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1 S A F E T Y D A T A S H E E T according to Regulation (EC) No. 1907/006 (amended by Regulation (EU) 015/830) SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Product name Product code 1.. Relevant identified uses of the substance or mixture and uses advised against Use of the Substance/Mixture Surface treatment 1.3. Details of the supplier of the safety data sheet Company/Undertaking Identification 1.4. Emergency telephone number Carlo Bernasconi AG Hohlstrasse Zürich Tel Fax info@carloag.ch 145 (Tox Info Suisse) Issuing date Version (Previous versions: 1) SECTION : Hazards identification.1. Classification of the substance or mixture Classification according to Regulation (EC) No. 17/008 The substance or mixture is not classified. In accordance with Regulation (EC) No. 17/008, the product does not need to be classified nor labelled. Print Date / 8

2 Additional information.. Label elements For the full text of the phrases mentioned in this Section, see Section 16. Signal Word - Hazard Statements Precautionary statements Supplemental information P60d: Do not breathe dust. Product identifier Mangan, CAS-No , EC-No Iron, CAS-No , EC-No Other hazards According to our experience and to the information provided to us, the product does not have any harmful effects if it is used and handled as specified. Contact with dust can cause mechanical irritation or drying of the skin. SECTION 3: Composition/information on ingredients 3.. Mixtures Metal alloy Components CLP Classification Product identifier Mangan 0.3 % Flam. Sol. H8 Iron > 97 % Flam. Sol. H8 CAS-No.: EC-No.: CAS-No.: EC-No.: For the full text of the phrases mentioned in this Section, see Section 16. Hazardous impurities SECTION 4: First aid measures 4.1. Description of first aid measures Inhalation Skin contact Eye contact Ingestion Move to fresh air in case of accidental inhalation of dust or fumes from overheating or combustion. Consult a physician for severe cases. Wash with water and soap as a precaution. If skin irritation persists, call a physician. Rinse immediately with plenty of water, also under the eyelids. If eye irritation persists, consult a specialist. Drink water as a precaution. Print Date / 8

3 4.. Most important symptoms and effects, both acute and delayed 4.3. Indication of any immediate medical attention and special treatment needed Contact with dust can cause mechanical irritation or drying of the skin. Consult a physician. None known. SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media Extinguishing media which must not be used for safety reasons 5.. Special hazards arising from the substance or mixture Special powder against metal fire. High volume water jet. Halons. Chlorocarbons. Aerosols of fine metal powder can ignite spontaneously in air. Fire may cause FeO, MnO to evolve. Collect contaminated fire extinguishing water separately. This must not be discharged into drains Advice for firefighters Special protective equipment for firefighters Specific methods In the event of fire, wear self-contained breathing apparatus. Wear protective suit. Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures Advice for non-emergency personnel Advice for emergency responders Use personal protective equipment. Avoid dust formation. Do not breathe vapours/dust. Avoid contact with skin and eyes. Use personal protective equipment. Evacuate personnel to safe areas. Do not breathe vapours/dust. 6.. Environmental precautions Do not flush into surface water or sanitary sewer system Methods and material for containment and cleaning up Contain spillage, and then collect with an electrically protected vacuum cleaner or by wet-brushing and place in container for disposal according to local regulations (see section 13) Reference to other sections See chapter 8 and 13. Print Date / 8

4 SECTION 7: Handling and storage 7.1. Precautions for safe handling 7.. Conditions for safe storage, including any incompatibilities Wear personal protective equipment. Avoid formation of dust and aerosols. Store in original container. Store in a place accessible by authorized persons only. Keep containers tightly closed in a dry, cool and wellventilated place. Do not store near acids Specific end use(s) No information available. SECTION 8: Exposure controls/personal protection 8.1. Control parameters Exposure limit(s) Mangan (CAS ) Switzerland - Occupational Exposure Limits - Developmental Risk Groups Switzerland - Occupational Exposure Limits - TWAs - (MAKs) Switzerland - Biological Limit Values (BAT-Werte) Austria - Occupational Exposure Limits - STELs - (MAK-KZWs) Austria - Occupational Exposure Limits - TWAs - (MAK-TMWs) Germany - DFG - Recommended Exposure Limits - TWAs (MAKs) Germany - DFG - Recommended Exposure Limits - Ceilings (Peak Limitations) Germany - TRGS Occupational Exposure Limits - TWAs (AGWs) Respirable dust fraction: Permissible exposure limit: 10 mg/m³. Alveolar dust fraction: Permissible exposure limit: 3 mg/m³. Developmental Risk Group C 0.5 mg/m3 TWA [MAK] (inhalable dust) 0 µg/l Medium: whole blood Time: end of shift, and after several shifts (for long-term exposures) Parameter: Manganese [Q] mg/m3 STEL [KZW] (inhalable fraction, 4 X 15 min) 0.5 mg/m3 TWA [TMW] (inhalable fraction) 0. mg/m3 TWA MAK (inhalable fraction) 0.0 mg/m3 TWA MAK (respirable fraction) 1.6 mg/m3 Peak (Ceiling factor 1 for Permanganates, inhalable fraction) 0.16 mg/m3 Peak (Ceiling factor 1 for Permanganates, respirable fraction) 0. mg/m3 TWA AGW (The risk of damage to the embryo or fetus can be excluded when AGW and BGW values are observed the limit values at the workplace is related to the elemental content of the metal, inhalable fraction, exposure factor 8) 0.0 mg/m3 TWA AGW (The risk of damage to the embryo or fetus can be excluded when AGW and BGW values are observed the limit values at the workplace is related to the elemental content of the metal, respirable fraction, exposure factor 8) 8.. Exposure controls Appropriate engineering controls Handle in accordance with good industrial hygiene and safety practice. Wash hands and face before breaks and immediately after handling the product. Print Date / 8

5 Personal protection equipment Respiratory protection Hand protection Eye protection Skin and body protection Thermal hazards In case of insufficient ventilation wear suitable respiratory equipment. Half mask with a particle filter P (EN 143). Normally none needed. Use gloves if repeated or prolonged contact is expected. Protective gloves complying with EN 374. Avoid contact with eyes. Safety glasses with side-shields conforming to EN166. Choose body protection according to the amount and concentration of the dangerous substance at the work place. Long sleeved clothing. No special measures required. Environmental exposure controls Avoid dust emission. Prevent product from entering surface water or sewage. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Appearance Granular. Colour Metallic. Odour Odourless. Odour Threshold ph: Melting point/range: ~1500 C Boiling point/range: Flash point: ~300 C Evaporation Rate: Flammability: Explosion limits: Vapour pressure: Vapor density: Relative density:.7 g/cm3 Water solubility: insoluble Partition coefficient (noctanol/water): Autoignition temperature: Decomposition temperature: Viscosity: Explosive properties: May form flammable dust-air mixture. Oxidising properties: None 9.. Other information General Product Characteristics No information available. Print Date / 8

6 SECTION 10: Stability and reactivity Reactivity No information available Chemical stability No decomposition if used as directed Possibility of hazardous reactions Aerosols of fine metal powder can ignite spontaneously in air Conditions to avoid Exothermic reaction with strong acids Incompatible materials Strong acids Hazardous decomposition products None under normal use. SECTION 11: Toxicological information Information on toxicological effects Acute toxicity Skin corrosion/irritation Serious eye damage/eye irritation Respiratory / Skin Sensitisation Carcinogenicity Germ cell mutagenicity Reproductive toxicity Specific target organ toxicity (single exposure) Specific target organ toxicity (repeated exposure) Aspiration hazard Human experience No data is available on the product itself. Endocrine disrupting chemical(s). Mangan (CAS ) Oral LD50 Rat = 9 g/kg (NLM_CIP) Iron (CAS ) Oral LD50 Rat = 30 g/kg (NLM_CIP) Contact with eyes may cause irritation. Classification not possible from current data. Classification not possible from current data. Classification not possible from current data. No data available. No data available. No data available. Inhalation of dust may cause shortness of breath, tightness of the chest, a sore throat and cough. Print Date / 8

7 SECTION 1: Ecological information 1.1. Toxicity No data is available on the product itself. 1.. Persistence and degradability Can be eliminated from water by sedimentation Bioaccumulative potential Bioaccumulation is unlikely Mobility in soil No data available Results of PBT and vpvb assessment No information available Other adverse effects No information available. SECTION 13: Disposal considerations Waste treatment methods Waste from residues / unused products Contaminated packaging Dispose of in accordance with local regulations. European Waste catalogue code (EWC-code): Dispose of as unused product. SECTION 14: Transport information ADR/RID IMDG IATA Further Information Not regulated. Not regulated. Not regulated. Not classified as dangerous in the meaning of transport regulations. SECTION 15: Regulatory information Safety, health and environmental regulations/legislation specific for the substance or mixture Regulatory Information Mangan (CAS ) TEDX (The Endocrine Disruption Exchange) - Potential Endocrine Disruptors In accordance with Regulation (EC) No. 17/008, the product does not need to be classified nor labelled. Water contaminating class (WGK Germany) = nwg. Present Print Date / 8

8 EU - REACH (1907/006) - List of Registered Substances EU - REACH (1907/006) - List of Registered Intermediates Iron (CAS ) TEDX (The Endocrine Disruption Exchange) - Potential Endocrine Disruptors EU - REACH (1907/006) - List of Registered Substances EU - REACH (1907/006) - List of Registered Intermediates 15.. Chemical safety assessment Present Present ([ ]) Present Present Present ([ ]) Not required. SECTION 16: Other information Revision Note Safety datasheet sections which have been updated:,3,8,9,11,15. Key or legend to abbreviations and acronyms Key literature references and sources for data Full text of phrases referred to under sections and 3 Instructions for use Disclaimer PEL: Permissible Exposure Limit According to information supplied by the manufacturer. Information taken from reference works and the literature. H8: Flammable solid. Restricted to professional users. The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. Print Date / 8