according to Regulation (EU) No. 1907/2006 RAKU-TOOL PF Product code : E Print date : Page 1 of 5

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1 Print date : Page 1 of 5 1. Identification of the substance/preparation and of the company/undertaking Identification of the substance or preparation Use of the substance/preparation Polyol component for polyurethane manufacture Company/undertaking identification Manufacturer Company name: Street: Place: RAMPF Tooling GmbH & Co. KG Robert-Bosch-Str D Grafenberg Telephone: +49(0) Telefax: +49(0) Emergency telephone: 2. Hazards identification Classification info@rampf-tooling.de Emergency telephone : ++49 (0) 6132 / GBK Gefahrgut Buero GmbH, Ingelheim This preparation is not classified as dangerous according to Directive 1999/45/EC. 3. Composition/information on ingredients Chemical characterization ( Mixture ) Formulation of polyols Hazardous components EC-No. CAS-No. Chemical name Quantity Classification polypropylenglycol % Xn R Destillate (Erdöl), mit Wasserstoff 2,5-5,0 % Xn R65-66 behandelte leichte Full text of each relevant R phrase can be found in heading First aid measures General information Remove contaminated soaked clothing immediately. In the event of persistent symptoms receive medical treatment. After inhalation Move to fresh air in case of accidental inhalation of vapours. In the event of symptoms refer for medical treatment. After contact with skin Wash off immediately with soap and plenty of water. Treat subsequently with skin cream. Consult a doctor if skin irritation persists. After contact with eyes Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes.

2 Print date : Page 2 of 5 Seek medical treatment by eye specialist. After ingestion Never give anything by mouth to an unconscious person. Summon a doctor immediately. Induce vomiting only upon the advice of a physician. 5. Fire-fighting measures Suitable extinguishing media Foam, carbon dioxide (CO2), dry chemical, water-spray. Extinguishing media which must not be used for safety reasons Full water jet Special exposure hazards arising from substance or preparation itself, combustion products, resulting gases Fire may produce: Carbon monoxide and carbon dioxide. Special protective equipment for fire-fighters Protective suit Use breathing apparatus with independent air supply. 6. Accidental release measures Personal precautions In case of vapour formation use respirator. Ensure adequate ventilation. Use personal protective clothing. Keep away from sources of ignition - No smoking. Environmental precautions Clean contaminated surface thoroughly. Do not discharge into the drains/surface waters/groundwater. Methods for cleaning up/taking up Soak up with inert absorbent material (e.g. sand, silica gel, acid binder, universal binder). After taking up the material dispose according to regulation. 7. Handling and storage Handling Advice on safe handling Keep container tightly closed. Provide sufficient air exchange and/or exhaust in work rooms. Avoid contact with skin, eyes and clothing. Storage Requirements for storage rooms and vessels Keep container tightly closed in a dry, cool and well-ventilated place. Protect against direct sun radiation. Further information on storage conditions Keep away from food, drink and animal feeding stuffs. Avoid temperatures above 50 C. Storageclass (VCI): 8. Exposure controls/personal protection 10

3 Print date : Page 3 of 5 Exposure limit values Exposure controls Occupational exposure controls Ensure adequate ventilation, especially in confined areas. Provide appropriate exhaust ventilation at machinery. Protective and hygiene measures Do not inhale vapours. Wash hands before breaks and immediately after handling the product. When using, do not eat, drink or smoke. Avoid contact with skin, eyes and clothing. Remove and wash contaminated clothes before re-use. Respiratory protection Use suitable breathing apparatus if there is inadequate ventilation. Hand protection Chemical-resistant gloves (EN 374) Suitable materials also for extended, direct contact (recommended: protection index 6, corresponding to a permeation rate > 480 minutes according to EN 374): butyl rubber (Butyl) - = 0.7 mm thickness; i.e. < Butoject 898> made by KCL. Nitrile rubber (Nitrile) mm thickness : i.e.<camatril Velours 730> made by KCL. Because of the great variety of glove types, the manufacturer s instructions for use must be adhered to. The data given refer to information from glove manufacturers or have been assessed by analogy to similar materials. It should be taken into consideration, that due to the great number of influential factors such as the temperature, the daily durability of chemicals resistant protective gloves may be considerably reduced in practice, compared to the permeation rate assessed according to EN 374. Eye protection Tightly fitting goggles / Face shield Skin protection Light protective clothing, Safety Shoes 9. Physical and chemical properties General information Physical state: Colour: Odour: Liquid white Characteristic Important health, safety and environmental information ph-value: Changes in the physical state Boiling point: Flash point: Water solubility: Viscosity / dynamic: (at 25 C) Test method n.a. > 200 C DIN > 100 C 0,95 g/cm³ ISO 2811 immiscible 85 mpa s ISO 9371

4 Print date : Page 4 of Stability and reactivity Conditions to avoid To avoid thermal decomposition, do not overheat. Hazardous decomposition products Carbon monoxide Additional information No decomposition if stored and applied as directed. Exothermic reaction with: Isocyanates 11. Toxicological information Acute toxicity PPG CAS LD50/oral/rat = < 2000mg/kg LD50/dermal/rabbit = >2000 mg/kg Corrosive and irritant effects Analogous to product of similar composition. : Eye irritation: Slightly irritating Skin irritation: Slightly irritating Sensitising effects No persistent or cumulative effects were observed. Further information 12. Ecological information Ecotoxicity The product was classified on the basis of the calculation procedure of the preparation directive (1999/45/EC). No data available. Further information Do not flush into surface water or sanitary sewer system. 13. Disposal considerations Advice on disposal Where possible recycling is preferred to disposal. Can be incinerated, when in compliance with local regulations. It is not possible to give this product a waste code number according to the European waste catalogue because only the intended use of the user consents the assignment of a specific code number. The waste code number must be agreed with the disposer / manufacturer / competent authority. Contaminated packaging Contaminated packagings are to be treated like the product itself. Contaminated packaging should be emptied as far as possible and after appropriate cleansing may be taken for reuse. Packaging that cannot be cleaned should be disposed of like the product. 14. Transport information

5 Print date : Page 5 of 5 Marine transport UN number: IMDG code: Marine pollutant: Hazard label: IMDG packing group: EmS: Limited quantity: Yes 9 III F-A, S-F 5 L Description of the goods ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. Other applicable information (marine transport) Special Provision: 274, 909 E1 15. Regulatory information Labelling Additional advice on labelling EU regulatory information The product does not require a hazard warning label in accordance with EC directives/the relevant national laws. 1999/13/EC (VOC): National regulatory information Water contaminating class (D): VOC (CH) 0,00% VOC (EU) 9,80% 1 - slightly water contaminating 16. Other information Full text of R-phrases referred to under sections 2 and 3 22 Harmful if swallowed. 65 Harmful: may cause lung damage if swallowed. 66 Repeated exposure may cause skin dryness or cracking. Further Information Data of items 4 to 8, as well as 10 to 12, do partly not refer to the use and the regular employing of the product (in this sense consult information on use and on product), but to liberation of major amounts in case of accidents and irregularities. The information describes exclusively the safety requirements for the product (s) and is based on the present level of our knowledge. The delivery specifications are contained in the corresponding product sheet. This data does not constitute a guarantee for the characteristics of the product(s) as defined by the legal warranty regulations. "(n.a. = not applicable; n.d. = not determined)" (The data for the hazardous ingredients were taken respectively from the last version of the sub-contractor's safety data sheet.)