Safety Data Sheet. Bostik Powder Adhesive. Replaces date: 08/04/2015 Revision date: 06/03/2017

Transcription

1 SECTION 1: Identification of the substance/preparation and of the company/undertaking 1.1. Product identifier Trade name: 1.2. Relevant identified uses of the substance or mixture and uses advised against Recommended uses: Adhesive Powder is a starch based wallpaper paste in powder form for machine and hand applisering in dry areas. Powder Adhesive is intended for setting wallpaper on absorbent substrates. For construction paper wallpaper Wall Adhesive should be used Details of the supplier of the safety data sheet Supplier Company: Bostik AB Address: Strandbadsvägen 22 Zip code: Country: Helsingborg SWEDEN info.se@bostik.com Phone: Homepage: Contact person: Name: - Environment dep., Phone: Emergency Telephone Number (Swedish Poisons Informations Centre) SECTION 2: Hazards identification 2.1. Classification of the substance or mixture CLP-classification: CLP Classification - other information: The product shall not be classified as hazardous according to the classification and labeling rules for substance and mixtures. Classification according to Regulation (EC) No 1272/2008 CLP / GHS: not classified. Most serious harmful effects: Further information on potential health effects and symptoms of Section Label elements 2.3. Other hazards Dust may form explosive mixture with air. The product shall not be classified as hazardous according to the classification and labeling rules for substance and mixtures. SECTION 3: Composition/information on ingredients 1 / 6

2 3.2. Mixtures Substance CAS number EC No REACH Reg. No. Concentration Notes starch % CLPclassification Please see section 16 for the full text of H-phrases. SECTION 4: First aid measures 4.1. Description of first aid measures Inhalation: Ingestion: Skin contact: Eye contact: Burns: General: Fresh air and rest. Contact physician if symptoms appears. Thoroughly rinse the mouth with water. Drink a few glasses of water. Contact physician if larger quantity has been consumed. Wash skin thoroughly with soap and water. Remove contact lenses. Rinse immediately with plenty of water. Flush area with plenty of water. Consult a doctor if symptoms should occur. Flush with water until pain ceases. Remove clothing that is not stuck to the skin - seek medical advice/transport to hospital. If possible, continue flushing until medical attention is obtained. When obtaining medical advice, show the safety data sheet or label Most important symptoms and effects, both acute and delayed No specific dangers known, if the regulations / instructions for storage and handling are considered Indication of any immediate medical attention and special treatment needed No special immediate treatment required. SECTION 5: Fire-fighting measures 5.1. Extinguishing media Suitable extinguishing media: Unsuitable extinguishing media: Extinguishing methods: Extinguish with powder, carbon dioxide, foam or fine water mist. Note the risk of dust explosion. Do not use a direct water jet. Keep trespassers away from danger area. Cool containers exposed to flames with water until well after the fire is out Special hazards arising from the substance or mixture Avoid generation and spreading of dust. Hazardous fumes are formed in fire conditions. Carbon monoxide (CO) and carbon dioxide (CO2) Advice for fire-fighters Wear a self contained breathing apparatus. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures 2 / 6

3 For non-emergency personnel: Wear necessary protective equipment. Extremely serious risk of slipping if the product comes into contact with water. For emergency responders: Avoid generation and spreading of dust. Static electricity and formation or sparks must be prevented Environmental precautions Prevent discharges into the sewage system, watercourses or ground Methods and material for containment and cleaning up Pick up small pieces carefully. Wet mop or vacuum. Use only explosion-proof equipment Reference to other sections See section 13 for waste disposal. See Sections 7 and 8 for prevention. SECTION 7: Handling and storage 7.1. Precautions for safe handling Use spark-proof tools and explosion-proof electric equipment. Good working hygiene must always be observed when handling product. Avoid direct contact. Provide adequate ventilation. Smoking and naked flames prohibited. Avoid handling which leads to dust formation Conditions for safe storage, including any incompatibilities Keep container tightly closed, in a cool, well ventilated place Specific end use(s) See Product Data Sheet. Ensure that air circulation is good in store and workplace. SECTION 8: Exposure controls/personal protection 8.1. Control parameters Exposure Limit values: Referring to Starch (CAS: ): respirable 4 mg/m3, total inhalable 10 mg/m3. TWA 8; EH40/2005 Worplace exposure limits. Breathing apparatus must be used if the limit values are exceeded Exposure controls Appropriate engineering controls: eye/face protection: skin protection: Workplace and work methods are designed to prevent direct contact. Observe hygiene limits. Use safety goggles and face shield in case of splash risk. Wear appropriate clothing to prevent any possibility of skin contact. hand protection: respiratory protection: Protective gloves is recommended if there is a risk of direct contact or splashes. Protective gloves (rubber, plastic). #Not translated# If necessary, respirator (full face mask or half mask) with P3 particle filter, or breathing apparatus. 3 / 6

4 Environmental exposure controls: Ensure compliance with local regulations for emissions. Wear respirator if there is dust formation. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Parameter State Colour Odour Solubility Explosive properties Oxidising properties Value/unit Flakes. White to yellow. Odourless or no characteristic odour. Miscible with water. Parameter Value/unit Remarks ph (solution for use) ~ 11 (25 g/l water) ph (concentrate) Melting point Freezing point Initial boiling point and boiling range Flash Point Evaporation rate Flammability (solid, gas) Flammability limits C Explosion limits Vapour pressure Vapour density Relative density Partition coefficient n-octonol/water Auto-ignition temperature Decomposition temperature Viscosity Odour threshold 9.2 Other information vol% Parameter Value/unit Remarks Dust Explosion Class, ST 1 Explosion overpressure (Pmax) Density SECTION 10: Stability and reactivity 6-8 bar 0,5 kg/l Reactivity No hazardous reactions with proper storage and handling Chemical stability Stable under recommended storage and handling conditions. 4 / 6

5 10.3. Possibility of hazardous reactions Conditions to avoid Avoid high temperatures and direct sunlight. Avoid sources of sparking (smoking, fire, static electricity) Incompatible materials Avoid contact with strong oxidisers Hazardous decomposition products The product is stable when used in accordance with the supplier's directions. SECTION 11: Toxicological information Information on toxicological effects Acute toxicity - oral: Acute toxicity - dermal: Acute toxicity - inhalation: Serious eye damage/eye irritation: Oral LD 50: > 2000 mg/kg. No information available Dust may irritate the respiratory tract. Splashes in the eyes may cause irritation and problems due to the adhesive properties of the product. SECTION 12: Ecological information Toxicity EC50 Daphnia >100 mg/l. EC50 Bacteria:>100 mg/l. No known data Persistence and degradability Biodegradable Bioaccumulative potential log Pow < Mobility in soil No known data Results of PBT and vpvb assessment No assessment has been made Other adverse effects No known data. Other Information Prevent discharges into the sewage system, watercourses or ground. Can be eliminated by adsorption onto activated sludge. 5 / 6

6 SECTION 13: Disposal considerations Waste treatment methods The generation of waste should be avoided or minimized wherever possible. Empty containers or liners may retain some product residues. This material and its container must be disposed of in a safe way. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Category of waste: waste adhesives and sealants other than those mentioned in SECTION 14: Transport information UN-No.: Not applicable Packing group: Not applicable UN proper shipping Not applicable Environmental Not applicable. name: hazards: Transport hazard class(es): Not applicable Special precautions for user Transport in bulk according to Annex II of MARPOL73/78 and the IBC code SECTION 15: Regulatory information Safety, health and environmental regulations/legislation specific for the substance or mixture Special Provisions: Safety, health and environmental regulations / legislation specific for the substance or mixture. EU Regulation (EC) No 1907/2006 (REACH) Chemical Safety Assessment Not established. SECTION 16: Other information Vendor notes: Version 5. The information in this SDS is based on our current knowledge and on current EU and national laws. The product should not be used for other purposes than those specified under section 1 without first obtaining written handling instruction. It is always the user who has full responsibility to comply with the requirements of current legislation. The information in this SDS is meant as a description of safety requirements for the product and not a guarantee of product properties. Date: 06/03/2017 Document language: GB 6 / 6