SAFETY DATA SHEET HİDROLİK FREN YAĞI DOT 4

Transcription

1 Page 1 of 11 SECTION 1 : IDENTIFICATION OF THE SUBSTANCE / MIXTURE AND OF THE COMPANY / UNDERTAKING 1.1 Product identifier 1.2 Relevant identified uses of the substance or mixture and uses advised against Identified uses: Brake Fluid 1.3 Details of the supplier of the safety data sheet MİLAN PETROL SANAYİ VE TİCARET A.Ş Sok. No. 6 A.O.S.B. Çiğli / İZMİR / TURKEY Tel: Faks: e-posta : laboratuvar@moil.com.tr 1.4 Emergency telephone number Milan Petrol : SECTION 2 : HAZARD IDENTIFICATION 2.1 Classification of the substance or mixture Classification according to Regulation ( EC ) No 1272/2008 Reproductive toxicity, Category 2 H361d: Suspected of damaging the unborn child. 2.2 Label elements Label elements according to Regulation ( EC ) No 1272/2008 Pictograms: Signal Words : Warning

2 Page 2 of 11 Hazard Statements: H361d : Suspected of damaging the unborn child. H316 : Causes mild skin irritation EUH208 : Contains Bisphenol A. May produce an allergic reaction. Precautionary Statements: P101: If medical advice is needed, have product container or label at hand. P102: Keep out of reach of children. P201: Obtain special instructions before use. P281: Use personal protective equipment as required. P308+P313: IF exposed or concerned: Get medical attention. P405: Store locked up. 2.3 Other hazards Physical / Chemical Hazards : No significant hazards. Health Hazards : Reproductive toxicity, Category 2 Environmental Hazards : No significant hazards SECTION 3 : COMPOSITION / INFORMATION ON INGREDIENTS 3.1 Substances Not Applicable 3.2 Mixtures Chemical Composition CAS No EC No Concentration Classification Diethylene glycol monomethyl ether %4 Rep.2; H361d 1,2,3-Benzotriazole %0,1 Bisphenol A %0,1 Additional information: The Full Text for all Hazard Statements are Displayed in Section 16 Acute Tox. 4; H302 Eye Irrit. 2A; H319 Aquatic Acute 3; H402 Aquatic Chronic 3; H412 Skin Sens. 1; H317 Eye Dam.1 ; H318 STOT SE 3; H335 Repr. 2; H361f Aquatic Chronic 2; H41

3 Page 3 of 11 SECTION 4: FIRST AID MEASURES 4.1 Description of first aid measures EYE CONTACT : Wash thoroughly with plenty of water. Obtain medical advice if any pain or redness develops or persists. SKIN CONTACT : Wash skin thoroughly with soap and plenty water. Remove heavily contaminated clothing and wash underlying skin. INHALATION: If inhalation of mists, fumes or vapour causes irritation to the nose or throat, or coughing, remove to fresh air. If symptoms persist, obtain medical advice. INGESTION: If contamination the mouth occurs, wash out thoroughly with water. If ingestion occurs large amounts, do not induce vomiting; obtain medical advice of. 4.2 Most important symptoms and effects, both acute and delayed EYE CONTACT: Lacrimatory SKIN CONTACT: Redness, dryness INHALATION INGESTION : Throat irritation, cough : Abdominal pain, vomiting, high concentration loss of consciousness 4.3 Indication of any immediate medical attention and special treatment needed Notes to doctor/physician: Treat symptomatically SECTION 5: FIREFIGHTING MEASURES 5.1 Extinguishing media Suitable extinguishing media: All extinguishing media. Unsuitable extinguishing media : 5.2 Special hazards arising from the substance or mixture Hazardous decomosition products may be formed under fire conditions. Exposure to decompos,tion products may be a hazard to health. 5.3 Advice for firefighters Closed areas, by trained personnel using fire protective clothing and oxygen mask deflated.

4 Page 4 of 11 SECTION 6: ACCIDENTAL RELEASE MEASURES 6.1 Personal precautions, protective equipment and emergency procedures Avoid contact with skin and eyes. Use personal protective equipment. 6.2 Environmental precautions Protect drains from spills and prevent entry of product. 6.3 Methods and material for containment and cleaning up Scrape up bulk of solid material and remove liquid with sand or other suitable inert absorbent material. Spilled product should be isolated from sources of ignition, good ventilation should be provided. Recovery of large spillages should be done by specialist personel. 6.4 Reference to other sections For guidance on selection of personal protective equipment see Chapter 8 of this Safety Data Sheet. For guidance on disposal of spilled material see Chapter 13 of this Safety Data Sheet. SECTION 7: HANDLING AND STORAGE 7.1 Precautions for safe handling Good ventilation should be provided in the environment and should be avoided during use of the inhalation. Skin contact should be avoided and hygienic rules should be applied. Avoid eating, drinking and smoking while using. Wash hands thoroughly after handling. 7.2 Conditions for safe storage, including any incompatibilities Cool, dry and well ventilated storage areas must be kept and should be kept in labeled containers. Be exposed to direct sun rays, should not be stored near heat sources. Store in steel and plastic flasks, steel special containers, tanker trucks, steel and aluminum containers. 7.3 Specific end use(s) Not applicable

5 Page 5 of 11 SECTION 8: EXPOSURE CONTROLS / PERSONAL PROTECTION 8.1 Control parameters Exposure Limit Values: Diethylene glycol monomethyl ether CAS No: Be absorbed deeply TWA: 50,1 mg/m³ TWA: 10 ppm 8 hour 8 hour Bisphenol A CAS No: TWA: 10 mg/m³ 8 hour 8.2 Exposure controls Appropriate engineering controls Provide adequate ventilation in the work area Individual protection measures, such as personal protective equipment Eye protection If contact is likely safety glasses with side shields are recommended. Skin protection Protective clothing should be used. Hand protection Chemical-resistant gloves (nitrile) should be used. Respiratory protection Full face mask with filters A and ABEP, isolating full face mask Environmental exposure controls Take appropriate measures to fulfill the requirements of relevant environmental protection legislation. Do not allow the material to interfere with water pipes, lacrimation and soil.

6 Page 6 of 11 SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES 9.1 Information on basic physical and chemical properties Physical State Colour Odour : Liquid : From light yellow to light brown : Characteristic Flash Point C : 123 ( Method: ASTM D92 ) Explosive properties : Non-explosive Flammability C : 152 ph : 7 11,5 Solubility in Water : Complete 9.2 Other information Data not available SECTION 10: STABILITY AND REACTIVITY 10.1 Reactivity Hydrolysis, etherifying 10.2 Chemical stability Stabile 10.3 Possibility of hazardous reactions 10.4 Conditions to avoid Low temperature, heating, moisture 10.5 Incompatible materials Acids, bases, oxidizers 10.6 Hazardous decomposition products Build-up of dangerous/toxic fumes possible in cases of fire/high temperature: Carbon oxides.

7 Page 7 of 11 SECTION 11: TOXICOLOGICAL INFORMATION 11.1 Information on toxicological effects Acute Toxicity Acute oral toxicity Diethylene glycol monomethylether 1,2,3-Benzotriazole Bisphenol A : LD50 ( mouse ) : mg/kg : LD50 ( rats ) : 500 mg/kg : LD50 ( rats ) : mg/kg Acute inhalation toxicity Acute dermal toxicity Diethylene glycol monomethylether 1,2,3-Benzotriazole Bisphenol A Skin corrosion / irritation Skin irritation : LD50 ( rabbits ) : mg/kg : LD50 ( rabbits ) : >2000 mg/kg : LD50 ( rabbits ) : ca 3000 mg/kg : Non-irritating. Serious eye damage / eye irritation Eye irritation : Non-irritating. Sensitization of the respiratory / skin Skin sensitization : Contains Bisphenol A. May produce an allergic reaction. Respiratory sensitization : Non respiratory sensitizing. Mutagenicity No mutagenic effect. Carcinogenicity No carcinogenic effect. Reproductive toxicity Suspected of damaging the unborn child. Teratogenicity Specific target organ toxicity after single exposure Specific target organ toxicity after repeated exposu ( sub-acute / sub-chronic ) Repeated dose toxicity: ( sub-acute / sub chronic )

8 Page 8 of 11 Aspiration hazard No aspiration hazard. Neurological effects Toxicology, metabolism, distribution SECTION 12: ECOLOGICAL INFORMATION 12.1 Toxicity Toxicity to fish: Diethylene glycol monomethyl ether 1,2,3-Benzotriazole Bisphenol A : LC50 ( Pimephales promelas ) : 5741 mg/l Exposure time : 96 h : LC50 ( Danio rerio ) : 180 mg/l Exposure time : 96 h : LC50 ( Menidia menidia ) : 9,4 mg/l Exposure time : 96 h Toxicity to daphnia and other aquatic invertebrates: Diethylene glycol monomethyl ether 1,2,3-Benzotriazole Bisphenol A : EC50 ( Daphnia magna ) : mg/l Exposure time : 48 h : EC50 ( Daphnia galeata ) : 15,8 mg/l Exposure time : 48 h : EC50 ( Daphnia magna ) : 10,2 mg/l Exposure time : 48 h Toxicity to aquatic plants 1,2,3-Benzotriazole : IC50 (Pseudokirchnerella subcapiata ) : mg/l Exposure time : 72 h Long-term toxicity to fish / daphnia / aquatic plants No data availabale Persistence and degradability Biodegradability : No data avaialable Bioaccumulative potential

9 Page 9 of Mobility in soil 12.5 Results of PBT and vpvb assessment No PBT and no vpvb Other adverse effects The Product should not be allowed to enter drains, water courses or the soil. SECTION 13: DISPOSAL CONSIDERATIONS 13.1 Waste treatment methods Dispose of by incineration or other suitable means under conditions approved by the local authority or via licensed waste disposal contractor. Waste no time to be spilled to the environment and waterways. Dispose of packaging or containers in accordance with local regional national and international regulations. SECTION 14: TRANSPORT INFORMATION 14.1 UN number Not classified as hazardous for transport ( ADR/RID, ADNR, IMDG, ICAO/IATA ) 14.2 UN proper shipping name Not classified as hazardous for transport ( ADR/RID, ADNR, IMDG, ICAO/IATA ) 14.3 Transport hazard class(es) Not classified as hazardous for transport ( ADR/RID, ADNR, IMDG, ICAO/IATA ) 14.4 Packing group Not classified as hazardous for transport ( ADR/RID, ADNR, IMDG, ICAO/IATA ) 14.5 Environmental hazards Not classified as hazardous for transport ( ADR/RID, ADNR, IMDG, ICAO/IATA ) 14.6 Special precautions for user Not applicable 14.7 Transport in bulk according to Annex II of Marpol and the IBC Code Not applicable

10 Page 10 of 11 SECTION 15: REGULATORY INFORMATION 15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture Applicable EU Directives and Regulations: Regulation (EC) No 1907/ REACH Regulation No 1272/2008 CLP ( Regulation on classification, labelling and packaging ) Commission Regulation ( EU ) 2015/830 ECHA Guidance on the compilation of safety data sheets SECTION 16: OTHER INFORMATION Abbreviations and acronyms ADR ADNR RID IMDG ICAO-TI IATA ACGIH ASTM CAS GHS OEL TWA STEL PBT vpvb MARPOL 73/78 : International Carriage of Dangerous Goods by Road : Carriage of Dangerous Goods by Inland Waterways : Regulations Relating to International Carriage of Dangerous Goods by Rail : International Maritime Dangerous Goods : International Civil Aviation Organization - Technical Instructions for the Safe Transport of Dangerous Goods by Air : International Air Transport Association : American Conference of Governmental Industrial Hygienists : American Society for Testing and Materials : Chemical Abstracts Service : Globally Harmonised System of Classification and Labelling of Chemicals : Occupational Exposure Limit : Time-Weighted Average. : Short term exposure limit : Persistent, Bioaccumulative and Toxic : very Persistent and very Bioaccumulative : International Convention for the Prevention of Pollution From Ships Wording of the H-statements in section 2 and 3: H361d H316 H302 H317 H318 H319 H335 H361f H402 H411 H412 : Suspected of damaging the unborn child. : Causes mild skin irritation : Harmful if swallowed. : May cause an allergic skin reaction : Causes serious eye damage : Causes serious eye irritation : May cause respiratory irritation : Suspected of damaging fertility : Harmful to aquatic life : Toxic to aquatic life with long-lasting effects : Harmful to aquatic life with long-lasting effects

11 Page 11 of 11 Full text of other abbreviations Acute Tox. : Acute Toxicity Eye Irrit. : Eye Irritation Aquatic Chronic : Aquatic Chronic Skin Sens. : Skin Sensitive Revision Comments Revised classification. Issued by GBF Preparer Tel : Document Date : Certificate No : GBF Warning The information presented about health safety and environment issues in this safety data sheet was given by considering of best knowledge and reliable sources at the date of its preparation. Although maximum effort was shown, no warranty is expressed or implied regarding the accuracy of these kdata or the results to be obtained from the use thereof. Health and safety precautions and environmental advice noted in this data sheet may not be accurate for all individuals and/or situations. It is the user s obligation to evaluate and use this product safety and to comply with all applicable laws and regulations. No statement made in this data sheet shall be construed as a permission, recomendation or authorization given or implied to practise any patented invention without a valid licence. The MİLAN PETROL SANAYİ ve TİCARET A.Ş. shall not be responsible for any damage or injuru resulting from abnormal use of the material from any failure to adhere to recommendations or from any hazards inherent in the nature of the material.