Safety Data Sheet According to Regulation (EC) No. 1907/2006

Transcription

1 01. Product and company identification Trade name: Use of the substance/preparation Chemical fixing EC market placer (manufacturer/importer or distributor) KALM Befestigungssysteme GmbH Street Marie-Curie-Straße 5 Country/Postcode/City D Kaiserslautern Information contact Section Sales International Telephone / Telefax / / / info@kalm.de Emergency telephone Hazards identification R-43: May cause sensitisation by skin contact Hazard symbols: Irritant 03. Composition/information on ingredients Chemical characterization

2 Hazard(ous) ingredients Hazard ingredient CAS no. Risk and safety sentences Content Sterene Xn; R /38 < 12,5 % Dibenzoyl peroxide Xi, E; R < 5% The Risk and safety sentences are written down completely in chapter First aid measures General information Change soaked clothing Inhalation Ensure supply of fresh air In the events of symptoms seek for medical treatment Skin contact In case of contact with skin wash off immediately with soap and water. Consult a doctor if skin irritation persists. Eye contact In case of contact with eyes rinse thoroughly with plenty of water and seek medical advice. Ingestion Not applicable Advice for doctor Treat symptomatically. 05. Fire-fighting measures Suitable extinguishing media Water spray jet, Dry powder, Foam, Carbon dioxide (CO 2 ) Extinguishing media that must not be used Full water jet Special exposure hazards arising from the substance or preparation itself or combustion products Maybe toxic pyrolysis products, which can sink down to the bottom of the room.

3 Special protective equipment for fire-fighters Use self-contained breathing apparatus Additional information Fire residues and contaminated fire fighting water must be disposed of in accordance within the local regulations 06. Accidental release measures Personal precautions Risk of slipping due to leakage/spillage of product Environmental precautions Do not discharge into the drains/surface waters/groundwaters Methods of cleaning up Take up mechanically. Dispose of absorbed material in accordance within the regulations Additional Information None 07. Handling and storage Advice of safe handling No special measures necessary if used correctly Advice on protection against fire and explosion No special measures necessary Additional information None Requirements for storage rooms Protect against heat/overheating (max. 25 C) Protect from the sun Storage class VCI : Not applicable

4 08. Exposure controls/personal protection Ingredients with occupational exposure limits to be mentioned Work area limits (AGW) Germany Ingrediant EG-Nr. Limit Factor Source / (mg/m³) Styrol (II) DFG (01/06) Dibenzoylperoxid E 1 (I) DFG (01/06) Respiratory protection: not applicable Hand protection: protective gloves Eye protection: safety glasses Skin protection: not applicable General protective measures: Avoid contact with eyes and skin. Do not inhale vapours Hygiene measures: At work - Do not eat, drink or smoke Before intermissions or after work - Wash hands Delimitation and monitoring of the environmental exposition Not applicable 09. Physical and chemical properties Form: Glass capsule Colour : brown Odour : characteristic Security relevant data Hazard of explosion: not applicable Lower explosion limit : not applicable Upper explosion limit : not applicable Vapour pressure : not applicable Density : not applicable Solubility in water : insoluble ph-value : not determinated Flashpoint : not determinated

5 Ignition point : not determinated 10. Stability and reactivity Hazardous reactions Under normal conditions is the product stable Keep away form high temperature and sun Hazardous decomposition products No Hazardous decomposition products known 11. Toxical information Ingredient CAS-no. Way of exposition Resultat Dosis Sterene Oral LD mg/kg (rattus) Dibenzoyl Oral LD 50 > 5000 mg/kg (rattus) peroxide Inhalativ LD 50 / 4h > 24,3 mg/kg (rattus) General Information Chronical Hazards: No information about chronical hazards available. 12. Ecological information Ingredient CAS-Nr. Resultat Species Dosis Exposition Styrol LC50 Lepomis 25 mg/l 96 h macrochirus LC50 Pimephales promelas h EC50 IC50 Daphnia magna Selenastrum capr. 4,7 48 h 0,72 96 h EC50 Mikro-tox-test 5,5 5 min Dibenzoylperoxid EC50 LC50 bacteria 35 mg/l daphnia 2,91 mg/l 48 h Poecilia 2,0 mg/l 96 h reticulata

6 Behaviour in a sewage plant: Introducing lower concentrations in adapted biological Purification plants will not probably affect the dismantling activities of purification mud. Not soluble -> do not introduce into biological purification plants and waters of the environment without special treatments. General information Ecological data are not available 13. Disposal considerations Non-cured Must be disposed of by special means, e.g. suitable incineration, in accordance with local regulations. Cured Can be dumped with domestic or incinerated in suitable plant in accordance with local Regulations. Packaging Uncontaminated packaging may be taken for recycling. Packaging that can not be cleaned should be disposed of as for product. 14. Transport information No dangerous good complied with the regulations Classification According to ADR: KEIN GEFAHRGUT According to IMDG: NOT CLASSIFIED AS DANGEROUS GOODS According to IATA: NOT CLASSIFIED AS DANGEROUS GOODS 15. Regulatory information Chemical safety report Not applicable Labelling The product is classified and labelled in accordance within EC-directives Hazard symbols

7 Irritant R-43: May cause sensitisation by skin contact Contains Sterene Dibenzoyl peroxide EC-regulations 1967/548(2004/73,29.ATP), 1991/689(2001/118), 1999/13, 2004/42, 684/2004, 1907/2006 National regulations Gefahrstoffverordnung GefStoffV 2004, Wasch- und Reinigungsmittelgesetz WRMG, Wasserhaushaltsgesetz WHG, TRG 300, TRGS: 200, 220, 615, 900, 905 Water hazard classification Class : 1, acc. VwVwS of (date 2009) Technical advice national air carrier (TA-Luft) 3. resin Authorisation None Restrictions Yes 16. Other information Tariff R-phrases R2: Risk of explosion by shock, fire or other sources of ignition R10: Flammable

8 R20: Harmful by inhalation R-36: Causes eye irritation R-36/38: Irritating to eyes and skin R-43: May cause sensitisation by skin contact S-phrases S-2: Keep out of the reach of children S24: Avoid contact with skin S : Wear suitable protection clothing, gloves and eye/face protection S-46: If swallowed seek medical advice immediately and show container or label. Modifications to previous version First draft General information This information is based on our present state of knowledge. They describe our product in view of the requirements for safety. They do not assure of certain properties of the product. A legal relationship is not vested. Duplication without charges of the original versions permitted. KALM Befestigungssysteme GmbH Marie-Curie-Str. 5 D Kaiserslautern GERMANY