Safety Data Sheet. according to Regulation (EC) No 1907/2006. Heim-Ex

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1 Page 1 of 6 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Further trade names PL-12/87 Product group: Zulieferprodukt 1.2. Relevant identified uses of the substance or mixture and uses advised against Use of the substance/mixture As agent in fire extinguishers (fire-extinguishing compound) 1.3. Details of the supplier of the safety data sheet Company name: Street: Gartenfeldstr. 14 Place: D Weilburg-Gaudernbach Telephone: / Telefax: 06471/ info@brandschutzheimlich.de Contact person: Sebastian Schrankel Telephone: / Internet: se@brandschutzheimlich.de Emergency telephone number: SECTION 2: Hazards identification 2.1. Classification of the substance or mixture 2.2. Label elements Giftinformationszentrum-Nord der Universität Göttingen Tel.:+49 (0) The preparation is not dangerous in the sense of Directive 1999/45/EC. Hazardous components which must be listed on the label Not classified according to regulation 1999/45/EC in the valid setting. SECTION 3: Composition/information on ingredients 3.2. Mixtures Chemical characterization Watery mixture SECTION 4: First aid measures 4.1. Description of first aid measures General information Change contaminated clothing. After inhalation Provide fresh air. Contact a doctor with permanent symptoms. After contact with skin The product generally isn't skin charming. After contact with skin, wash immediately with plenty of water and soap. After contact with eyes If product gets into the eye, keep eyelid open and rinse immediately with large quantities of water, for at

2 Page 2 of 6 least 5 minutes. Subsequently consult an ophthalmologist. After ingestion Rinse mouth immediately and drink large quantities of water. Contact a doctor with permanent symptoms Most important symptoms and effects, both acute and delayed 4.3. Indication of any immediate medical attention and special treatment needed SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media The product itself is not combustible. Extinguishing materials should be selected according to the surrounding area. Extinguishing media which must not be used for safety reasons No data available 5.2. Special hazards arising from the substance or mixture Carbon monoxide. Carbon dioxide (CO2) Advice for firefighters In case of fire: Wear self-contained breathing apparatus. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures Provide adequate ventilation. Avoiding eye contact Environmental precautions Do not empty into drains or the aquatic environment Methods and material for containment and cleaning up Provide adequate ventilation. Absorb with liquid-binding material (e.g. sand, diatomaceous earth, acid- or universal binding agents). Remove mechanically, placing in appropriate containers for disposal. Disposing of the taken material as instructed Reference to other sections Information about the safe handling see section 7. Information about the personal protective equipment see section 8. Information about the disposal see section 13. SECTION 7: Handling and storage 7.1. Precautions for safe handling Advice on safe handling Provide for sufficient ventilation and punctiform suction at critical points. Avoiding skin contact which is longer lasting/repeated. Advice on protection against fire and explosion No special fire protection measures are necessary Conditions for safe storage, including any incompatibilities Requirements for storage rooms and vessels Storage according to endangering water class (see section 15).

3 Page 3 of 6 Advice on storage compatibility irrelevant Further information on storage conditions Keep container tightly closed in a cool, well-ventilated place Specific end use(s) SECTION 8: Exposure controls/personal protection 8.1. Control parameters 8.2. Exposure controls Occupational exposure controls None job limit values which can be supervised admits. Protective and hygiene measures Wash hands before breaks and at the end of work. Protect skin by using skin protective cream. Do not eat, drink, smoke or sneeze at the workplace. Keep away from food, drink and animal feedingstuffs. Respiratory protection At short time or low load using a breath filtration device, at intensive or longer outline using an air recycling independent breathing apparatus. Hand protection Chemical constant protective gloves (EN 374) Notice the information on permeabilities and by break times from the glove manufacturer and the special conditions at work. Eye protection Wear eye/face protection. Skin protection Using a personal protective clothing. Selecting body protective substance into dependence of activity and possible influence. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state: Colour: Odour: liquid clear odourless ph-value (at 20 C): 7,8-7,9 Changes in the physical state Melting point: Boiling point: Flash point: Explosive properties not explosive. Lower explosion limits: Upper explosion limits: -10 C 100 C not applicable Test method

4 Page 4 of 6 Oxidizing properties not self-inflammable Vapour pressure: (at 20 C) Density (at 20 C): Water solubility: Partition coefficient: Viscosity / dynamic: Viscosity / kinematic: Vapour density: Evaporation rate: 9.2. Other information SECTION 10: Stability and reactivity Chemical stability No decomposition if used according to specifications Possibility of hazardous reactions No dangerous reactions known at determination-like use Conditions to avoid Incompatible materials Oxidizing agents, strong Hazardous decomposition products Carbon monoxide. Carbon dioxide. SECTION 11: Toxicological information Information on toxicological effects Acute toxicity No data available Irritation and corrosivity Irritant effect on the skin: Not an irritant. Irritant effect on the eye: may cause irritation. 23 hpa 1,16 g/cm³ complete miscible Further information The product doesn't cause any effects bad for health on proper dealing and use as agreed. SECTION 12: Ecological information Toxicity Aquatoxicity Persistence and degradability Bioaccumulative potential Mobility in soil

5 Page 5 of Results of PBT and vpvb assessment Not applicable Other adverse effects SECTION 13: Disposal considerations Waste treatment methods Advice on disposal Carry out a burning of harzardous waste according to official regulations. Observe regulations when disposing. Hand over to officially registered waste disposal company. Waste disposal number of waste from residues/unused products WASTES NOT OTHERWISE SPECIFIED IN THE LIST; off-specification batches and unused products; organic wastes other than those mentioned in Waste disposal number of used product WASTES NOT OTHERWISE SPECIFIED IN THE LIST; gases in pressure containers and discarded chemicals; discarded chemicals other than those mentioned in , or Waste disposal number of contaminated packaging WASTES FROM ORGANIC CHEMICAL PROCESSES; wastes from the MFSU of fine chemicals and chemical products not otherwise specified; other organic solvents, washing liquids and mother liquors Classified as hazardous waste. SECTION 14: Transport information Land transport (ADR/RID) Other applicable information (land transport) Inland waterways transport (ADN) Other applicable information (inland waterways transport) Marine transport (IMDG) Other applicable information (marine transport) Air transport (ICAO) Other applicable information (air transport) SECTION 15: Regulatory information Safety, health and environmental regulations/legislation specific for the substance or mixture EU regulatory information 1999/13/EC (VOC): Additional information irrelevant irrelevant

6 Page 6 of 6 National regulatory information Water contaminating class (D): 1 - slightly water contaminating Chemical safety assessment For this substance a chemical safety assessment has not been carried out. SECTION 16: Other information Further Information The data contained in this safety data sheet are based on our current knowledge and experience and describe the product with regard to safety requirements. The figures should be regarded in any way as a description of the product's properties (product specification). Any agreed property nor the suitability of the product for a specific purpose of our safety data sheet can not be derived. Proprietary rights and existing laws and legislation are Recipient of our products to their own responsibility. (The data for the hazardous ingredients were taken respectively from the last version of the sub-contractor's safety data sheet.)

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