AP 600 Safety Data Sheet

Transcription

1 AP 600 Date of issue: 17/09/2018 Revision date: 17/09/2018 Supersedes: 3/04/2017 Version: 3.0 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Product form Trade name : Mixture : AP Relevant identified uses of the substance or mixture and uses advised against Relevant identified uses Main use category : Industrial use Uses advised against 1.3. Details of the supplier of the safety data sheet DL CHEMICALS Roterijstraat B-8793 Waregem - Belgium T F info@dl-chem.com Emergency telephone number Emergency number : Country Official advisory body Address Emergency number Comment United Kingdom Guy's & St Thomas' Poisons Unit Medical Toxicology Unit, Guy's & St Thomas' Hospital Trust SECTION 2: Hazards identification 2.1. Classification of the substance or mixture Avonley Road SE14 5ER London Classification according to Regulation (EC) No. 1272/2008 [CLP] Not classified Adverse physicochemical, human health and environmental effects 2.2. Label elements Labelling according to Regulation (EC) No. 1272/2008 [CLP] Extra labelling to displayextra classification(s) to display EUH-statements : EUH208 - Contains Reaction mass of bis(1,2,2,6,6-pentamethyl-4-piperidyl) sebacate and methyl 1,2,2,6,6-pentamethyl-4-piperidyl sebacate. May produce an allergic reaction. EUH210 - Safety data sheet available on request Other hazards This substance/mixture does not meet the PBT criteria of REACH regulation, annex XIII This substance/mixture does not meet the vpvb criteria of REACH regulation, annex XIII SECTION 3: Composition/information on ingredients 3.1. Substances 3.2. Mixtures 17/09/2018 EN (English) 1/6

2 Name Product identifier % Classification according to Regulation (EC) No. 1272/2008 [CLP] vinyltrimethoxysilane (CAS-No.) (EC-No.) (REACH-no) Titanium dioxide substance with a Community workplace exposure limit Full text of H-statements: see section 16 SECTION 4: First aid measures 4.1. Description of first aid measures First-aid measures after inhalation First-aid measures after skin contact First-aid measures after eye contact First-aid measures after ingestion (CAS-No.) (EC-No.) (REACH-no) : Move to fresh air. : Wash with plenty of water/. 2,5-5 Flam. Liq. 3, H226 Acute Tox. 4 (Inhalation), H332 STOT RE 2, H ,5 Not classified : Wash with plenty of water/. If eye irritation persists: Get medical advice/attention. : Rinse mouth Most important symptoms and effects, both acute and delayed Symptoms/effects after inhalation Symptoms/effects after skin contact Symptoms/effects after eye contact Symptoms/effects after ingestion : Not expected to present a significant inhalation hazard under anticipated conditions of normal use. : Not expected to present a significant skin hazard under anticipated conditions of normal use. : May cause slight irritation. : Not expected to present a significant ingestion hazard under anticipated conditions of normal use Indication of any immediate medical attention and special treatment needed SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media : All extinguishing media allowed Special hazards arising from the substance or mixture Fire hazard : Not combustible Advice for firefighters Precautionary measures fire Firefighting instructions Protection during firefighting : Do not breathe fumes from fires or vapours from decomposition. Evacuate unnecessary personnel. Exercise caution when fighting any chemical fire. : Cool down the containers exposed to heat with a water spray. : Wear a self contained breathing apparatus. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures For non-emergency personnel For emergency responders Protective equipment : Equip cleanup crew with proper protection. Equip rescue crew with proper protection Environmental precautions Do not allow into drains or water courses Methods and material for containment and cleaning up For containment : Cover spill with non combustible material, e.g.: sand, earth, vermiculite. Methods for cleaning up : Sweep or shovel spills into appropriate container for disposal Reference to other sections 17/09/2018 EN (English) 2/6

3 SECTION 7: Handling and storage 7.1. Precautions for safe handling Precautions for safe handling Hygiene measures : Avoid all unnecessary exposure Conditions for safe storage, including any incompatibilities Storage conditions 7.3. Specific end use(s) : Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work. : Store in dry, well-ventilated area. SECTION 8: Exposure controls/personal protection 8.1. Control parameters EU Local name Titanium dioxide EU Notes (Ongoing) EU Regulatory reference SCOEL Recommendations United Kingdom WEL TWA (mg/m³) 10 mg/m³ inhalable dust 4 mg/m³ respirable dust Exposure controls Appropriate engineering controls: Ensure good ventilation of the work station. Emergency eye wash fountains should be available in the immediate vicinity of any potential exposure. Hand protection: Time of penetration is to be checked with the glove producer. Please follow the instructions related to the permeability and the penetration time provided by the manufacturer. Gloves must be replaced after each use and whenever signs of wear or perforation appear Type Material Permeation Thickness (mm) Penetration Standard Disposable gloves Eye protection: Nitrile rubber (NBR) 3 (> 60 minutes) > 0,35 EN 374 Type Use Characteristics Standard Safety glasses Droplet With side shields EN 166 Skin and body protection: No special clothing/skin protection equipment is recommended under normal conditions of use Respiratory protection: No special respiratory protection equipment is recommended under normal conditions of use with adequate ventilation Device Filter type Condition Standard Gas mask ABEK If conc. in air > exposure limit Consumer exposure controls: 17/09/2018 EN (English) 3/6

4 Avoid contact with skin and eyes. Wash hands and other exposed areas with soap and water before leaving work. Other information: Do no eat, drink or smoke when using this product. Take off immediately all contaminated clothing. Wash contaminated clothing before reuse. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state Appearance Colour Odour Density Solubility 9.2. Other information : Liquid : Paste. : Grey. : characteristic. : 1,58 g/ml SECTION 10: Stability and reactivity Reactivity : Water: practically insoluble No dangerous reactions known under normal conditions of use Chemical stability Stable at ambient temperature and under normal conditions of use Possibility of hazardous reactions No dangerous reactions known Conditions to avoid Incompatible materials Hazardous decomposition products None under normal conditions. SECTION 11: Toxicological information Information on toxicological effects Acute toxicity (oral) Acute toxicity (dermal) Acute toxicity (inhalation) vinyltrimethoxysilane ( ) LD50 oral rat LD50 dermal rabbit LC50 inhalation rat (mg/l) LC50 inhalation rat (ppm) LC50 inhalation rat (Dust/Mist - mg/l/4h) LD50 oral rat LD50 dermal rabbit LC50 inhalation rat (Dust/Mist - mg/l/4h) Skin corrosion/irritation Serious eye damage/irritation Respiratory or skin sensitisation Germ cell mutagenicity Carcinogenicity Reproductive toxicity 7120 mg/kg 3540 mg/kg 16,79 mg/l/4h 2773 ppm/4h (OECD 403 method) 16,8 mg/l/4h > 5000 mg/kg > mg/kg > 6,82 mg/l/4h 17/09/2018 EN (English) 4/6

5 STOT-single exposure STOT-repeated exposure vinyltrimethoxysilane ( ) LOAEL (oral, rat, 90 days) Aspiration hazard mg/kg bodyweight/day SECTION 12: Ecological information Toxicity Acute aquatic toxicity Chronic aquatic toxicity vinyltrimethoxysilane ( ) LC50 fish 1 EC50 Daphnia 1 EC50 72h algae (1) ErC50 (algae) NOEC chronic fish NOEC chronic crustacea NOEC chronic algae LC50 fish 1 LC50 fish 2 EC50 Daphnia 1 EC50 other aquatic organisms 1 EC50 other aquatic organisms 2 NOEC (chronic) NOEC chronic algae 191 mg/l 168,7 mg/l > 957 mg/l > 100 mg/l (OECD 201 method) >= 100 mg/l 28 mg/l 957 mg/l > 1000 mg/l > mg/l 2 mg/l > mg/l 61 mg/l 0,01 mg/l rat mg/l Persistence and degradability Persistence and degradability Bioaccumulative potential Not readily biodegradable Mobility in soil Results of PBT and vpvb assessment Adhesive AP 600 This substance/mixture does not meet the PBT criteria of REACH regulation, annex XIII This substance/mixture does not meet the vpvb criteria of REACH regulation, annex XIII Other adverse effects SECTION 13: Disposal considerations Waste treatment methods Regional legislation (waste) SECTION 14: Transport information In accordance with ADR ADR UN number UN proper shipping name : Disposal must be done according to official regulations. 17/09/2018 EN (English) 5/6

6 ADR Transport hazard class(es) Packing group Environmental hazards Dangerous for the environment : No No supplementary information available Special precautions for user - Overland transport Transport regulations (ADR) Transport in bulk according to Annex II of Marpol and the IBC Code SECTION 15: Regulatory information Safety, health and environmental regulations/legislation specific for the substance or mixture EU-Regulations Contains no REACH substances with Annex XVII restrictions Contains no substance on the REACH candidate list Contains no REACH Annex XIV substances National regulations Chemical safety assessment SECTION 16: Other information Full text of H- and EUH-statements: Acute Tox. 4 (Inhalation) Acute toxicity (inhal.), Category 4 Flam. Liq. 3 Flammable liquids, Category 3 STOT RE 2 Specific target organ toxicity Repeated exposure, Category 2 H226 H332 H373 EUH208 EUH210 Flammable liquid and vapour. Harmful if inhaled. May cause damage to organs through prolonged or repeated exposure. Contains Reaction mass of bis(1,2,2,6,6-pentamethyl-4-piperidyl) sebacate and methyl 1,2,2,6,6-pentamethyl-4-piperidyl sebacate. May produce an allergic reaction. Safety data sheet available on request. MSDS Reach Annex II DL-Chem This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. It should not therefore be construed as guaranteeing any specific property of the product 17/09/2018 EN (English) 6/6