Material Safety Data Sheet acc. to ISO/DIS 11014

Transcription

1 Page 1/6 1 Identification of substance Product details Application of the substance / the preparation Electroplating auxiliary Manufacturer/Supplier: Wieland Dental + Technik GmbH & Co.KG Schwenninger Str Pforzheim Telefon + 49 (07231)-37050, Telefax + 49 (07231) Information department: Abteilung Umweltschutz Marcus.Mueller@wieland-dental.de Emergency information: +49 (07231) ( Be kindly advised that this number can only be contacted at usual office hours.) 2 Composition/Data on components Chemical characterization: CAS No. Description potassium carbonate Identification number(s) EINECS Number: Chemical characterization Dangerous components: Void 3 Hazards identification Hazard description: Harmful Information pertaining to particular dangers for man and environment: Harmful if swallowed. Irritating to eyes, respiratory system and skin. Classification system: NFPA ratings (scale 0-4) Health = 2 Fire = 0 Reactivity = 0 WHMIS-ratings (scale 0-4) HEALTH FIRE REACTIVITY Health = 2 Fire = 0 Reactivity = 0 GHS label elements Danger 3.1/3 - Toxic if swallowed. 3.2/2 - Causes skin irritation. 3.3/2A - Causes serious eye irritation. 3.8/3 - May cause respiratory irritation. (Contd. on page 2)

2 Page 2/6 (Contd. of page 1) Prevention: Avoid breathing dust/fume/gas/mist/vapours/spray. Response: IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Specific treatment (see on this label). Storage: Store locked up. Disposal: Dispose of contents/container in accordance with local/regional/national/international regulations. 4 First aid measures General information: Immediately remove any clothing soiled by the product. After inhalation: Supply fresh air; consult doctor in case of complaints. After skin contact: Immediately wash with water and soap and rinse thoroughly. If skin irritation continues, consult a doctor. After eye contact: Rinse opened eye for several minutes under running water. If symptoms persist, consult a doctor. After swallowing: Rinse out mouth and then drink plenty of water. Seek immediate medical advice. Information for doctor: The following symptoms may occur: Nausea 5 Fire fighting measures Suitable extinguishing agents: CO2, extinguishing powder or water spray. Fight larger fires with water spray or alcohol resistant foam. Protective equipment: Wear self-contained respiatory protective device. 6 Accidental release measures Person-related safety precautions: Avoid formation of dust. Wear protective equipment. Keep unprotected persons away. Measures for environmental protection: Do not allow to enter sewers/ surface or ground water. Measures for cleaning/collecting: Dispose contaminated material as waste according to item 13. Pick up mechanically. 7 Handling and storage Handling: Information for safe handling: Prevent formation of dust. Information about protection against explosions and fires: No special measures required. Storage: Requirements to be met by storerooms and receptacles: Store only in the original receptacle. Information about storage in one common storage facility: Not required. Further information about storage conditions: Keep receptacle tightly sealed. (Contd. on page 3)

3 Page 3/6 (Contd. of page 2) 8 Exposure controls and personal protection Additional information about design of technical systems: No further data; see item 7. Components with limit values that require monitoring at the workplace: Not required. Additional information: The lists that were valid during the creation were used as basis. Personal protective equipment: General protective and hygienic measures: Keep away from foodstuffs, beverages and feed. Immediately remove all soiled and contaminated clothing. Wash hands before breaks and at the end of work. Avoid contact with the eyes. Avoid contact with the eyes and skin. Breathing equipment: Use suitable respiratory protective device in case of insufficient ventilation. Protection of hands: Protective gloves Material of gloves Chloroprene rubber, CR Butyl rubber, BR Fluorocarbon rubber (Viton) Nitrile rubber, NBR The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and varies from manufacturer to manufacturer. Penetration time of glove material The determined penetration times according to EN 374 part III are not performed under practical conditions. Therefore a maximum wearing time, which corresponds to 50% of the penetration time, is recommended. Value for the permeation: Level 6 The exact break trough time has to be found out by the manufacturer of the protective gloves and has to be observed. Eye protection: Tightly sealed goggles Body protection: Protective work clothing 9 Physical and chemical properties General Information Form: Color: Odor: Powder White Characteristic Change in condition Melting point/melting range: 891 C (1636 F) Boiling point/boiling range: Undetermined. Flash point: Not applicable. Flammability (solid, gaseous): Product is not flammable. Danger of explosion: Product does not present an explosion hazard. Density at 20 C (68 F): g/cm³ (Contd. on page 4)

4 Page 4/6 Bulk density at 20 C (68 F): 750 kg/m³ Solubility in / Miscibility with Water at 20 C (68 F): 1120 g/l ph-value: Alkaline Organic solvents: 0.0 % Solids content: % (Contd. of page 3) 10 Stability and reactivity Thermal decomposition / conditions to be avoided: To avoid thermal decomposition do not overheat. Materials to be avoided: Dangerous reactions No dangerous reactions known. Dangerous products of decomposition: No dangerous decomposition products known. 11 Toxicological information Acute toxicity: Primary irritant effect: on the skin: No irritant effect. on the eye: Irritating effect. Sensitization: No sensitizing effects known. 12 Ecological information Additional ecological information: General notes: Water hazard class 1 (Assessment by list): slightly hazardous for water Do not allow undiluted product or large quantities of it to reach ground water, water course or sewage system. 13 Disposal considerations Product: Recommendation: Must be specially treated adhering to official regulations. Uncleaned packagings: Recommendation: Packaging can be reused or recycled after cleaning. Packagings that cannot be cleansed are to be disposed of in the same manner as the product. Recommended cleansing agent: Water, if necessary with cleansing agents. 14 Transport information DOT regulations: Hazard class: - Land transport ADR/RID (cross-border): ADR/RID class: - Maritime transport IMDG: IMDG Class: - (Contd. on page 5)

5 Page 5/6 Air transport ICAO-TI and IATA-DGR: ICAO/IATA Class: - UN "Model Regulation": - (Contd. of page 4) 15 Regulations Sara Section 355 (extremely hazardous substances): Section 313 (Specific toxic chemical listings): TSCA (Toxic Substances Control Act): Substance is listed. Proposition 65 Chemicals known to cause cancer: Chemicals known to cause reproductive toxicity for females: Chemicals known to cause reproductive toxicity for males: Chemicals known to cause developmental toxicity: Cancerogenity categories EPA (Environmental Protection Agency) IARC (International Agency for Research on Cancer) NTP (National Toxicology Program) TLV (Threshold Limit Value established by ACGIH) MAK (German Maximum Workplace Concentration) NIOSH-Ca (National Institute for Occupational Safety and Health) OSHA-Ca (Occupational Safety & Health Administration) Product related hazard informations: The product has been classified and marked in accordance with directives on hazardous materials. Hazard symbols: Harmful Risk phrases: Harmful if swallowed. Irritating to eyes, respiratory system and skin. Safety phrases: Do not breathe dust. (Contd. on page 6)

6 Page 6/6 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. National regulations: Water hazard class: Water hazard class 1 (Assessment by list): slightly hazardous for water. (Contd. of page 5) 16 Other information This information is based on our present knowledge. However, this shall not constitute a guarantee for any specific product features and shall not establish a legally valid contractual relationship. Department issuing MSDS: Abteilung Umweltschutz Contact: Herr Marcus Müller Abbreviations and acronyms: ADR: Accord européen sur le transport des marchandises dangereuses par Route (European Agreement concerning the International Carriage of Dangerous Goods by Road) RID: Règlement international concernant le transport des marchandises dangereuses par chemin de fer (Regulations Concerning the International Transport of Dangerous Goods by Rail) IMDG: International Maritime Code for Dangerous Goods DOT: US Department of Transportation IATA: International Air Transport Association IATA-DGR: Dangerous Goods Regulations by the "International Air Transport Association" (IATA) ICAO: International Civil Aviation Organization ICAO-TI: Technical Instructions by the "International Civil Aviation Organization" (ICAO) GHS: Globally Harmonized System of Classification and Labelling of Chemicals ACGIH: American Conference of Governmental Industrial Hygienists EINECS: European Inventory of Existing Commercial Chemical Substances CAS: Chemical Abstracts Service (division of the American Chemical Society) NFPA: National Fire Protection Association () HMIS: Hazardous Materials Identification System ()