not regulated. SECTION 15 REGULATORY INFORMATION TSCA: not regulated. CERCLA: Article 103(40 CFR 302.1): not regulated. SARA: Article 302(40 CFR ): not regulated. Page4

5 SARA: Article 304(40 CFR ): not regulated. SARA: Article 313(40 CFR ): not regulated. OSHA: 29 CFR : not regulated. CALIFORNIA proposition 65: not regulated. SARA Hazard Category: Articles 311/312(40 CFR ) - Acute hazard: none - Chronic hazard: none - Fire hazard: none - Reactivity hazard: none SECTION 16 OTHER INFORMATION The information contained herein is based on the present state of our knowledge and is believed to be accurate. No warranty as to its accuracy or completeness is expressed or implied. LG Chem, Ltd. LG Twin Towers 20, Yeouido-dong, Yeongdeungpo-gu, Seoul, Korea Page5