Safety Data Sheet according to 1907/2006/EC, Article 31. Printing date Revision: Xn Harmful

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1 Page 1/6 * 1 Identification of substance Product details Application of the substance / the preparation Polyurethane resin Injektion Manufacturer/Supplier: MC-Bauchemie Müller GmbH & Co. KG Am Kruppwald 1-8 D Bottrop Tel.: ++49(0) Fax.: ++49(0) Informing department: Product safety department. msds@mc-bauchemie.com Emergency information: Tel.: ++49(0) * 2 Hazards identification Hazard designation:?@g Xn Harmful Information pertaining to particular dangers for man and environment R 20 Harmful by inhalation. R 36/37/38 Irritating to eyes, respiratory system and skin. R 42/43 May cause sensitisation by inhalation and skin contact. Contains isoc yanates. See information supplied by the manufacturer Classification system The classification is in line with current EC lists. It is expanded, however, by information from technical literature and by information furnished by supplier companies. * 3 Composition/information on ingredients Chemical characterization Description: Active substance with propellant. Dangerous components: CAS: diphenylmethane-4,4'-di-isocyanante % EINECS: Xn, Xi; R 20-36/37/ /43-48/20 Additional information For the wording of the listed risk phrases refer to section 16. * 4 First aid measures General information Instantly remove any clothing soiled by the product. Take affected persons into the open air. Seek medical treatment. After inhalation Supply fresh air. Call a doctor immediately. After skin contact Instantly wash with water and soap and rinse thoroughly. After eye contact Rinse opened eye for several minutes under running water. Seek medical treatment. (Contd. on page 2)

2 Page 2/6 After swallowing Call a doctor immediately. (Contd. of page 1) * 5 Fire fighting measures Suitable extinguishing agents CO2, extinguishing powder or water jet. Fight larger fires with water jet or alcohol-resistant foam. Special hazards caused by the material, its products of combustion or flue gases: Can be released in case of fire Carbon monoxide (CO) Nitrogen oxides (NOx) Under certain fire conditions, traces of other toxic gases cannot be excluded, e.g.: Hydrogen cyanide (HCN) Protective equipment: Wear self-contained breathing apparatus. * 6 Accidental release measures Person-related safety precautions: Measures for environmental protection: Measures for cleaning/ collecting: Ensure adequate ventilation Use breathing protection against the effects of fumes/dust/aerosol. Prevent material from reaching sewage system, holes and cellars. Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust). Dispose of contaminated material as waste according to item 13. Ensure adequate ventilation. * 7 Handling and storage Handling Information for safe handling: Ensure good ventilation/exhaustion at the workplace. Prevent formation of aerosols. Information about protection against explosions and fires: No special measures required. Storage Requirements to be met by storerooms and containers: Store only in the original container. Information about storage in one common storage facility: Store away from foodstuffs. Further information about storage conditions: Keep container tightly sealed. * 8 Exposure controls and personal protection Additional information about design of technical systems: No further data; see item 7. (Contd. on page 3)

3 Page 3/6 (Contd. of page 2) Components with critical values that require monitoring at the workplace: diphenylmethane-4,4'-di-isocyanante (70-100%) WEL Short-term value: 0.07 mg/m³ Long-term value: 0.02 mg/m³ Sen; as -NCO di-''isononyl'' phthalate (<25%) WEL Long-term value: 5 mg/m³ Additional information: The lists that were valid during the compilation were used as basis. Personal protective equipment General protective and hygienic measures Keep away from foodstuffs, beverages and food. Instantly remove any soiled and impregnated garments. Wash hands during breaks and at the end of the work. Avoid contact with the eyes and skin. Do not eat, drink or smoke while working. Breathing equipment: Short term filter device: In case of brief exposure or low pollution use breathing filter apparatus. In case of intensive or longer exposure use breathing apparatus that is independent of circulating air. Protection of hands: Protective gloves. Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation After use of gloves apply skin-cleaning agents and skin cosmetics. Material of gloves Butyl rubber, BR Nitrile rubber, NBR The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and varies from manufacturer to manufacturer. As the product is a preparation of several substances, the resistance of the glove material can not be calculated in advance and has therefore to be checked prior to the application. Penetration time of glove material Eye protection: Tightly sealed safety glasses. Body protection: Protective work clothing. The exact break trough time has to be found out by the manufacturer of the protective gloves and has to be observed. * 9 Physical and chemical properties: General Information Form: Colour: Smell: Fluid Dark brown Characteristic Change in condition Melting point/melting range: Not determined Boiling point/boiling range: 351 C Flash point: > 110 C (Contd. on page 4)

4 Page 4/6 Ignition temperature: 400 C Self-inflammability: Product is not selfigniting. Danger of explosion: Product is not explosive. Density at 20 C 1.16 g/cm³ Solubility in / Miscibility with Water: Viscosity: kinematic at 20 C: Hydrolized 14 s (DIN 53211/4 s beach) (Contd. of page 3) 10 Stability and reactivity Thermal decomposition / conditions to be avoided: No decomposition if used according to specifications. Dangerous reactions No dangerous reactions known Dangerous products of composition: No dangerous decomposition products known * 11 Toxicological information Acute toxicity: Primary irritant effect: on the skin: Irritant for skin and mucous membranes. on the eye: Irritant effect. Sensitization: Sensitization possible by inhalation. Sensitization possible by skin contact. Additional toxicological information: Harmful Irritant The product shows the following dangers according to the calculation method of the General EC Classification Guidelines for Preparations as issued in the latest version: * 12 Ecological information: General notes: Do not allow product to reach ground water, water bodies or sewage system. Danger to drinking water if even small quantities leak into soil. * 13 Disposal considerations Product: Recommendation Must not be disposed of together with household garbage. Do not allow product to reach sewage system. (Contd. on page 5)

5 Page 5/6 (Contd. of page 4) European waste catalogue WASTES FROM THE MANUFACTURE, FORMULATION, SUPPLY AND USE (MFSU) OF COATINGS (PAINTS, VARNISHES AND VITREOUS ENAMELS), ADHESIVES, SEALANTS AND PRINTING INKS wastes from MFSU and removal of paint and varnish waste paint and varnish containing organic solvents or other dangerous substances Uncleaned packagings: Recommendation: Empty contaminated packagings thoroughly. They can be recycled after thorough and proper cleaning. * 14 Transport information Land transport ADR/RID and GGVS/GGVE (cross-border/domestic) ADR/RID-GGVS/E Class: - Maritime transport IMDG/GGVSea: IMDG/GGVSea Class: - Marine pollutant: No Air transport ICAO-TI and IATA-DGR: ICAO/IATA Class: - * 15 Regulatory information Designation according to EC guidelines: The product has been labelled in accordance with EC Directives / relevant national laws. Code letter and hazard designation of product: Hazard-determining components of labelling:?@g Xn Harmful diphenylmethane-4,4'-di-isocyanante Risk phrases: 20 Harmful by inhalation. 36/37/38 Irritating to eyes, respiratory system and skin. 42/43 May cause sensitisation by inhalation and skin contact. Safety phrases: 9 Keep container in a well-ventilated place. 23 Do not breathe fumes/aerosol. 24 Avoid contact with skin. 26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. 37 Wear suitable gloves. 45 In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). (Contd. on page 6)

6 Page 6/6 Special designation of certain preparations: (Contd. of page 5) Contains isoc yanates. See information supplied by the manufacturer * 16 Other information: These data are based on our present knowledge. However, they shall not constitute a guarantee for any specific product features and shall not establish a legally valid contractual relationship. Relevant R-phrases 20 Harmful by inhalation. 36/37/38 Irritating to eyes, respiratory system and skin. 40 Limited evidence of a carcinogenic effect. 42/43 May cause sensitisation by inhalation and skin contact. 48/20 Harmful: danger of serious damage to health by prolonged exposure through inhalation. Department issuing data specification sheet: Environment protection department. Contact: Mr. Hemming