Section 1: Identification of the Substance/Mixture and of the Company Undertaking

Transcription

1 Page 1 of 7 Section 1: Identification of the Substance/Mixture and of the Company Undertaking Product identifier used on the label: Product Name: M9 Cleaner/Decrystallizer Other means of identification: Product Codes: Manufacturer MSDS Number: Recommended use of the chemical and restrictions on use: Product Uses: Cleans and aids in deodorization urinary systems Do not use on wounds or take internally. Product Restrictions: Chemical manufacturer address and telephone number: Manufacturer Name: Hollister Incorporated Manufacturer Address 1: Manufacturer City: Manufacturer State: Cleans and aids in deodorization urinary systems Do not use on wounds or take internally Hollister Drive Libertyville Illinois Manufacturer Zip Code: Manufacturer Country: Manufacturer Web: USA Business Phone: Emergency phone number: Emergency Phone: Revision Date: 12/17/2018 Section 2: Hazards Identification Classification of the chemical in accordance with CFR (d)(f): Signal Words: Emergency Overview: Warning. WARNING! Irritant. GHS Class: Eye Irritant, Category 2. Hazard Statements: Precautionary Statements: H320 - Causes eye irritation. P305+P351+P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P337+P313 - If eye irritation persists: Get medical advice/attention. Hazards not otherwise classified that have been identified during the classification process: M9 Cleaner/Decrystallizer Hollister Incorporated 12/17/2018 Page 1 of 7

2 Section 3: Composition/Information on Ingredients Page 2 of 7 Mixtures: Ingredient Name CAS Number Ingredient Percent EC Number Comments Bronopol <=2.5% by weight Sodium Aceta te <=2.5 % by weight Non ha za rdous ingredient(s ) No da ta >95% by weight Section 4: First Aid Measures Description of necessary measures: Eye Contact: Immediately flush eyes with plenty of water for at least 15 to 20 minutes. Ensure adequate flushing of the eyes by separating the eyelids with fingers. Get immediate medical attention. Skin Contact: Inhalation: Ingestion: Immediately wash skin with plenty of soap and water for 15 to 20 minutes, while removing contaminated clothing and shoes. Get medical attention if irritation develops or persists. If inhaled, remove to fresh air. If not breathing, give artificial respiration or give oxygen by trained personnel. Seek immediate medical attention. If swallowed, do NOT induce vomiting. Call a physician or poison control center immediately. Never give anything by mouth to an unconscious person. Most important symptoms/effects, acute and delayed: Other First Aid: First Responders should provide for their own safety prior to rendering assistance. Indication of immediate medical attention and special treatment needed Note To Physicians: None. Section 5: Firefighting Measures Suitable and unsuitable extinguishing media Extinguishing Media: Use dry chemical or foam when fighting fires involving this material. Water mist may be used to cool closed containers. Specific hazards arising from the chemical Unusual Fire Hazards: Material may spatter above 100 C/212 F. Special protective equipment and precautions for fire-fighters Fire Fighting Instructions: Evacuate area of unprotected personnel. Use cold water spray to cool fire exposed containers to minimize risk of rupture. Do not enter confined fire space without full protective gear. If possible, contain fire run-off water. Protective Equipment: NFPA Health: 1 NFPA Fire: 0 NFPA Reactivity: 0 In the event of a fire, wear Self-Contained Breathing Apparatus (SCBA), approved or in accordance to NFPA, NIOSH, and/or European Standard EN 137 guidelines or equivalent and full protective gear. Section 6: Accidental Release Measures Personal precautions, protective equipment and emergency procedures M9 Cleaner/Decrystallizer Hollister Incorporated 12/17/2018 Page 2 of 7

3 Personnel Precautions: Evacuate area and keep unnecessary and unprotected personnel from entering the spill area. Methods and materials for containment and cleaning up Methods for Containment: Spills are very unlikely, because the wiper fabric has absorbed the liquid solvent solution. In the event of a spill, contain with an inert absorbent. Methods for Cleanup: Environmental precautions Environmental Precautions: Absorb spill with inert material (e.g., dry sand or earth), then place in a chemical waste container. Provide ventilation. Clean up spills immediately observing precautions in the protective equipment section. Avoid runoff into storm sewers, ditches, and waterways. Comply with all government regulations on reporting releases. Page 3 of 7 Section 7: Handling and Storage Precautions for safe handling Handling: Work Practices: Hygiene Practices: Use with adequate ventilation. Avoid breathing vapor, aerosol or mist. Handle in accordance with good industrial hygiene and safety practices. Wash thoroughly after handling. Conditions for safe storage, including any incompatibilities Storage: Store in a cool, dry, well ventilated area away from sources of heat, combustible materials, and incompatible substances. Keep container tightly closed when not in use. Section 8: Exposure Controls/Personal Protection Exposure Guidelines Appropriate engineering controls Engineering Controls: Use appropriate engineering control such as process enclosures, local exhaust ventilation, or other engineering controls to control airborne levels below recommended exposure limits. Good general ventilation should be sufficient to control airborne levels. Where such systems are not effective wear suitable personal protective equipment, which performs satisfactorily and meets OSHA or other recognized standards. Consult with local procedures for selection, training, inspection and maintenance of the personal protective equipment. Individual protection measures Eye Protection: Face Protection: Skin Protection: Hand Protection: Respiratory Protection: Other Protective: Safety glasses with side shields must be worn at all times. If splash hazard exists, wear chemical splash goggles and/or face shield. Safety glasses with side shields must be worn at all times. If splash hazard exists, wear chemical splash goggles and/or face shield. Wear appropriate protective gloves and other protective apparel to prevent skin contact. Consult manufacturer's data for permeability data. Nitrile rubber or natural rubber gloves are recommended. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.,comply with the OSHA respirator regulations found in 29 CFR or European Standard EN 149,Use a positive pressure air supplied respirator if there is any potential for an uncontrolled release, exposure levels are not known, or any other circumstances where air purifying respirators may not provide adequate protection. Facilities storing or utilizing this material should be equipped with an eyewash and a deluge shower safety station. M9 Cleaner/Decrystallizer Hollister Incorporated 12/17/2018 Page 3 of 7

4 Hygiene Practices: Wash thoroughly after handling. Page 4 of 7 Section 9: Physical and Chemical Properties Physical and chemical properties Physical State: Physical State Appearance : Liquid. Odor: Characteristic ph: Melting Temperature: Boiling Temperature: 190 F (88 C) Flash Point: Not applicable. Ignition Temperature: Not applicable. Lower Flammable Limit: Not applicable. Upper Flammable Limit: Not applicable. Vapor Pressure: C Vapor Density: Solubility: Completely soluble Specific Gravity: 1.0 Evaporation Rate: Percent Volatile: VOC Content: 5.1% Odor Threshold: Section 10: Stability and Reactivity Reactivity: Chemical Stability: Chemical Stability: Stable under recommended handling and storage conditions. Possibility of hazardous reactions: Hazardous Polymerization: Hazardous polymerization does not occur. Conditions To Avoid: Conditions To Avoid: Incompatible Materials: Incompatible Materials: Hazardous Decomposition Products: Heat, flames, ignition sources, and sparks. Incompatible materials. Freezing or temperatures below 0 C (32 F). Water reactive materials. Thermal decomposition can lead to release irritant fumes and toxic gases. Section 11: Toxicological Information Toxicological Information: Route of Exposure: Eyes. Skin. Inhalation. M9 Cleaner/Decrystallizer Hollister Incorporated 12/17/2018 Page 4 of 7

5 Target Organ Data: Eyes. Skin. Respiratory system. Digestive system. Acute Inhalation Effects: Acute Skin Effects: Acute Ingestion Effects: Acute Eye Effects: Bronopol: Eye Toxicity: Prolonged or excessive inhalation may cause respiratory tract irritation. May cause irritation. Ingestion can cause gastrointestinal irritation, nausea, vomiting and diarrhea. May cause irritation. Administration into the eye - Rabbit Standard Draize test : 5 mg [ Not reported. ] (RTECS) Skin Toxicity: Administration onto the skin - Mouse LD50 - Lethal dose, 50 percent kill : 4750 mg/kg [ Details of toxic effects not reported other than lethal dose value ] Administration onto the skin - Rabbit TDLo - Lowest published toxic dose : 250 mg/k g/8h [ Skin and Appendages - Primary irritation (After topical exposure ) ] Administration onto the skin - Rabbit LD50 - Lethal dose, 50 percent kill : >2000 mg/kg [ Details of toxic effects not reported other than lethal dose value ] Administration onto the skin - Rat TDLo - Lowest published toxic dose : >2000 mg/kg/24h [ Lungs, Thorax, or Respiration - Dyspnea Skin and Appendages - Primary irritation (After topical exposure ) Nutritional and Gross Metabolic - Weight loss or decreased weight gain ] Administration onto the skin - Rat LD50 - Lethal dose, 50 percent kill : 64 mg/kg [ Details of toxic effects not reported other than lethal dose value ] Administration onto the skin - Rabbit Standard Draize test : 500 mg/24h [ Mild ] Administration onto the skin - Rabbit Standard Draize test : 80 mg [ Moderate ] Administration onto the skin - Rat Standard Draize test : 0.2 % ( RTECS) Ingestion Toxicity: Oral - Rat LD50 - Lethal dose, 50 percent kill : 180 mg/kg [ Details of toxic effects not reported other than lethal dose value ] Oral - Mouse LD50 - Lethal dose, 50 percent kill : 270 m g/kg [ Details of toxic effects not reported other than lethal dose value ] Oral - Mouse LD50 - Lethal dose, 50 percent kill : 194 mg/kg [ Lungs, Thorax, or Respiration - Othe r changes Gastrointestinal - Gastritis ] Oral - Rat LD50 - Lethal dose, 50 percent kill : 267 mg/kg [ Lungs, Thorax, or Respiration - Othe r changes Gastrointestinal - Gastritis ] Oral - Rabbit LD50 - Lethal dose, 50 percent kill : 190 mg/kg [ Lungs, Thorax, or Respiration - Othe r changes Gastrointestinal - Gastritis ] Oral - Rat LD50 - Lethal dose, 50 percent kill : 254 mg/kg [ Behavioral - Coma Lungs, Thorax, or Respiration - Respiratory depression Blood - Changes in spleen ] Oral - Rat LD50 - Lethal dose, 50 percent kill : 342 mg/kg [ Behavioral (RTECS) Inhalation Toxicity: Inhalation - Rat LC50 - Lethal concentration, 50 percent kill : >5 gm/m 3/6H [ Details of toxic effects not reported other than lethal dose value ] Inhalation - Rat LC50 - Lethal concentration, 50 percent kill : 800 mg/m 3/4H [ Details of toxic effects not reported other than lethal dose value ] Inhalation - Rat LC50 - Lethal concentration, 50 percent kill : >5 gm /m 3/4H [ Details of toxic effects not reported other than lethal dose value ] (RTECS) Page 5 of 7 Section 12: Ecological Information Ecotoxicity: Ecotoxicity: Persistence and degradability: Environmental Fate: No environmental information found for this product. No environmental information found for this product. M9 Cleaner/Decrystallizer Hollister Incorporated 12/17/2018 Page 5 of 7

6 Section 13: Disposal Considerations Page 6 of 7 Description of waste: Waste Disposal: Consult with the US EPA Guidelines listed in 40 CFR Part or the EU Directive 2008/98/EC on waste for the classifications of hazardous waste prior to disposal. Furthermore, consult with your state, local, or provincial waste requirements or guidelines, if applicable, to ensure compliance. Arrange disposal in accordance to the EPA and/or state and local guidelines. Section 14: Transport Information DOT Shipping Name: DOT UN Number: Notes from Section 14: Not Restricted Not Applicable The data provided in this section is for information only. Please apply the appropriate regulations to properly classify your shipment. Section 15: Regulatory Information Safety, health and environmental regulations specific for the product: Regulatory - Product Based: California POP 65: Canada WHMIS: SARA: Regulatory - Ingredient Based: Bronopol: TSCA Inventory Status: The following statement(s) are provided under the California Safe Drinking Water and Toxic Enforcement Act of 1986 (Proposition 65):,This product does not contain any Proposition 65 chemicals. Xi - Irritant. This product does not contain any chemicals which are subject to the reporting requirements of the Superfund Amendments and Reauthorization Act of 1986 (SARA) Title III (40CFR, Part 372). Listed EC Number: Sodium Acetate: TSCA Inventory Status: Listed EC Number: Section 16: Additional Information Issue Date: 01/22/2015 Revision Date: 12/17/2018 Revision Notes: "" M9 Cleaner/Decrystallizer Hollister Incorporated 12/17/2018 Page 6 of 7

7 Disclaimer: Copyright: HMIS: Health 1 NFPA: This product is exempt from Safety Data Sheet regulations as the product is for consumer use. The information contained in this Safety Data Sheet (SDS) is offered as a guide to the use and handling of this material. All safety aspects of all Hollister products are thoroughly evaluated prior to commercialization. This SDS has been prepared in good faith by technically knowledgeable personnel. Hollister Incorporated shall not be held liable for any damages, losses or injuries of any nature which may result from the use of or reliance upon any information contained in this SDS. Each individual should make a determination as to the suitability of the information for his or her particular purpose(s). Copyright Actio Corporation. All Rights Reserved. Flammability 0 Reactivity 0 PPE X Chronic Health Hazard Page 7 of 7 Other Information: Copyright Enviance Inc. All Rights Reserved. M9 Cleaner/Decrystallizer Hollister Incorporated 12/17/2018 Page 7 of 7