Revision Date 04/30/2012. Product name : D3 LIQUID CONC Relevant identified uses of the substance or mixture and uses advised against
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1 D LIQUID CONC 64 Version 1.0 Revision Date 04/0/2012 DSM Print Date 04/0/201 2 SECTION 1. PRODUCT AND COMPANY IDENTIFICATION Product name : D LIQUID CONC Relevant identified uses of the substance or mixture and uses advised against Use of the Substance/Mixture : Premixfor Animal Feeds 1. Details of the supplier of the safety data sheet Company Telephone Telefax address Responsible/issuing person 1.4 Emergency telephone number DSM Nutritional Products 45 Waterview Blvd US Parsippany (908) (908) sds.nutritionalproducts@dsm.com Emergency # (24 HR CHEMTREC) SECTION 2. HAZARDS IDENTIFICATION Emergency Overview Warning Form: liquid, Odour: No information available. Hazard Summary OSHA Hazards Flammable. FLAMMABLE LIQUID HARMFUL BY INGESTION. SEVERE EYE IRRITANT Potential Health Effects Aggravated Medical Condition Eyes Symptoms of Overexposure : Eyes : Causes eye irritation. : No specific symptoms known. Carcinogenicity: IARC OSHA NTP ACGIH equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC. equal to 0.1% is identified as a carcinogen or potential carcinogen by OSHA. equal to 0.1% is identified as a known or anticipated carcinogen by NTP. equal to 0.1% is identified as a carcinogen or potential carcinogen by ACGIH. /9 MSDS US/EN
2 D LIQUID CONC 64 j^ 1& DSM Version 1.0 Revision Date 04/0/2012 Print Date 04/0/2012 SECTION. COMPOSITION/INFORMATION ON INGREDIENTS Brief description of the product : Mixture Hazardous components Component CAS-No Weight percent 5-10 SECTION 4. FIRST AID MEASURES First aid procedures General advice Inhalation Skin contact Eye contact Ingestion Notes to physician Symptoms Treatment : Move out of dangerous area. Show this safety data sheet to the doctor in attendance. : Move to fresh air in case of accidental inhalation of dust or fumes from overheating or combustion. If symptoms persist, call a physician. : Take off contaminated clothing and shoes immediately. Wash off with soap and plenty of water. : Immediately flush eye(s) with plenty of water. Remove contact lenses. Protect unharmed eye. Keep eye wide open while rinsing. If eye irritation persists, consult a specialist. : Clean mouth with water and drink afterwards plenty of water. Do not give milk or alcoholic beverages. Never give anything by mouth to an unconscious person. Obtain medical attention. : No specific symptoms known. : Treat symptomatically. SECTION 5. FIREFIGHTING MEASURES Flammable properties Flash point Ignition temperature Lower explosion limit Upper explosion limit : 9.0 F (.9 C) : not determined : not determined : not determined Fire fighting Suitable extinguishing media : Alcohol-resistant foam Dry chemical 2/9 MSDS US/EN
3 D LIQUID CONC 64 Version 1.0 Revision Date 04/0/2012 I&DSM Print Date 04/0/2012 Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Further information Standard procedure for chemical fires. Protective equipment and precautions for firefighters Specific hazards during firefighting Special protective equipment for firefighters : None known. SECTION 6. ACCIDENTAL RELEASE MEASURES In the event of fire, wear self-contained breathing apparatus. Personal precautions Environmental precautions Methods for containment / Methods for cleaning up Use personal protective equipment. Ensure adequate ventilation. Try to prevent the material from entering drains or water courses. Soak up with inert absorbent material (e.g. sand, silica gel, acid binder, universal binder, sawdust). Keep in suitable, closed containers for disposal. SECTION 7. HANDLING AND STORAGE Handling Handling Advice on protection against fire and explosion Storage Requirements for storage areas and containers Advice on common storage Avoid exceeding of the given occupational exposure limits (see section 8). Avoid contact with skin and eyes. For personal protection see section 8. Provide sufficient air exchange and/or exhaust in work rooms. No special handling advice required. Smoking, eating and drinking should be prohibited in the application area. Take precautionary measures against static discharges. Store at room temperature. Keep container tightly closed and dry. No special restrictions on storage with other products. SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Exposure Guidelines Components with workplace control parameters Components CAS-No Value TWA Control parameters 100 ppm Update Basis ACGIH Eye & Upper Respiratory Tract irritation /9 MSDS US/EN
4 D LIQUID CONC 64 Version 1.0 Revision Date 04/0/2012 DSM Print Date 04/0/201 2 Not classifiable as a human carcinogen TWA 200 ppm 500 mg/m OSHAP1 The value in mg/m is approximate. TWA 200 ppm 500 mg/m NIOSH REL Potential for dermal absorption ST 250 ppm 625 mg/m NIOSH REL Potential for dermal absorption Immediately Dangerous to Life or Health Concentrations (IDLH) Substance name Engineering measures CAS-No For technical measures see section 7. Personal protective equipment Eye protection Control parameters Immediately Dangerous to Life or Health Concentration Value 800 parts per million Safety glasses with side-shields Update Hand protection Glove material: for example nitrile rubber Consider the hazard characteristics of this product and any special workplace conditions when selecting the appropriate type of protective gloves. Skin and body protection Respiratory protection Hygiene measures Choose body protection according to the amount and concentration of the dangerous substance at the work place. In the case of vapour formation use a respirator with an approved filter. No personal respiratory protective equipment normally required. Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and at the end of workday. SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance Form Odour Odour Threshold Safety data Flash point : liquid : No information available. : No information available. :.9 C 4/9 MSDS US/EN
5 ^1$ DSM D LIQUID CONC 64 Version 1.0 Revision Date 04/0/2012 Print Date 04/0/2012 Eye irritation : May irritate eyes. Further information : May cause irritation of respiratory tract. STOT - single exposure (Acute exposure) : May cause drowsiness or dizziness. SECTION 12. ECOLOGICAL INFORMATION Elimination information (persistence and degradability) Bioaccumulation : no data available Distribution among environmental compartments : no data available Further information on ecology Additional ecological information Ecotoxicology Assessment : There is no data available for this product, Results of PBT assessment This mixture contains no substance considered to be persistent, bioaccumulating nor toxic (PBT). This mixture contains no substance considered to be very persistent nor very bioaccumulating (vpvb). SECTION 1. DISPOSAL CONSIDERATIONS Further information : Do not contaminate ponds, waterways or ditches with chemical or used container. Do not dispose of waste into sewer. Offer surplus and non-recyclable solutions to a licensed disposal company. User must determine if any wastes generated exhibit hazardous characteristics as per 40 CFR Part 261 or other national / local legislation. Contaminated packaging : Dispose of as unused product. Do not re-use empty containers. Empty containers should be taken to an approved waste handling site for recycling or disposal. SECTION 14. TRANSPORT INFORMATION DOT UN number Description of the goods Class Packing group Labels Emergency Response 199 Flammable liquids, n.o.s. () III 128 6/9 MSDS US/EN
6 D LIQUID CONC 64 Version 1.0 Revision Date 04/0/2012 J&DSM Print Date 04/0/2012 Guidebook Number Environmentally hazardous : yes IATA UN number Description of the goods Class Packing group Labels Packing instruction (cargo aircraft) Environmentally hazardous IMDG UN number Description of the goods Class Packing group Labels EmS Number 1 EmS Number 2 Marine pollutant Environmentally hazardous 199 Flammable liquid, n.o.s. () III 66 no 199 FLAMMABLE LIQUID, N.O.S. () III F-E S-E no yes Special precautions for user Other information : No additional requirements. Transport in bulk according to Annex II of MARPOL 7/78 and the IBC Code not applicable SECTION 15. REGULATORY INFORMATION OSHA Hazards : Flammable liquid, Harmful by ingestion., Severe eye irritant CERCLA Reportable : Quantity This material does not contain any components with a CERCLA RQ. SARA 11/12 Hazards : Fire Hazard Acute Health Hazard EPCRA - EMERGENCY PLANNING COMMUNITY RIGHT - TO - KNOW SARA 02 Reportable : SARA 02: No chemicals in this material are subject to the Quantity reporting requirements of SARA Title III, Section 02. This material does not contain any components with a SARA 02 RQ. SARA 04 Extremely : This material does not contain any components with a section Hazardous Substances 04 EHS RQ. SARA 1 Components : SARA 1: This material does not contain any chemical components with known CAS numbers that exceed the threshold (De Minimis) reporting levels established by SARA Title III, Section 1. 7/9 MSDS US/EN
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