1. IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING 2. HAZARDS IDENTIFICATION

Transcription

1 SAFETY DATA SHEET 1. IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING 1.1 PRODUCT IDENTIFIER: PRODUCT CODE: Chemical Name: Polyetherpolysiloxan RELEVANT IDENTIFIED USES OF THE SUBSTANCE OR MIXTURE AND USES ADVISED AGAINST: Identified uses Surface additive; Uses advised against None DETAILS OF THE SUPPLIER OF THE SAFETY DATA SHEET: OMG Borchers GmbH Berghausener Str. 100, Langenfeld, Germany Tel.: , Fax: address: EMERGENCY TELEPHONE NUMBER: Carechem 24: +44(0) HAZARDS IDENTIFICATION 2.1 CLASSIFICATION OF THE SUBSTANCE OR MIXTURE CLASSIFICATION ACCORDING TO DIRECTIVE 1999/45/EC OR 67/548/EEC Not classified. CLASSIFICATION ACCORDING TO REGULATION (EC) NO 1272/2008 Not classified. 2.2 LABEL ELEMENTS: HAZARDOUS COMPONENT(S) TO BE INDICATED ON LABEL: SIGNAL WORD: Not Classified Page 1 of 7

2 HAZARD STATEMENTS: PRECAUTIONARY STATEMENTS: 3. COMPOSITION/INFORMATION ON INGREDIENTS CHEMICAL CHARACTERISTICS: Polyetherpolysiloxane. 4.1 DESCRIPTION OF FIRST AID MEASURES 4. FIRST AID MEASURES GENERAL INFORMATION: When symptoms persist or in all cases of doubt seek medical advice. EYE CONTACT: Rinse with plenty of water. SKIN CONTACT: Wash off with soap and plenty of water. INHALATION: No hazards which require special first aid measures. INGESTION: Do NOT induce vomiting. Call a physician immediately. 4.2 MOST IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED: 4.3 INDICATION OF ANY IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT NEEDED: 5.1 EXTINGUISHING MEDIA SUITABLE EXTINGUISHING MEDIA: All extinguishing materials are suitable. 5. FIRE FIGHTING MEASURES UNSUITABLE EXTINGUISHING MEDIA: Do not use a solid water stream as it may scatter and spread fire. 5.2 SPECIAL HAZARDS ARISING FROM THE SUBSTANCE OR MIXTURE: This information is not available. Page 2 of 7

3 5.3 ADVICE FOR FIREFIGHTERS: Keep people away from and upwind of spill/leak. In the event of fire, wear self contained breathing apparatus. Use personal protective equipment. Collect contaminated fire extinguishing water separately. This must not be discharged into drains. 6. ACCIDENTAL RELEASE MEASURES PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURE: Wear personal protective equipment. ENVIRONMENTAL PRECAUTIONS: The product should not be allowed to enter drains, water courses or the soil. METHODS AND MATERIAL FOR CONTAINMENT AND CLEANING UP: Soak up with inert absorbent material (e.g. sand, silica gel, acid binder, universal binder, sawdust). Keep in suitable, closed containers for disposal. REFERENCE TO OTHER SECTIONS: For handling advice see section 7. For personal protection see section 8. For waste disposal see section HANDLING AND STORAGE 7.1 PRECAUTIONS FOR SAFE HANDLING: Handle in accordance with good industrial hygiene and safety practice. Wear personal protective equipment. When using, do not eat, drink or smoke. Wash hands and face before breaks and immediately after handling the product. Preparation may charge electrostatically: always use earthing leads when transferring from one container to another. Take measures to prevent the build up of electrostatic charge. Keep away from heat and sparks - No Smoking. Keep away from combustible material. Do not let product enter drains. 7.2 CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES: Keep containers tightly closed in a dry, cool and well-ventilated place. Keep away from heat. Keep at temperatures between 5 C and 30 C. Incompatible products: German storage class 10 (TRGS 510) 7.3 SPECIFIC END USE(S): 8.1 CONTROL PARAMETERS 8. EXPOSURE CONTROLS/PERSONAL PROTECTION 8.2 EXPOSURE CONTROLS APPROPRIATE ENGINEERING CONTROLS: Ensure adequate ventilation, especially in confined areas. PERSONAL PROTECTIVE EQUIPMENT: EYE/FACE PROTECTION: Safety glasses with side-shields. (EN 166) Page 3 of 7

4 SKIN PROTECTION: Long sleeved clothing. Hand protection: There is no risk to health due to contact with the chemical. Use hand protection to prevent mechanically injuries according to EN 388. Check protective gloves prior to each use use for their proper conditions. Hygiene measures: Handle in accordance with good industrial hygiene and safety practice. Avoid contact with skin, eyes and clothing. When using, do not eat, drink or smoke. Wash hands before breaks and at the end of workday. Keep away from food and drink. RESPIRATORY PROTECTION: No personal respiratory protective equipment normally required. In case of insufficient ventilation, wear suitable respiratory equipment. ENVIRONMENTAL EXPOSURE CONTROLS: No information available. 9. PHYSICAL AND CHEMICAL PROPERTIES 9.1 INFORMATION ON BASIC PHYSICAL AND CHEMICAL PROPERTIES: Appearance Liquid Colour Yellow Odour Weak Odour Threshold ph Melting point/range -45 C Boiling point/range > 250 C (1013 hpa) Flash point 80 C (DIN 51758) Evaporation rate Flammability (solid, gas) Vapour pressure 5 hpa (20 C) 16 hpa (50 ºC) (EU A4) 18 hpa (55 C) Vapour density Relative density g/cm3 (20 C) (DIN 51757) Solubility -Water solubility Hydrolyses. Miscible. (>90 %) -Fat solubility -Solubility in other solvents Partition coefficient (n-octanol/water) Autoignition temperature 360 C (DIN 51794) Decomposition temperature Viscosity kinematic: 650 mm2/s (23 C) Explosive properties Oxidizing properties 9.2 OTHER INFORMATION: Bulk density 10. STABILITY AND REACTIVITY Page 4 of 7

5 STABILITY AND REACTIVITY REACTIVITY: No dangerous reaction known under conditions of normal use CHEMICAL STABILITY: POSSIBILITY OF HAZARDOUS REACTIONS: No dangerous reaction known under conditions of normal use. CONDITIONS TO AVOID: Keep away from heat. INCOMPATIBLE MATERIALS: None known. HAZARDOUS DECOMPOSITION PRODUCTS: No decomposition if stored and applied as directed. Measurements at temperatures above 150 C in presence of air (oxygen) have shown that small amounts of formaldehyde are formed due to oxidative degradation INFORMATION ON TOXICOLOGICAL EFFECTS 11. TOXICOLOGICAL INFORMATION ACUTE TOXICITY: Ingestion: LD50/oral/rat: > 5000 mg/kg Human experience According to our experience and to the information provided to us, the product does not have any harmful effects if it is used and handled as specified. SKIN CORROSION/IRRITATION: Rabbit skin: No skin irritation. Exposure time 24 h SERIOUS EYE DAMAGE/EYE IRRITATION: Rabbit eye: No eye irritation. RESPIRATORY OR SKIN SENSITIZATION: GERM CELL MUTAGENICITY: CARCINOGENICITY: REPRODUCTIVE TOXICITY: SPECIFIC TARGET ORGAN SYSTEMIC TOXICITY (SINGLE EXPOSURE): SPECIFIC TARGET ORGAN SYSTEMIC TOXICITY (REPEATED EXPOSURE): Page 5 of 7

6 ASPIRATION HAZARD: 12. ECOLOGICAL INFORMATION TOXICITY: There is no data available for this product. PERSISTENCE AND DEGRADABILITY: BIOACCUMULATIVE POTENTIAL: MOBILITY IN SOIL: RESULTS OF PBT AND vpvb ASSESSMENT: OTHER ADVERSE EFFECTS: 13. DISPOSAL CONSIDERATIONS 13.1 WASTE TREATMENT METHODS: EWC WASTE CODE: Waste codes should be assigned by the user based on the application for which the product was used. Always check the given waste codes according to the actual conditions of manufacturing, formulation or use in your facilities. WASTE FROM RESIDUES / UNUSED PRODUCTS: Can be incinerated, when in compliance with local regulations. CONTAMINATED PACKAGING: Dispose of as unused product. 14. TRANSPORT INFORMATION LAND TRANSPORT: SEA TRANSPORT: AIR TRANSPORT: 14.1 UN-Number 14.2 UN proper shipping name 14.3 Transport hazard class(es) 14.4 Packing group 14.5 Environmental hazards 14.6 Special precautions for users 14.7 Transport in bulk according to Not applicable. Not applicable. Not applicable. Annex II of MARPOL 73/78 and the IBC Code Page 6 of 7

7 15. REGULATORY INFORMATION 15.1 SAFETY, HEALTH AND ENVIRONMENT REGULATIONS/LEGISLATION SPECIFIC FOR THE SUBSTANCE OR MIXTURE: NATIONAL REGULATIONS: Risk classification according to BetrSichV (Germany): Not subject to the German Regulation on Flammable Liquids (VbF). TA-Luft List (Germany): Not applicable. LIST OF RELEVANT R-PHRASES: None HAZARD STATEMENTS: Volatile organic compounds (VOC) content: Directive 1999/13 /EC on the limitation of emissions of volatile organic compounds: 100 % Switzerland. VOC Ordinance, Annex II (Products): 0 % 16. OTHER INFORMATION FURTHER INFORMATION: This material safety data sheet complies with the requirements of Regulation (EC) No. 1907/2006. PREPARED BY: OMG Borchers GmbH REVISED INFORMATION: This data sheet contains changes from the previous version in section(s): 1-16 DISCLAIMER OF EXPRESSED AND IMPLIED WARRANTIES: The information in this document is believed to be correct as of the date issued. However, no warranty of merchantability, fitness for any particular purpose, or any other warranty is expressed or is to be implied regarding the accuracy or completeness of this information, the results to be obtained from the use of this information or the product, the safety of this product, or the hazards related to its use. This information and product are furnished on the condition that the person receiving them shall make his own determination as to the suitability of the product for his particular purpose and on the condition that he assume the risk of his use thereof. Page 7 of 7