Safety Data Sheet Freeman Synthene PRC 1719 Clear Casting Resin

Transcription

1 Section 1 Identification Product identifiers Product name: Isocyanate Relevant identified uses of the substance or mixture and uses advised against Identified uses: Polyurethane resin, for professional use only Details of the supplier of the safety data sheet Freeman Manufacturing and Supply Company 1101 Moore Road, Avon, OH Phone (440) FAX (440) Hour Emergency Phone Number: (800) Section 2 Hazards Identification GHS classification in accordance with 29 CFR (OSHA HCS) Acute toxicity (inhalation, dust, mist), Category 2 Skin corrosion/irritation, Category 2 Serious eye damage/eye irritation, Category 2 Sensitization - Respiratory, Category 1 Sensitization - Skin, Category 1 Specific target organ toxicity - Single exposure, Category 3, Respiratory tract irritation Hazard pictograms: Signal word: Danger Hazard statements Causes skin irritation May cause an allergic skin reaction Causes serious eye irritation Fatal if inhaled May cause allergy or asthma symptoms or breathing difficulties if inhaled May cause respiratory irritation Precautionary statements Prevention Do not handle until all safety precautions have been read and understood. Do not breathe dust/fume/gas/mist/vapors/spray. Use only outdoors or in a well-ventilated area. Contaminated work clothing should not be allowed out of the workplace. Wear protective gloves/protective clothing/eye protection/face protection. In case of inadequate ventilation wear respiratory protection. Date of Preparation: April 20, 2018 Page 1 of 5

2 Section 2 Hazards Identification continued Wash with soap and water thoroughly after handling. Do not eat, drink or smoke when using this product. Response If on skin: Wash with plenty of soap and water. If inhaled: Remove victim to fresh air. If in eyes: Rinse continuously with water for at least 15 minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. If on skin: Wash with plenty of soap and water. If skin irritation or rash occurs: Get medical advice/attention. If swallowed, do not induce vomiting. Call physician immediately. Section 3 Composition/Information on Ingredients Ingredient Name CAS Number Concentration (%) Dicyclohexylmethane-4,4'-di-isocyanate Section 4 First Aid Measures Inhalation: Move to fresh air in case of accidental inhalation of vapors or decomposition products. Eye Contact: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Skin Contact: Remove/Take off immediately all contaminated clothing. Gently wash with plenty of soap and water. Get medical advice/attention. Ingestion: Take victim to fresh air, in a quiet place in an half laying position and urgently take medical advice. Do not give anything to drink. Do not induce vomiting. Section 5 Fire-Fighting Measures Suitable extinguishing media Use alcohol-resistant foam, dry chemical, carbon dioxide, or water spray. Special hazards arising from mixture In case of fire and/or explosion do not breathe fumes. Advice for firefighters Exercise caution when fighting any chemical fire. Prevent fire-fighting water from entering the environment. Do not enter fire area without proper protective equipment, including respiratory protection. Section 6 Accidental Release Measures Personal precautions, protective equipment and emergency procedures For personal protection see section 8. Provide local exhaust or general room ventilation. Evacuate unnecessary personnel. Only qualified personnel equipped with suitable protective equipment may intervene. Equip cleanup crew with proper protection. Do not breathe gas, fumes, vapor or spray. Date of Preparation: April 20, 2018 Page 2 of 5

3 Section 6 Accidental Release Measures continued Environmental precautions Prevent entry to sewers and public waters. Avoid release to the environment. Methods and materials for containment and cleaning up Soak up spills with inert solids, such as clay or diatomaceous earth as soon as possible. Shovel into suitable and closed container for disposal. Hose down area with water. Store away from other materials. Dispose of this material and its container to hazardous or special waste collection point. Section 7 Handling and Storage Precautions for safe handling Provide good ventilation in process area to prevent formation of vapor. Do not get in eyes, on skin, or on clothing. Use personal protective equipment as required. Do not eat, drink or smoke when using this product. Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work. Regular cleaning of equipment, work area and clothing. Conditions for safe storage, including any incompatibilities Keep only in the original container in a cool, well-ventilated place. Store at temperatures between C. Keep away from food, drink and animal feed. Section 8 Exposure Controls/Personal Protection Personal protective equipment Eye/face protection Wear chemical goggles or face shield Hand Protection PVC or other plastic material gloves Body Protection Wear suitable protective clothing Respiratory Protection In case of insufficient ventilation, wear suitable respiratory equipment General Hygienic Practices Avoid contamination of food, beverages, or smoking materials. Wash thoroughly after handling, and before eating, drinking or smoking. Remove contaminated clothing promptly and clean thoroughly before reuse. Section 9 Physical and Chemical Properties Appearance Transparent colorless liquid Odor Characteristic Odor threshold ph Not applicable Melting Point/Freezing Point Initial boiling point/boiling range Flash Point Evaporation rate Flammability (solid, gas) Date of Preparation: April 20, 2018 Page 3 of 5

4 Section 9 Physical and Chemical Properties continued Upper/lower flammability Vapor pressure at 68 F Vapor density (Air=1) Specific gravity 1.07 Solubility Reacts with water, insoluble Coefficient: n-octanol/ water Auto-ignition temperature Decomposition temperature Viscosity 320 cp Danger of explosion VOC Content 0% Section 10 Stability and Reactivity Reactivity: No hazardous reactions if stored and handled as prescribed/indicated., No corrosive effect on metal. Not fire propagating. Chemical stability: These products are stable at room temperature in closed containers under normal storage and handling conditions. Possibility of hazardous reactions: No additional information available Conditions to avoid: None known Incompatible materials: Strong bases, alcohol, amine, ammonia Hazardous decomposition products: Carbon oxides, nitrogen oxides Section 11 Toxicological Information Information on toxicological effects Acute toxicity (oral): Not classified Acute toxicity (dermal): Not classified Acute toxicity (inhalation): Inhalation of dust/mist, fatal if inhaled 4,4'-methylenedi(cyclohexyl isocyanate), dicyclohexylmethane-4,4'-di-isocyanate ( ) LD50 oral rat mg/kg LD50 dermal rat > 7000 mg/kg LC50 inhalation rat (mg/l) 0.33 mg/l 4h Skin Corrosion/Irritation: Causes skin irritation Serious Eye Damage/Irritation: Causes serious eye irritation Respiratory/Skin Sensitization: May cause allergy or asthma symptoms or breathing difficulties if inhaled. May cause an allergic skin reaction. Germ Cell Mutagenicity: Not classified Carcinogenicity: Not classified Reproductive Toxicity: Not classified Specific Target Organ Toxicity Single Exposure: May cause respiratory irritation Specific Target Organ Toxicity Repeated Exposure: Not classified Aspiration Hazard: Not classified Date of Preparation: April 20, 2018 Page 4 of 5

5 Section 12 Ecological Information Ecotoxicity: Not classified Persistence and degradability: Not readily biodegradable Bioaccumulative potential: May be harmful to aquatic organisms, to flora, to soil organisms Mobility in soil: No additional information available Results of PBT & vpvb: No additional information available Other Adverse Effects: No additional information available Section 13 Disposal Considerations Dispose of material and container at hazardous or special waste collection point.. Contact a licensed contractor for detailed recommendations. Follow applicable Federal, State, and local regulations. Section 14 Transport Information DOT: Not Regulated IMDG: Not Regulated IATA: UN 3334 aviation regulated liquid, n.o.s. (Dicyclohexylmethane-4,4 -di-isocyanate),9, III Section 15 Regulatory Information US Federal Regulations TSCA Inventory Status: All ingredients listed on the Toxic Substance Control Act Inventory CERCLA/SARA Title III, Section 302 EHS: No reportable components CERCAL/SARA Title III, Section 313: Dicyclohexylmethane-4,4'-di-isocyanate, CAS US State Regulations California Proposition 65: This product does not contain any chemicals known to the state of California to cause cancer, birth defects, or other reproductive harm. Section 16 Other Information Disclaimer The following supersedes Buyer s documents. SELLER MAKES NO REPRESENTATION OR WARRANTY, EXPRESSED OR IMPLIED, INCLUDING ANY WARRANTY OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE. No statements herein are to be construed as inducements to infringe any relevant patent. Under no circumstances shall Seller be liable for incidental, consequential or indirect damages for alleged negligence, breach of warranty, strict of liability arising in connection with the product(s). Buyer s sole remedy and Seller s sole liability for any claims shall be Buyer s purchase price. Data and results are based on controlled lab work and must be confirmed by Buyer by testing for its intended conditions of use. The product(s) has not been tested for, and is therefore not recommended for, uses for which prolonged contact with mucous membranes, abraded skin, or blood is intended; or for uses for which implantation within the human body is intended. Date of Preparation: April 20, 2018 Page 5 of 5

6 Section 1 Identification Product identifiers Product name: Polyol Hardener Relevant identified uses of the substance or mixture and uses advised against Identified uses: Polyurethane resin, for professional use only Details of the supplier of the safety data sheet Freeman Manufacturing and Supply Company 1101 Moore Road, Avon, OH Phone (440) FAX (440) Hour Emergency Phone Number: (800) Section 2 Hazards Identification GHS classification in accordance with 29 CFR (OSHA HCS) This mixture is classified as not hazardous Section 3 Composition/Information on Ingredients Ingredient Name CAS Number Concentration (%) Trimethyl orthoformate Section 4 First Aid Measures Inhalation: Move victim to fresh air. If breathing has stopped, give artificial respiration, then oxygen if needed. Eye Contact: Flush eyes with plenty of water. Seek medical attention. Skin Contact: In case of skin contact, wash thoroughly with soap and water. If irritation persists, seek medical attention. Ingestion: Do not give victim anything to drink. Do not induce vomiting. Seek medical attention. Section 5 Fire-Fighting Measures Suitable extinguishing media Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide. Special hazards arising from mixture In case of fire and/or explosion do not breath fumes. Advice for firefighters Do not enter fire area without proper protective equipment, including respiratory protection. Section 6 Accidental Release Measures Personal precautions, protective equipment and emergency procedures For personal protection see section 8. Date of Preparation: April 20, 2018 Page 1 of 4

7 Section 6 Accidental Release Measures continued Environmental precautions Prevent entry to sewers and public waters. Avoid release to the environment. Methods and materials for containment and cleaning up Soak up spills with inert solids, such as clay or diatomaceous earth as soon as possible. Shovel into suitable and closed container for disposal. Hose down area with water. Store away from other materials. Dispose of this material and its container to hazardous or special waste collection point. Section 7 Handling and Storage Precautions for safe handling Provide good ventilation in process area to prevent formation of vapor. Do not get in eyes, on skin, or on clothing. Use personal protective equipment as required Conditions for safe storage, including any incompatibilities Keep only in the original container in a cool, well-ventilated place. Store at temperatures between 5-40 C. Keep away from food, drink and animal feed. Section 8 Exposure Controls/Personal Protection Personal protective equipment Eye/face protection Wear chemical goggles or face shield Hand Protection Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work. PVC or other plastic material gloves Body Protection Wear suitable protective clothing Respiratory Protection In case of insufficient ventilation, wear suitable respiratory equipment General Hygienic Practices Avoid contamination of food, beverages, or smoking materials. Wash thoroughly after handling, and before eating, drinking or smoking. Remove contaminated clothing promptly and clean thoroughly before reuse. Section 9 Physical and Chemical Properties Appearance Transparent colorless liquid Odor Mild Odor threshold ph Not applicable Melting Point/Freezing Point Initial boiling point/boiling range Flash Point >200 F Evaporation rate Flammability (solid, gas) Upper/lower flammability Vapor pressure at 68 F Date of Preparation: April 20, 2018 Page 2 of 4

8 Section 9 Physical and Chemical Properties continued Vapor density (Air=1) Specific gravity 1.08 Solubility Reacts with water, insoluble Coefficient: n-octanol/ water Auto-ignition temperature Decomposition temperature Viscosity 450 cp Danger of explosion VOC Content 0% Section 10 Stability and Reactivity Reactivity: No hazardous reactions if stored and handled as prescribed/indicated., No corrosive effect on metal. Not fire propagating. Chemical stability: These products are stable at room temperature in closed containers under normal storage and handling conditions. Possibility of hazardous reactions: No additional information available Conditions to avoid: None known Incompatible materials: Metals, aluminum, zinc Hazardous decomposition products: Carbon oxides, nitrogen oxides Section 11 Toxicological Information Information on toxicological effects Skin Corrosion/Irritation: Not classified Serious Eye Damage/Irritation: Not classified Respiratory/Skin Sensitization: Not classified Germ Cell Mutagenicity: Not classified Carcinogenicity: Not classified Reproductive Toxicity: Not classified Specific Target Organ Toxicity Single Exposure: Not classified Specific Target Organ Toxicity Repeated Exposure: Not classified Section 12 Ecological Information Ecotoxicity: Not classified Persistence and degradability: Not readily biodegradable Bioaccumulative potential: May be harmful to aquatic organisms, to flora, to soil organisms Mobility in soil: No additional information available Results of PBT & vpvb: No additional information available Other Adverse Effects: No additional information available Section 13 Disposal Considerations Dispose of material and container at hazardous or special waste collection point.. Contact a licensed contractor for detailed recommendations. Follow applicable Federal, State, and local regulations. Date of Preparation: April 20, 2018 Page 3 of 4

9 Section 14 Transport Information DOT: Not Regulated IMDG: Not Regulated IATA: Not Regulated Section 15 Regulatory Information US Federal Regulations TSCA Inventory Status: All ingredients listed on the Toxic Substance Control Act Inventory CERCLA/SARA Title III, Section 302 EHS: No reportable components CERCAL/SARA Title III, Section 313: No reportable components US State Regulations California Proposition 65: This product does not contain any chemicals known to the state of California to cause cancer, birth defects, or other reproductive harm. Section 16 Other Information Disclaimer The following supersedes Buyer s documents. SELLER MAKES NO REPRESENTATION OR WARRANTY, EXPRESSED OR IMPLIED, INCLUDING ANY WARRANTY OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE. No statements herein are to be construed as inducements to infringe any relevant patent. Under no circumstances shall Seller be liable for incidental, consequential or indirect damages for alleged negligence, breach of warranty, strict of liability arising in connection with the product(s). Buyer s sole remedy and Seller s sole liability for any claims shall be Buyer s purchase price. Data and results are based on controlled lab work and must be confirmed by Buyer by testing for its intended conditions of use. The product(s) has not been tested for, and is therefore not recommended for, uses for which prolonged contact with mucous membranes, abraded skin, or blood is intended; or for uses for which implantation within the human body is intended. Date of Preparation: April 20, 2018 Page 4 of 4