MATERIAL SAFETY DATA SHEET

Transcription

1 MATERIAL SAFETY DATA SHEET Ferro Corporation 54 Kellogg Court Edison, N.J USA Emergency telephone number CHEMTREC: CHEMTREC (outside U.S.): Phone Number: IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE COMPANY/UNDERTAKING Product Name: Dk Brown W/ UV CAS-No.: Mixture Recommended use: Industrial Use Only Product Code: Date of Preparation: 03/24/ HAZARDS IDENTIFICATION Emergency Overview WARNING May cause respiratory tract, eye and skin irritation. Contains titanium dioxide which may cause lung damage including cancer. Color: Brown Physical Paste state: Odor: Mild Health: Flammability: Physical Hazard: PPE: HMIS 2* 1 0 B NFPA Potential Health Effects Principle routes of exposure: Eye contact: Skin contact: Inhalation: Ingestion: Chronic toxicity: Inhalation, ingestion, skin and eye contact. Contact with eyes may cause irritation. Prolonged skin contact may cause skin irritation. May cause irritation of respiratory tract. May irritate digestive tract. Excessive inhalation of fumes or dust may cause chemical pneumonitis, cyanosis, and pulmonary edema. is listed by IARC as possibly carcinogenic to humans (Group 2B) based on inadequate evidence of carcinogenicity in humans and sufficient evidence in experimental animals. 3. COMPOSITION/INFORMATION ON INGREDIENTS CAS Number Weight % % % Iron Oxide Yellow % % 4. FIRST AID MEASURES Eye contact: Rinse immediately with plenty of water, also under the eyelids. Get medical attention if irritation develops. Product name: Dk Brown W/ UV Page 1 of 5

2 Skin contact: Inhalation: Ingestion: Notes to physician: Wash off immediately with soap and plenty of water. Remove and wash contaminated clothing before re-use. If symptoms persist, call a physician. Move to fresh air. If breathing is difficult, give oxygen. If symptoms persist, call a physician. Drink plenty of water. Do not induce vomiting. Consult a physician if necessary. Treat symptomatically. 5. FIRE-FIGHTING MEASURES Flash point ( C): 100( 212 F) Method: Closed cup Suitable extinguishing media: Hazardous decomposition products under fire conditions: Special protective equipment for firefighters: Unusual hazards: Carbon dioxide (CO2). Dry chemical. Water spray mist or foam. Carbon oxides. Metal compounds. As in any fire, wear self-contained breathing apparatus (pressure-demand, NIOSH approved or equivalent) and full protective gear. None known. 6. ACCIDENTAL RELEASE MEASURES Personal precautions: Environmental precautions: Methods for cleaning up: Remove all non-essential people from the affected area. Ensure adequate ventilation. In case of insufficient ventilation, wear suitable respiratory equipment. Avoid contact with skin, eyes and clothing. Wear personal protective equipment. Prevent further leakage or spillage if safe to do so. Prevent product from entering drains. Do not flush into surface water or sanitary sewer system. Do not allow material to contaminate ground water system. Wear personal protective equipment. Absorb spill with inert material (e.g. dry sand or earth), then place in a chemical waste container. Clean contaminated surface thoroughly. Dispose of promptly. 7. HANDLING AND STORAGE Handling: Handle in accordance with good industrial hygiene and safety practice. Use only in area provided with appropriate exhaust ventilation. In case of insufficient ventilation, wear suitable respiratory equipment. Avoid contact with skin, eyes and clothing. Wear personal protective equipment. Do not eat, drink, or smoke in areas of use or storage. Do not take internally. Wash thoroughly after handling. Storage: Keep in a dry, cool and well-ventilated place. Exposure limits Minimize exposure in accordance with good hygiene practice. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION OSHA PEL ACGIH 15 mg/m 3 TWA total dust 10 mg/m 3 TWA 10 mg/m 3 TWA fume 5 mg/m 3 TWA respirable fraction 15 mg/m 3 TWA total dust 5 mg/m 3 TWA respirable fraction 3.5 mg/m 3 TWA 3 mg/m 3 TWA inhalable fraction Engineering measures: Provide appropriate exhaust ventilation wherever dust, mist, vapors, or fumes can be generated. Ensure that eyewash stations and safety showers are proximal to the work-station location. Product name: Dk Brown W/ UV Page 2 of 5

3 Eye protection: Skin and body protection: Hand protection: Respiratory protection: Hygiene measures: Safety glasses with side-shields. Lightweight protective clothing. Keep working clothes separately. Remove and wash contaminated clothing before re-use. Impervious gloves. Follow the recommendations given by the manufacturer of protective gloves. In case of insufficient ventilation, wear suitable respiratory equipment. NIOSH-approved respirators should be worn where engineering controls and work practices do not reduce exposure to or below the PEL. Seek professional advice prior to respirator selection and use. Wash hands before breaks and at the end of workday. 9. PHYSICAL AND CHEMICAL PROPERTIES Color: Odor: Boiling point/range ( C): Melting point/range ( C): Vapor pressure : VOC content Brown Mild Physical state: Paste Molecular weight: ph: Specific gravity (Water =1): Water solubility: No information available 10. STABILITY AND REACTIVITY Stability: Polymerization Stable at normal ambient temperatures and storage conditions. Will not occur. Hazardous decomposition products: No decomposition if stored normally. Thermal decomposition can lead to release of irritating gases and vapors. Carbon oxides. Metal compounds. Materials to avoid: Conditions to avoid Strong oxidizing agents. Strong acids and strong bases. None known. 11. TOXICOLOGICAL INFORMATION Acute toxicity: Chronic Toxicity: Information given is based on data on the components and the toxicology of similar products In lifetime inhalation studies of rats, airborne respirable size titanium dioxide particles have been shown to cause lung tumors at concentrations associated with substantial particle lung burdens and consequential pulmonary overload and inflammation. However, other laboratory animals such as mice and hamsters did not develop lung tumors under similar testing with titanium dioxide. Human epidemiology studies do not suggest an association between occupational exposure to titanium dioxide and risk for cancer. NIOSH - Pocket Guide - Target Organs Respiratory system. respiratory system eyes skin eyes respiratory system Component information, if any, is listed below OSHA - Select Carcinogens: IARC - Group 2B: Oral LD50 (Rat) = mg/kg Present Listed Oral LD50 (Rat) = mg/kg Product name: Dk Brown W/ UV Page 3 of 5

4 OSHA - Select Carcinogens: IARC - Group 2B: Oral LD50 (Rat) = mg/kg Dermal LD50 (Rabbit) = 3 g/kg Present Listed 12. ECOLOGICAL INFORMATION Aquatic toxicity: No data is available on the product itself. Information given is based on data on the components and the ecotoxicology of similar products. Ecotoxicity - Water Flea Data: 24 h EC50 (Daphnia magna) = 5600 mg/l Persistence and degradability: No information available. 13. DISPOSAL CONSIDERATIONS Waste from residues / unused products: DOT (U.S.) Proper shipping name: Waste must be disposed of in accordance with federal, state and local environmental control regulations. Where possible recycling is preferred to disposal or incineration. 14. TRANSPORT INFORMATION TDG (Canada) Proper Shipping Name IMDG Proper Shipping Name IATA Proper shipping name U.S. Regulations: TSCA: 15. REGULATORY INFORMATION Not subject to TSCA 12(b) Export Notification SARA 313: Not subject to the provisions of SARA 313 Title III State Regulations This product or its ingredients have been evaluated for New Jersey, Pennsylvania, and California Prop 65 supplier notification requirements. Substances that are subject to notification requirements, if any, are listed below. Product name: Dk Brown W/ UV Page 4 of 5

5 NJRTK: 1036 Listed (NJRTK) Listed (NJRTK) State Regulation - CA Prop65 Carcinogen Carcinogen Canadian WHMIS WHMIS hazard class: D2A Very toxic materials D2B Toxic materials Canadian Ingredient Disclosure List (IDL): WHMIS Ingredient Disclosure: 1% 1 International Inventories U.S. EPA TSCA 8(b): Canada DSL/NDSL list Europe (EINECS): Philippines (PICCS): Japan (ENCS): Korea (KECL): China (IECS): Australia (AICS): New Zealand (NZloC): Listed or exempt. One or more ingredient(s) are not listed on the DSL or NDSL list. One or more ingredient(s) are not on the EINECS list. One or more ingredient(s) are not on the PICCS list. One or more ingredient(s) are not on the ENCS list. One or more ingredient(s) are not on the KECL list. One or more ingredient(s) are not on the IECS list. One or more ingredient(s) are not on the AICS list. One or more ingredient(s) are not on the NZloC list. 16. OTHER INFORMATION For Industrial Use Only. Prepared by: Ferro Technical Center Disclaimer: The information and recommendations contained in this Material Safety Data Sheet have been compiled from sources believed to be reliable and to represent the most reasonable current opinion on the subject when the MSDS was prepared. No warranty, guaranty or representation is made as to the correctness or sufficiency of the information. The user of this product must decide what safety measures are necessary to safely use this product, either alone or in combination with other products, and determine its environmental regulatory compliance obligations under any applicable federal or state laws. End of Safety Data Sheet Product name: Dk Brown W/ UV Page 5 of 5