MATERIAL SAFETY DATA SHEET

Transcription

1 1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND COMPANY/UNDERTAKING 1/6 Application: Fuel catalyst Container size: 25 l, 200 l Supplier: Tejohn Oil ApS Skoleholmen DK Greve Strand 2. COMPOSITION/INFORMATION ON INGREDIENTS The product contains: organic solvents. %: CAS-No.: EC No.: Chemical name: Hazard classification: Notes: Fuels, diesel Carc. Cat. 3;R40 Xn;R65 R66 R Distillates (petroleum), Xn;R65 R66 hydrotreated light Alicyclic ketone Xn;R20/22 Xi;R36/ Dipropylenglycolmethylether - 3. HAZARDS IDENTIFICATION The product has been classified according to the legislation in force: Carc3; R40 Xn;R65 R66 R52/53 Human health: Organic solvents may be absorbed into the body by inhalation and ingestion and cause permanent damage to the nervous system, including the brain. Droplets of the product aspirated into the lungs through ingestion or vomiting may cause a serious chemical pneumonia. Repeated exposure may cause skin dryness or cracking. Limited evidence of a carcinogenic effect. Environment: Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment. 4. FIRST-AID MEASURES Inhalation: Move injured person into fresh air immediately. Call an ambulance. Be aware that symptoms of lung edema (shortness of breath) may develop up to 24 hours after exposure. Take along these instructions. Skin contact: Remove contaminated clothes and rinse skin thoroughly with water. In case of rashes, wounds or other skin disorders: Seek medical attention and bring along these instructions. Eye contact: Immediately flush with plenty of water for up to 15 minutes. Remove any contact lenses and open eyelids widely. If irritation persists: Seek medical attention and bring along these instructions. Ingestion: Immediately rinse mouth and drink plenty of water or milk. Keep person under observation. Do not induce vomiting. If vomiting occurs, keep head low. Transport immediately to hospital and take these instructions.

2 2/ 6 5. FIRE-FIGHTING MEASURES Extinguishing media: Extinguish with carbon dioxide or dry powder. Cool containers exposed to heat with water spray and remove container, if no risk is involved. Specific hazards: By heating and fire, harmful vapors/gases may be formed. Vapors are heavier than air and may travel along the floor and in the bottom of containers. Vapors may be ignited by a spark, a hot surface or an ember. Protective equipment for fire-fighters: Use air-supplied respirator during fire fighting. 6. ACCIDENTAL RELEASE MEASURES Personal precautions: Avoid inhalation of vapors and contact with skin and eyes. Do not smoke, use open fire or other sources of ignition. For personal protection, see section 8. Environmental precautions: Do not discharge into drains, water courses or onto the ground. Methods for cleaning up: Absorb spillage with non-combustible, absorbent material. For waste disposal, see section HANDLING AND STORAGE Safe handling advice: Avoid inhalation of vapors and contact with skin and eyes. Observe good industrial hygiene practices. Technical measures: Use work methods which minimize aerosol production. Avoid exposure to temperatures above the flash point. Technical precautions: Local exhaust is recommended. Provide easy access to water supply or an emergency shower. Technical measures for safe storage: No special precautions. Storage conditions: Store in tightly closed original container in a well-ventilated place. Store segregated from other chemicals (oxidizing agent).

3 3/ 6 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Engineering measures: Provide adequate ventilation. Observe Occupational Exposure Limits and minimize the risk of inhalation of vapors and spray mist. Chemical name: Exposure limits: Type: Notes: References: Diesel fuel, as total 100 mg/m³ TWA Skin; A3 ACGIH hydrocarbons-vapor and aerosol Keosene-as total 200 mg/m³ TWA Skin; A4 ACGIH hydrocarbon vapor Bis-(2-Methoxypropyl) ether 100 ppm 150 ppm TWA STEL Skin 15min ACGIH Dipropylene glycol methyl ether 100 ppm 600 mg/m³ TWA Skin OSHA Respiratory equipment: In case of inadequate ventilation and work of brief duration, use suitable respiratory equipment. Use respiratory equipment with gas filter, type A2. Hand protection: Risk of contact: Wear protective gloves. Nitrile gloves are recommended, but be aware that the liquid may penetrate the gloves. Frequent change is advisable. The most suitable glove must be chosen in consultation with the gloves supplier, who can inform about the breakthrough time of the glove material. Eye protection: Risk of splashes: Wear goggles/face shield. Skin protection: Wear apron or protective clothing in case of splashes. Hygiene measures: Wash hands after contact. When using do not eat, drink or smoke. Environmental Exposure Controls: Demand for control of air pollution. 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance: Odor: ph: Boiling point: Flash point: Explosive properties: Relative density: Solubility: Other data: Liquid of varying colour - green towards red characteristic 66 C Insoluble in water. kinematic viscosity at 104 F: <7 mm²/s

4 4/ STABILITY AND REACTIVITY Stability: Stable under normal temperature conditions. Conditions/ materials to avoid: Oxidizing agents. Hazardous decomposition products: By heating, vapors/gases hazardous to health may be formed. 11. TOXICOLOGICAL INFORMATION Inhalation: Vapors have a narcotic effect and may cause headache, fatigue, dizziness and nausea. Skin contact: Repeated exposure may cause skin dryness or cracking. Eye contact: May irritate and cause redness and pain. Ingestion: Harmful: may cause lung damage if swallowed. Droplets of the product aspirated into the lungs through ingestion or vomiting may cause a serious chemical pneumonia. Specific effects: Frequent inhalation of even small concentrations may cause irritability, fatigue and memory failure and eventually permanent damage to the nervous system, including the brain. Limited evidence of a carcinogenic effect. 12. ECOLOGICAL INFORMATION Mobility: The product contains organic solvents which will evaporate easily from all surfaces. Degradability: The product is not biodegradable. Ecotoxicity: Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment. 13. DISPOSAL CONSIDERATIONS Dispose of waste and residues in accordance with local authority requirements. Waste is classified as hazardous waste. Waste from residues: EWC-code: TRANSPORT INFORMATION The product is not covered by international regulation on the transport of dangerous goods (IMDG, IATA, ADR/RID).

5 5/ REGULATORY INFORMATION Labelling: Contains: Fuels, diesel Distillates (petroleum), hydrotreated light Harmful R40 R65 R66 R52/53 S36/37 S60 S61 S62 Limited evidence of a carcinogenic effect. Harmful: may cause lung damage if swallowed. Repeated exposure may cause skin dryness or cracking. Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Wear suitable protective clothing and gloves. This material and its container must be disposed of as hazardous waste. Avoid release to the environment. Refer to special instructions/safety data sheets. If swallowed, do not induce vomiting: seek medical advice immediately and show this container or label. NFPA Rating: Health:2 Fire:0 Reactivity:0 Other:- Specific provisions: National regulation: As a main rule, persons under 18 years of age are not allowed to work with this product. TSCA: Listed. State and local regulation may apply. The following lists have been checked: Threshold Limit Values (2004), ACGIH, by the American Conference on Governmental Industrial Hygienists. The Code of Federal Regulation, Title 29, part Occupational Safety and Health Standards, Air contaminants. U.S. Department of health and human services: Report on Carcinogens - 10th Ed. International Agency for Research on Cancer (IARC): IARC Monographs on the Evaluation of Carcinogenic Risks to Humans. Lyon: IARC, World Health Organization,

6 6/ OTHER INFORMATION The user must be instructed in the proper work procedure and be familiar with the contents of these instructions. Wording of Risk Phrases: R20/22 Harmful by inhalation and if swallowed. R36/38 Irritating to eyes and skin. R40 Limited evidence of a carcinogenic effect. R52/53 Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment. R65 Harmful: may cause lung damage if swallowed. R66 Repeated exposure may cause skin dryness or cracking. The information on this data sheet represents our current data and is reliable provided that the product is used under the prescribed conditions and in accordance with the application specified on the packaging and/or in the technical guidance literature. Any other use of the product which involves using the product in combination with any other product or any other process is the responsibility of the user. Made by DANISH TOXICOLOGY CENTRE, Kogle Allé 2, DK-2970 Hørsholm, Denmark. Telephone Telefax