Version 2.0 SDB_GB Revision Date Print Date Identification of the substance/mixture and of the company/undertaking

Transcription

1 1. Identification of the substance/mixture and of the company/undertaking 1.1 Product identifier Trade name : 1.2 Relevant identified uses of the substance or mixture and uses advised against Use of the : Insulating varnish Substance/Mixture 1.3 Details of the supplier of the safety data sheet Company : ELANTAS Italia S.r.l. Strada Antolini Collecchio Italy Telephone : Telefax : address : msds.elantas.italia@altana.com 1.4 Emergency telephone number +39 (0) (8-17 h) 2. Hazards identification 2.1 Classification of the substance or mixture Classification (67/548/EEC, 1999/45/EC) Sensitising Irritant Dangerous for the environment : May cause sensitization by skin contact. R36/38: Irritating to eyes and skin. R51/53: Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. 2.2 Label elements Labelling (REGULATION (EC) No 1272/2008) Labelling according to EC Directives (1999/45/EC) Hazard pictograms : Irritant Dangerous for the environment R-phrase(s) : R36/38 Irritating to eyes and skin. May cause sensitization by skin contact. R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. 1 / 9

2 S-phrase(s) : S24 Avoid contact with skin. S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S37 Wear suitable gloves. S57 Use appropriate container to avoid environmental contamination. S60 This material and its container must be disposed of as hazardous waste. Hazardous components which must be listed on the label: Phenol, polymer with formaldehyde, oxiranylmethyl ether reaction product: bisphenol-a-(epichlorhydrin) and epoxy resin (number average molecular weight <= 700) ,3-bis(2,3-epoxypropoxy)-2,2-dimethylpropane 2.3 Other hazards No information available. 3. Composition/information on ingredients 3.2 Mixtures Chemical nature : Epoxy Emulsion Resin Hazardous components Chemical Name CAS-No. EC-No. Registration number Phenol, polymer with formaldehyde, oxiranylmethyl ether Classification (67/548/EEC) Xi; R36/38 N; R51/53 Classification (REGULATION (EC) No 1272/2008) Skin Irrit. 2; H315 Eye Irrit. 2; H319 Skin Sens. 1; H317 Aquatic Chronic 2; H411 Concentration [%] >= 12,5 - < 20 reaction product: bisphenol-a- (epichlorhydrin) and epoxy resin (number average molecular weight <= 700) 1,3-bis(2,3- epoxypropoxy)-2,2- dimethylpropane trichloro(n,ndimethyloctylamine)bor on Xi; R36/38 N; R51-R53 Xi; R38 Xi; R36/37/38 Eye Irrit. 2; H319 Skin Irrit. 2; H315 Skin Sens. 1; H317 Aquatic Chronic 2; H411 Skin Irrit. 2; H315 Skin Sens. 1; H317 Skin Irrit. 2; H315 Eye Irrit. 2; H319 STOT SE 3; H335 >= 12,5 - < 20 >= 1 - < 3 >= 1 - < 3 For the full text of the R-phrases mentioned in this Section, see Section 16. For the full text of the H-Statements mentioned in this Section, see Section / 9

3 4. First aid measures 4.1 Description of first aid measures General advice : Move out of dangerous area. Consult a physician. Show this safety data sheet to the doctor in attendance. If inhaled In case of skin contact In case of eye contact If swallowed : Move to fresh air in case of accidental inhalation of dust or fumes from overheating or combustion. If symptoms persist, call a physician. : Take off contaminated clothing and shoes immediately. Wash off with soap and plenty of water. If symptoms persist, call a physician. : Immediately flush eye(s) with plenty of water. Remove contact lenses. Protect unharmed eye. Keep eye wide open while rinsing. If eye irritation persists, consult a specialist. : Clean mouth with water and drink afterwards plenty of water. Do not give milk or alcoholic beverages. Never give anything by mouth to an unconscious person. Obtain medical attention. 5. Firefighting measures 5.1 Extinguishing media Suitable extinguishing media : Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. 5.2 Special hazards arising from the substance or mixture Specific hazards during firefighting : Do not allow run-off from fire fighting to enter drains or water courses. 5.3 Advice for firefighters Special protective equipment for firefighters Further information : In the event of fire, wear self-contained breathing apparatus. : Collect contaminated fire extinguishing water separately. This must not be discharged into drains. Fire residues and contaminated fire extinguishing water must be disposed of in accordance with local regulations. 6. Accidental release measures 6.1 Personal precautions, protective equipment and emergency procedures Personal precautions : Use personal protective equipment. 3 / 9

4 Ensure adequate ventilation. 6.2 Environmental precautions Environmental precautions : Do not flush into surface water or sanitary sewer system. Prevent further leakage or spillage if safe to do so. If the product contaminates rivers and lakes or drains inform respective authorities. 6.3 Methods and materials for containment and cleaning up Methods for cleaning up : Soak up with inert absorbent material (e.g. sand, silica gel, acid binder, universal binder, sawdust). Keep in suitable, closed containers for disposal. 6.4 Reference to other sections Make sure that there is a sufficient amount of neutralizing/ absorbent material near the storage area., Mark the contaminated area with signs and prevent access to unauthorized personnel. 7. Handling and storage 7.1 Precautions for safe handling Advice on safe handling : Avoid contact with skin and eyes. For personal protection see section 8. Persons with a history of skin sensitisation problems or asthma, allergies, chronic or recurrent respiratory disease should not be employed in any process in which this mixture is being used. Smoking, eating and drinking should be prohibited in the application area. Dispose of rinse water in accordance with local and national regulations. Advice on protection against : Normal measures for preventive fire protection. fire and explosion 7.2 Conditions for safe storage, including any incompatibilities Requirements for storage areas and containers : Keep container tightly closed in a dry and well-ventilated place. Containers which are opened must be carefully resealed and kept upright to prevent leakage. Other data : No decomposition if stored and applied as directed. 8. Exposure controls/personal protection 8.1 Control parameters Contains no substances with occupational exposure limit values. PNEC 4 / 9

5 reaction product: bisphenol- A-(epichlorhydrin) and epoxy resin (number average molecular weight <= 700) : Fresh water Value: 0,006 mg/l Fresh water sediment Value: 0,0627 mg/kg Marine water Value: 0,0006 mg/l Marine sediment Value: 0,00627 mg/kg Sewage treatment plant Value: 10 mg/l Soil Value: 0,0478 mg/kg 8.2 Exposure controls Personal protective equipment Respiratory protection : In the case of vapour formation use a respirator with an approved filter. Hand protection Eye protection Skin and body protection Hygiene measures Protective measures : Polyvinyl alcohol or nitrile- butyl-rubber gloves The selected protective gloves have to satisfy the specifications of EU Directive 89/686/EEC and the standard EN 374 derived from it. Before removing gloves clean them with soap and water. : Eye wash bottle with pure water Tightly fitting safety goggles : impervious clothing Choose body protection according to the amount and concentration of the dangerous substance at the work place. : Handle in accordance with good industrial hygiene and safety practice. When using do not eat or drink. When using do not smoke. Wash hands before breaks and at the end of workday. : Do not wear contact lenses. Environmental exposure controls General advice : Do not flush into surface water or sanitary sewer system. Prevent further leakage or spillage if safe to do so. If the product contaminates rivers and lakes or drains inform respective authorities. 5 / 9

6 9. Physical and chemical properties 9.1 Information on basic physical and chemical properties Appearance : liquid Colour : milky Odour Flash point : slight : does not flash Initial boiling point : 100 C Density : ca.1 g/cm3 10. Stability and reactivity 10.1 Reactivity Stable under recommended storage conditions Chemical stability No decomposition if stored and applied as directed Possibility of hazardous reactions Hazardous reactions : Stable under recommended storage conditions., No decomposition if used as directed Conditions to avoid Conditions to avoid 10.5 Incompatible materials Materials to avoid : Strong acids and strong bases Strong oxidizing agents Strong reducing agents 10.6 Hazardous decomposition products Hazardous decomposition products : Thermal decomposition can lead to release of irritating gases and vapours. 11. Toxicological information 11.1 Information on toxicological effects Acute toxicity Acute oral toxicity Skin corrosion/irritation Skin irritation 6 / 9

7 Serious eye damage/eye irritation Eye irritation Respiratory or skin sensitization Sensitisation : May cause skin irritation in susceptible persons. : Vapours may cause irritation to the eyes, respiratory system and the skin. : Causes sensitization. Target Organ Systemic Toxicant - Repeated exposure Further information 12. Ecological information 12.1 Toxicity Toxicity to fish : no data available Toxicity to daphnia and other aquatic invertebrates 12.2 Persistence and degradability Biodegradability 12.3 Bioaccumulative potential Bioaccumulation 12.4 Mobility in soil 12.5 Results of PBT and vpvb assessment 12.6 Other adverse effects Additional ecological information : An environmental hazard cannot be excluded in the event of unprofessional handling or disposal. Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. 7 / 9

8 13. Disposal considerations 13.1 Waste treatment methods Product Contaminated packaging : The product should not be allowed to enter drains, water courses or the soil. Do not contaminate ponds, waterways or ditches with chemical or used container. Offer surplus and non-recyclable solutions to a licensed disposal company. : Empty remaining contents. Dispose of as unused product. Do not re-use empty containers. 14. Transport information Land transport ADR / RID: Class: 9 Packaging group: III UN number: 3082 ADR/RID-Labels: 9 Description of the goods: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (Epoxy resin) Sea transport IMDG: Class: 9 Packaging group: III UN number: 3082 Labels: 9 EmS: F-A S-F Description of the goods: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (Epoxy resin) Marine Pollutant Air transport IATA-DGR : Class: 9 Packaging group: III UN/ID No.: UN 3082 Labels: 9 8 / 9

9 Description of the goods: Environmentally hazardous substance, liquid, n.o.s. (Epoxy resin) 15. Regulatory information 15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture Major Accident Hazard Legislation : 96/82/EC Update: 2003 Dangerous for the environment 9b Quantity 1: 200 t Quantity 2: 500 t 15.2 Chemical Safety Assessment 16. Other information Full text of R-phrases referred to under sections 2 and 3 R36/37/38 Irritating to eyes, respiratory system and skin. R36/38 Irritating to eyes and skin. R38 Irritating to skin. May cause sensitization by skin contact. R51 Toxic to aquatic organisms. R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. R53 May cause long-term adverse effects in the aquatic environment. Full text of H-Statements referred to under sections 2 and 3. H315 Causes skin irritation. H317 May cause an allergic skin reaction. H319 Causes serious eye irritation. H335 May cause respiratory irritation. H411 Toxic to aquatic life with long lasting effects. Further information Training advice : Provide adequate information, instruction and training for operators. The information contained herein is based on the present state of our knowledge and does therefore not guarantee certain properties. 9 / 9