1. IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING 2. HAZARDS IDENTIFICATION

Transcription

1 SAFETY DATA SHEET 1. IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING 1.1 PRODUCT IDENTIFIER: PRODUCT NAME: Borchi Gol 3451 PRODUCT CODE: RELEVANT IDENTIFIED USES OF THE SUBSTANCE OR MIXTURE AND USES ADVISED AGAINST: Identified uses Surface additive; Uses advised against None 1.3 DETAILS OF THE SUPPLIER OF THE SAFETY DATA SHEET: OMG Borchers GmbH Berghausener Str. 100, Langenfeld, Germany Tel.: , Fax: address: 1.4 EMERGENCY TELEPHONE NUMBER: Carechem 24- OMG29003-NCEC: Intl: +44(0) USA: HAZARDS IDENTIFICATION 2.1 CLASSIFICATION OF THE SUBSTANCE OR MIXTURE CLASSIFICATION ACCORDING TO DIRECTIVE 1999/45/EC OR 67/548/EEC R10 Xn; R20/21 Xi; R38 For the full text of the R-phrases mentioned in this Section, see Section 16. CLASSIFICATION ACCORDING TO REGULATION (EC) NO 1272/2008 Acute inhalation toxicity Category 4 ; H332 Acute dermal toxicity Category 4 ; H312 Skin corrosion/irritation Category 2 ; H315 Flammable Liquid Category 3 ; H226 Page 1 of 9

2 2.2 LABEL ELEMENTS: HAZARDOUS COMPONENT(S) TO BE INDICATED ON LABEL: Xylene SIGNAL WORD: WARNING HAZARD STATEMENTS: H226 - Flammable liquid and vapor. H312 - Harmful in contact with skin. H315 - Causes skin irritation. H332 - Harmful if inhaled. PRECAUTIONARY STATEMENTS: P280 - Wear protective gloves/clothing. P501 - Dispose of contents/container to an approved waste disposal plant. 3. COMPOSITION/INFORMATION ON INGREDIENTS CHEMICAL NAME: Xylene Ethylbenzene PERCENT:EINECS NO: REGISTRATION NUMBER: WARNING SYMBOL, R PHRASES AND OTHER INFORMATION: GHS CLASSIFICATION: R10, Xn; R20/21, Xi; R38 Flam. Liq. 3; H226, Acute Tox. 4; H332/312, Skin Irrit. 2; H315, None F; R11, Xn; R20 Flam. Liquid 2; H225 Acute Tox. 4; H332, CHEMICAL CHARACTERISTICS: Polydimethylsiloxane in mixture. 4.1 DESCRIPTION OF FIRST AID MEASURES 4. FIRST AID MEASURES EYE CONTACT: Immediately flush with plenty of water. After initial flushing, remove any contact lenses and continue flushing for at least 15 minutes. Obtain medical attention. SKIN CONTACT: Remove soiled or soaked clothing immediately. After contact with skin, wash immediately with a polyethylene glycol solution, followed by plenty of water. If symptoms persist, call a physician. Page 2 of 9

3 INHALATION: Remove victim to fresh air and keep at rest in a position comfortable for breathing. If symptoms persist, call a physician. INGESTION: Call a physician immediately. 4.2 MOST IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED: 4.3 INDICATION OF ANY IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT NEEDED: 5.1 EXTINGUISHING MEDIA SUITABLE EXTINGUISHING MEDIA: All extinguishing materials are suitable. 5. FIRE FIGHTING MEASURES UNSUITABLE EXTINGUISHING MEDIA: Do not use a solid water stream as it may scatter and spread fire. 5.2 SPECIAL HAZARDS ARISING FROM THE SUBSTANCE OR MIXTURE: In the event of fire the following can be released: Carbon dioxide (CO2). Carbon monoxide (CO). Vapors are heavier than air and may spread along floors. Vapors may form explosive mixtures with air. 5.3 ADVICE FOR FIREFIGHTERS: Wear self contained breathing apparatus for fire fighting if necessary. Use personal protective equipment. Standard procedure for chemical fires. Cool closed containers exposed to fire with water spray. Collect contaminated fire extinguishing water separately. This must not be discharged into drains. 6. ACCIDENTAL RELEASE MEASURES 6.1 PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURE: Keep people away from and upwind of spill/leak. Keep away from heat and sparks - No Smoking. Wear personal protective equipment. Ensure adequate ventilation. 6.2 ENVIRONMENTAL PRECAUTIONS: Should not be released into the environment. Do not discharge into the drains/surface waters/groundwater. 6.3 METHODS AND MATERIAL FOR CONTAINMENT AND CLEANING UP: Soak up with inert absorbent material (e.g. sand, silica gel, acid binder, universal binder, sawdust). Sweep up or vacuum up spillage and collect in suitable container for disposal. Local authorities should be advised if significant spillages cannot be contained. 6.4 REFERENCE TO OTHER SECTIONS: For handling advice see section 7. For personal protection see section 8. For waste disposal see section HANDLING AND STORAGE Page 3 of 9

4 7.1 PRECAUTIONS FOR SAFE HANDLING: Wear personal protective equipment. Avoid contact with skin and eyes. Wash hands before breaks and at the end of workday. Keep away from heat and sparks - No Smoking. Do not let product enter drains. Take precautionary measures against static discharges. Preparation may charge electrostatically: always use earthing leads when transferring from one container to another. Vapors may form explosive mixtures with air. Normal measures for preventive fire protection. Provide good ventilation of working area (local echaust ventilation if necessary). 7.2 CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES: Keep containers tightly closed in a dry, cool and well-ventilated place. Avoid temperatures above 50 C. Keep at temperatures between 5 C and 30 C. Incompatible products: None. German storage class 3 (TRGS 510) 7.3 SPECIFIC END USE(S): Nodataavailable. 8.1 CONTROL PARAMETERS 8. EXPOSURE CONTROLS/PERSONAL PROTECTION CHEMICAL NAME: EXPOSURE LIMIT(S): SOURCE: Xylene Xylene, O-, M-, P- or mixed isomers TWA: 50 ppm / 220 mg/ml STEL: 100 ppm / 441 mg/m 3 Can be absorbed through skin. UK Workplace Exposure Limits (WELs) BMGVs: 650 (mmol/mol creatinine) Determinant Methyl hippuric acid Specimen U (urine) Sampling time: End of shift Ethylbenzene Indicative occupational exposure limit values: 50 ppm / 221 mg/m 3 (8h); 100 ppm / 442 mg/m 3 (15 min) Possibility of significant uptake through the skin. Ethylbenzene TWA: 100 ppm / 441 mg/n3 STEL: 125 ppm / 552 mg/m 3 Can be absorbed through skin. Indicative occupational exposure limit values: 100 ppm / 442 mg/m 3 (8h); 200 ppm / 884 mg/m 3 (15 min) Possibility of significant uptake through the skin. UK Workplace Exposure Limits (WELs) 8.2 EXPOSURE CONTROLS Page 4 of 9

5 APPROPRIATE ENGINEERING CONTROLS: Provide sufficient air exchange and/or exhaust in work rooms. PERSONAL PROTECTIVE EQUIPMENT: EYE/FACE PROTECTION: Tightly fitting safety goggles. SKIN PROTECTION: Long sleeved clothing. Hand protection: Chemical resistant gloves. Suitable material Nitrile rubber. Break through time: >= 480 min. Glove thickness: 0.4 mm. Take note of the information given by the producer concerning permeability and break through times, and of special workplace conditions (mechanical strain, duration of contact). Gloves should be discarded and replaced if there is any indication of degradation or chemical breakthrough. Be aware that in daily use the durability of a chemical resistant protective glove can be notably shorter than the break through time measured according to EN 374, due to the numerous outside influences (e.g. temperature). Hygiene measures: Handle in accordance with good industrial hygiene and safety practice. Avoid contact with skin, eyes and clothing. Wash hands before breaks and immediately after handling the product. When using, do not eat, drink or smoke. RESPIRATORY PROTECTION: Respirator with a vapor filter (EN 141). In the case of vapour formation use a respirator with filter model ABEK. ENVIRONMENTAL EXPOSURE CONTROLS: No information available. 9. PHYSICAL AND CHEMICAL PROPERTIES 9.1 INFORMATION ON BASIC PHYSICAL AND CHEMICAL PROPERTIES: Appearance Liquid Colour Colourless Odour Solvent Odour Threshold ph Melting point/range -50 C Boiling point/range 130 C (1013 hpa) Flash point 26 C (DIN 51755) Evaporation rate Flammability (solid, gas) Vapour pressure 10 hpa (20 C) 48 hpa (50 ºC) (EU A4) 60 hpa (55 C) Vapour density Relative density g/cm3 (20 C) (DIN 51757) Solubility -Water solubility Immiscible. -Fat solubility -Solubility in other solvents Partition coefficient (n-octanol/water) Autoignition temperature > 500 C (DIN 51794) Decomposition temperature Viscosity kinematic: 280 mm2/s (23 C) Page 5 of 9

6 Explosive properties Oxidizing properties 9.2 OTHER INFORMATION: Bulk density 10. STABILITY AND REACTIVITY 10.1 REACTIVITY: 10.2 CHEMICAL STABILITY: Stable under recommended storage conditions POSSIBILITY OF HAZARDOUS REACTIONS: No dangerous reaction known under conditions of normal use CONDITIONS TO AVOID: 10.5 INCOMPATIBLE MATERIALS: None known HAZARDOUS DECOMPOSITION PRODUCTS: No decomposition if stored and applied as directed. Fire may cause evolution of: Carbon monoxide (CO). Carbon dioxide (CO2). Fumes. Measurements at temperatures above 150 C in presence of air (oxygen) have shown that small amounts of formaldehyde are formed due to oxidative degradation INFORMATION ON TOXICOLOGICAL EFFECTS ACUTE TOXICITY: 11. TOXICOLOGICAL INFORMATION Ingestion: Inhalation: Skin contact: Eye contact: LD50/oral/rat: 4300 mg/kg Reference substance: Xylene, CAS: LC50/inhalation/4h/rat: 23.6 mg/l Reference substance: Xylene, CAS: SKIN CORROSION/IRRITATION: SERIOUS EYE DAMAGE/EYE IRRITATION: RESPIRATORY OR SKIN SENSITIZATION: Page 6 of 9

7 GERM CELL MUTAGENICITY: CARCINOGENICITY: REPRODUCTIVE TOXICITY: SPECIFIC TARGET ORGAN SYSTEMIC TOXICITY (SINGLE EXPOSURE): SPECIFIC TARGET ORGAN SYSTEMIC TOXICITY (REPEATED EXPOSURE): ASPIRATION HAZARD: FURTHER INFORMATION: Human experience: According to our experience and to the information provided to us, the product does not have any harmful effects if it is used and handled as specified TOXICITY: No data available 12.2 PERSISTENCE AND DEGRADABILITY: 12.3 BIOACCUMULATIVE POTENTIAL: 12.4 MOBILITY IN SOIL: 12.5 RESULTS OF PBT AND vpvb ASSESSMENT: 12.6 OTHER ADVERSE EFFECTS: 13.1 WASTE TREATMENT METHODS: 12. ECOLOGICAL INFORMATION 13. DISPOSAL CONSIDERATIONS EWC WASTE CODE: According to the European Waste Catalogue, Waste Codes are not product specific, but application specific. Waste codes should be assigned by the user based on the application for which the product was used. Page 7 of 9

8 WASTE FROM RESIDUES / UNUSED PRODUCTS: Can be incinerated, when in compliance with local regulations. CONTAMINATED PACKAGING: Dispose of as unused product. 14. TRANSPORT INFORMATION LAND TRANSPORT: SEA TRANSPORT: AIR TRANSPORT: 14.1 UN-Number UN proper shipping name (xylenes in mixture) (xylenes in mixture) (xylenes in mixture) 14.3 Transport hazard class(es) Packing group III III III 14.5 Environmental hazards None. None. None Special precautions for users Hazard identification No 30 EmS (Fire): F-E EmS (Spill): S-D None Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code Not applicable. Not applicable. Not applicable. 15. REGULATORY INFORMATION 15.1 SAFETY, HEALTH AND ENVIRONMENT REGULATIONS/LEGISLATION SPECIFIC FOR THE SUBSTANCE OR MIXTURE: NATIONAL REGULATIONS: Water pollution class (Germany) = 2 German legislation on water endangering substances VwVwS LIST OF RELEVANT R-PHRASES: R10 - Flammable. R11 - Highly flammable. R20 - Harmful by inhalation. R20/21 - Harmful by inhalation and in contact with skin. R38 - Irritating to skin. HAZARD STATEMENTS: H225 - Highly flammable liquid and vapor H226 - Flammable liquid and vapor H312 - Harmful in contact with skin H315 - Causes skin irritation. H332 - Harmful if inhaled Volatile organic compounds (VOC) content: Switzerland. VOC Ordinance, Annex II (Products): 80 % Directive 1999/13/EC on the limitation of emissions of volatile organic compounds: 80 % 16. OTHER INFORMATION Page 8 of 9

9 FURTHER INFORMATION: This material safety data sheet complies with the requirements of Regulation (EC) No. 1907/2006. PREPARED BY: OMG Borchers GmbH LIST OF ABBREVIATIONS USED IN THE SAFETY DATA SHEET: Flam. Liq. 3 = Flammable Liquid Category 3 Acute Tox. 4 = Acute Oral Toxicity Category 4 Skin irrit. 2 = Skin corrosion/irritation Category 2 Flam. Liq. 2 = Flammable Liquid Category 2 REVISED INFORMATION: This data sheet contains changes from the previous version in section(s): 1; Product name; 16; DISCLAIMER OF EXPRESSED AND IMPLIED WARRANTIES: The information in this document is believed to be correct as of the date issued. However, no warranty of merchantability, fitness for any particular purpose, or any other warranty is expressed or is to be implied regarding the accuracy or completeness of this information, the results to be obtained from the use of this information or the product, the safety of this product, or the hazards related to its use. This information and product are furnished on the condition that the person receiving them shall make his own determination as to the suitability of the product for his particular purpose and on the condition that he assume the risk of his use thereof. Page 9 of 9