SECTION 1: Identification of the substance/mixture and of the company/undertaking

Transcription

1 Date of issue: 15/02/2017 Revision date: 15/02/2017 Supersedes: 6/02/2015 Version: 6.0 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Product form : Mixtures Trade name : 1.2. Relevant identified uses of the substance or mixture and uses advised against Relevant identified uses Main use category : Professional use Uses advised against 1.3. Details of the supplier of the safety data sheet DL CHEMICALS Roterijstraat B-8793 Waregem - Belgium T F info@dl-chem.com Emergency telephone number Emergency number : SECTION 2: Hazards identification 2.1. Classification of the substance or mixture Classification according to Regulation (EC) No. 1272/2008 [CLP] Not classified Adverse physicochemical, human health and environmental effects 2.2. Label elements Labelling according to Regulation (EC) No. 1272/2008 [CLP] Extra labelling to displayextra classification(s) to display EUH-statements : EUH208 - Contains Methyl tris-(methyl ethyl ketoximo) silane, 3- aminopropyltriethoxysilane, 3-(2-aminoethylamino)propyltrimethoxysilane. May produce an allergic reaction EUH210 - Safety data sheet available on request 2.3. Other hazards SECTION 3: Composition/information on ingredients 3.1. Substances 3.2. Mixtures Name Product identifier % Classification according to Regulation (EC) No. 1272/2008 [CLP] Methyl tris-(methyl ethyl ketoximo) silane (CAS No) (EC No) (REACH-no) Specific concentration limits: 1-5 Eye Irrit. 2, H319 Skin Sens. 1, H317 STOT RE 2, H373 Name Product identifier Specific concentration limits Methyl tris-(methyl ethyl ketoximo) silane (CAS No) (EC No) (REACH-no) Full text of H-statements: see section 16 (C >= 3,755) Skin Sens. 1, H317 15/02/2017 EN (English) 1/6

2 SECTION 4: First aid measures 4.1. Description of first aid measures First-aid measures after inhalation First-aid measures after skin contact First-aid measures after eye contact First-aid measures after ingestion : Move to fresh air. : Wash skin with mild soap and water. : Rinse immediately with plenty of water. If eye irritation persists: Get medical advice/attention. : Rinse mouth Most important symptoms and effects, both acute and delayed Symptoms/injuries after inhalation Symptoms/injuries after skin contact Symptoms/injuries after eye contact Symptoms/injuries after ingestion : Not expected to present a significant inhalation hazard under anticipated conditions of normal use. : Not expected to present a significant skin hazard under anticipated conditions of normal use. : Direct contact with the eyes is likely slightly irritating. : Not expected to present a significant ingestion hazard under anticipated conditions of normal use Indication of any immediate medical attention and special treatment needed SECTION 5: Fire-fighting measures 5.1. Extinguishing media Suitable extinguishing media : All extinguishing media allowed Special hazards arising from the substance or mixture Fire hazard 5.3. Advice for firefighters Precautionary measures fire Firefighting instructions Protection during firefighting Other information SECTION 6: Accidental release measures : No fire hazard. Not combustible. : Do not breathe fumes from fires or vapours from decomposition. Evacuate area. : Cool down the containers exposed to heat with a water spray. : Wear a self contained breathing apparatus. : Do not allow run-off from fire fighting to enter drains or water courses Personal precautions, protective equipment and emergency procedures General measures For non-emergency personnel For emergency responders 6.2. Environmental precautions Avoid release to the environment Methods and material for containment and cleaning up For containment Methods for cleaning up 6.4. Reference to other sections SECTION 7: Handling and storage 7.1. Precautions for safe handling Precautions for safe handling : Wear respiratory protection. Equip cleanup crew with proper protection. : Collect spillage. Handling temperature : 5-40 C Hygiene measures : Sweep or shovel spills into appropriate container for disposal. : Avoid all unnecessary exposure Conditions for safe storage, including any incompatibilities Storage conditions Maximum storage period : Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work. : Store in dry, well-ventilated area. : 12 months Storage temperature : 5-25 C 7.3. Specific end use(s) 15/02/2017 EN (English) 2/6

3 SECTION 8: Exposure controls/personal protection 8.1. Control parameters methanol ( ) EU Local name Methanol EU IOELV TWA (mg/m³) 260 mg/m³ EU IOELV TWA (ppm) 200 ppm EU Notes skin EU Skin United Kingdom WEL TWA (mg/m³) 266 mg/m³ United Kingdom WEL TWA (ppm) 200 ppm United Kingdom WEL STEL (mg/m³) 333 mg/m³ United Kingdom WEL STEL (ppm) 250 ppm 8.2. Exposure controls Appropriate engineering controls: Ensure good ventilation of the work station. Personal protective equipment: Gloves. Safety glasses. Hand protection: In case of repeated or prolonged contact wear gloves. Time of penetration is to be checked with the glove producer. Please follow the instructions related to the permeability and the penetration time provided by the manufacturer. Gloves must be replaced after each use and whenever signs of wear or perforation appear Type Material Permeation Thickness (mm) Penetration Standard Disposable gloves Nitrile rubber 6 (> 480 minutes) > 0,1 EN 374 Eye protection: Type Use Characteristics Standard Safety glasses With side shields EN 166 Skin and body protection: No special clothing/skin protection equipment is recommended under normal conditions of use Respiratory protection: No special respiratory protection equipment is recommended under normal conditions of use with adequate ventilation Environmental exposure controls: Avoid release to the environment. Other information: Do not eat, drink or smoke during use. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state : Liquid Appearance : Paste. Colour : According to product specification. Odour : characteristic. Density : 1 g/cm³ Solubility : Water: Insoluble 9.2. Other information 15/02/2017 EN (English) 3/6

4 SECTION 10: Stability and reactivity Reactivity None under normal conditions Chemical stability Stable at ambient temperature and under normal conditions of use Possibility of hazardous reactions None under normal conditions Conditions to avoid None to our knowledge Incompatible materials Hazardous decomposition products None under normal conditions. SECTION 11: Toxicological information Information on toxicological effects Acute toxicity LD50 oral rat LD50 dermal rat Skin corrosion/irritation Serious eye damage/irritation Respiratory or skin sensitisation Germ cell mutagenicity Carcinogenicity 2463 mg/kg (OECD 401 method) > 2000 mg/kg (OECD 402 method) NOAEL (chronic, oral, animal/male, 2 years) NOAEL (chronic, oral, animal/female, 2 years) Reproductive toxicity STOT-single exposure STOT-repeated exposure > 692,06 mg/kg bodyweight (OECD 414 method) > 230,69 mg/kg bodyweight (OECD 416 method) NOAEL (oral, rat, 90 days) Aspiration hazard SECTION 12: Ecological information Toxicity 29 mg/kg bodyweight/day (OECD 408 method) LC50 fish 1 LC50 fish 2 EC50 Daphnia 1 EC50 72h algae (1) ErC50 (algae) NOEC (acute) NOEC (chronic) Persistence and degradability > 100 ( 120) mg/l Oncorhynchus mykiss (Rainbow trout) 972,34 mg/l (OECD 203 method) 231,84 mg/l (OECD 202 method) 18,45 mg/l (OECD 201 method) 72h 94 mg/l Pseudokirchneriella subcapitata 57,67 mg/l (OECD 204 method) >= 115,34 mg/l (OECD 211 method) Biodegradation Bioaccumulative potential 28d 20 % (OECD 301C method) Log Pow 9,83 15/02/2017 EN (English) 4/6

5 12.4. Mobility in soil Log Koc Results of PBT and vpvb assessment Other adverse effects SECTION 13: Disposal considerations Waste treatment methods Regional legislation (waste) Product/Packaging disposal recommendations 5,481 EPA (Environmental Protection Agency) : Disposal must be done according to official regulations. : Empty the packaging completely prior to disposal. European List of Waste (LoW) code : waste adhesives and sealants other than those mentioned in SECTION 14: Transport information In accordance with ADR ADR UN number UN proper shipping name Transport hazard class(es) Packing group Environmental hazards Dangerous for the environment : No No supplementary information available Special precautions for user - Overland transport No data available Transport in bulk according to Annex II of Marpol and the IBC Code SECTION 15: Regulatory information Safety, health and environmental regulations/legislation specific for the substance or mixture EU-Regulations Contains no REACH substances with Annex XVII restrictions Contains no substance on the REACH candidate list Contains no REACH Annex XIV substances National regulations Chemical safety assessment 15/02/2017 EN (English) 5/6

6 SECTION 16: Other information Full text of H- and EUH-statements: Eye Irrit. 2 Serious eye damage/eye irritation, Category 2 Skin Sens. 1 Sensitisation Skin, Category 1 STOT RE 2 Specific target organ toxicity Repeated exposure, Category 2 H317 May cause an allergic skin reaction H319 Causes serious eye irritation H373 May cause damage to organs through prolonged or repeated exposure EUH208 Contains. May produce an allergic reaction EUH210 Safety data sheet available on request MSDS Reach Annex II DL-Chem This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. It should not therefore be construed as guaranteeing any specific property of the product 15/02/2017 EN (English) 6/6