MATERIAL SAFETY DATA SHEET SECTION 1: IDENTIFICATION OF PRODUCT

Transcription

1 Trade Name: PANGOFOL CHLOROPRENE CEMENT (BLACK) 1 MATERIAL SAFETY DATA SHEET SECTION 1: IDENTIFICATION OF PRODUCT TRADE NAME: PRODUCT NUMBER: WHMIS CLASS: DESCRIPTION: PRODUCT USE: PANGOFOL CHOLOROPRENE CEMENT (BLACK) TPD-RP-002 in TPD-RP-KIT TPD-RP-023 D1B, D2A, D2B PANGOFOL BLACK - NON FLAMMABLE RUBBER CEMENT TRANSPORT: TRICHLOROETHYLENE, CLASS 6.1, UN 1710, PG III HMIS CODE: HEALTH (2) FIRE (1) REACTIVITY (0) SPECIFIC ( ) 0: Minor 1: Light 2: Moderate 3: High 4: Dangerous SUPPLIER : American Biltrite 200 Bank Street Sherbrooke, Quebec, Canada J1H 4K3 EMERGENCY PHONE NUMBER : (Canutec) (Chemtrec) SECTION 2: HAZARDOUS INGREDIENTS HAZARDOUS INGREDIENTS # CAS % T.L.V. LD50 TRICHLOROETHYLENE ppm 10,000 mg/kg (rat dermal) SECTION 3: PHYSICAL PROPERTIES APPEARANCE AND ODOUR: Black, high viscosity liquid, strong solvent odour. BOILING POINT ( C): 87.8 (at 760 mm Hg) SPECIFIC GRAVITY (H 2 0 = 1): 1.46 (at 15.5 C) VAPOUR DENSITY (Air = 1): 4.53 MELTING POINT ( C): N/A EVAPORATION RATE: 3.6 (butyl acetate = 1) SOLUBILITY IN WATER (%): VOLATILE MATTER (% Vol.): 87.3 VAPOUR PRESSURE (mm of Hg): 60 (at 37.7 C) ph: N/A VOC: (lbs/gal)

2 Trade Name: PANGOFOL CHLOROPRENE CEMENT (BLACK) 2 SECTION 4: FIRE AND EXPLOSION HAZARD DATA FLAMMABLE: YES ( ) NO (x) IF YES, IN WHICH CONDITIONS: FLASH POINT ( C): None METHOD: Tag closed cup AUTO-IGNITION TEMPERATURE ( C): 420 FLAMMABLE LIMITS (% VOL. IN AIR): LOWER LIMIT: 8 (at 25 C) UPPER LIMIT: 10.5 (at 25 C) EXTINGUISHING MEDIA: WATER SPRAY ( ) WATER FOG (x) CARBON DIOXIDE (x) FOAM (x) DRY CHEMICAL (x) OTHERS ( ) SPECIAL FIRE FIGHTING PROCEDURES: Self-contained breathing apparatus required. Firefighters should wear the usual protective gear. Stay upwind if possible. UNUSUAL FIRE AND EXPLOSION HAZARDS: Vapours are heavier than air and may travel along the ground and be ignited by flames, sparks or other ignition sources at locations distant from the material handling point. Containers may rupture if exposed to heat or fire. SECTION 5: REACTIVITY DATA STABILITY: UNSTABLE ( ) STABLE (x) CONDITIONS TO AVOID: None known. HAZARDOUS POLYMERIZATION: MAY OCCUR ( ) WILL NOT OCCUR (x) CONDITIONS TO AVOID: INCOMPATIBILITY (materials to avoid): WATER ( ) BASE (x) strong OXIDIZING AGENTS (x) strong ACID (x) strong CORROSIVE ( ) OTHERS (x) Zinc powders. Aluminium powder. HAZARDOUS DECOMPOSITION PRODUCTS: Oxides of carbon (CO, CO 2 ). Phosgene, chlorine (Cl 2 ), hydrogen chloride (HCl). Various hydrocarbons.

3 Trade Name: PANGOFOL CHLOROPRENE CEMENT (BLACK) 3 SECTION 6: PREVENTIVE MEASURES VENTILATION: RESPIRATORY PROTECTION: EYE PROTECTION: HAND PROTECTION: OTHER PROTECTIVE EQUIPMENT: HANDLING: STORAGE: Explosion proof ventilation equipment. Local exhaust and/or general ventilation. Provide sufficient mechanical ventilation to maintain exposure below TLV. NIOSH approved respirator, if necessary (negative pressure type). Splash proof chemical goggles. Chemical resistant gloves. Impervious boots. Impervious clothing. Eye wash facility should be in close proximity. Emergency shower should be in close proximity. Maintain a good personal hygiene. Keep away from heat, sparks and open flames. Avoid breathing vapours / mists. Use adequate ventilation. Wash thoroughly after using, particularly before eating or smoking. Wear personal protective equipment appropriate to task. Empty containers containing residue may cause a hazard. Do not cut, grind, weld or drill empty container. Use proper grounding procedures. Avoid contact with skin, eyes and clothing. Do not eat, drink or smoke in handling area. Launder contaminated clothing prior to reuse. Do not ingest. Store away from all sources of ignition and incompatible materials. Store in a dry place. Keep containers tightly closed. Do not store in aluminium containers, plastic containers or zinc containers. SECTION 7: SPILL OR LEAK PROCEDURES STEPS TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED: WASTE DISPOSAL METHOD: OTHER INFORMATION: Recover using a pump. Eliminate all sources of ignition. Dike area to prevent spreading. Evacuate all non-essential personnel. Prevent entry into drains, sewers and other waterways. Absorb residual material with sand or other absorbent material. Stop leak if without risk. Wear appropriate protective equipment. Ground handling equipment. Stay upwind. Transfer to an approved container for disposal. Notify the appropriate authorities as required. In accordance with municipal, provincial and federal regulations. Material is moderately toxic to aquatic organisms on an acute basis (LC50 between 1 and 10 mg/l in most sensitive species). All ingredients are listed on the TSCA inventory.

4 Trade Name: PANGOFOL CHLOROPRENE CEMENT (BLACK) 4 SECTION 8: HEALTH HAZARD DATA ABSORPTION ROUTE: SKIN (x) EYES (x) INHALATION (x) INGESTION (x) EFFECTS OF OVEREXPOSURE: SKIN: EYES: INHALATION: INGESTION: CARCINOGENIC: TERATOGENIC: MUTAGENIC: SYNECGISTIC MATERIALS: May affect the central nervous system. May cause kidney effects, hearing loss and liver effects. May cause severe irritation, drying and cracking, mild irritation, redness or burning sensation, numbness in fingers if immersed in liquid. May be harmful if absorbed through the skin. May cause irritation, redness and tearing, stinging. Corneal injury is unlikely. May cause swelling, pain and discomfort. Vapors may cause irritation. Upper respiratory tract irritation may occur. May cause dizziness or drunkenness effects, an irregular heartbeat. In extreme cases, unconsciousness and death may occur. May cause nausea, vomiting and diarrhea, gastrointestinal irritation. Ingestion of large amounts may cause injury. No hazard known for ingestion of small quantities. Aspiration hazard if swallowed. May cause central nervous system depression. Large amounts may be fatal. Alcohol. SECTION 9: FIRST AID PROCEDURES SKIN: EYES: INHALATION: INGESTION: ADDITIONAL INFORMATION: Remove contaminated clothing. Wash with mild soap and water. Consult a physician if irritation persists. Flush with water for at least 15 minutes, holding eyelids open with fingers. Consult a physician if irritation persists. Keep person warm and at rest. Remove victim to fresh air. If breathing is difficult, administer oxygen. If not breathing, have qualified person give artificial respiration. Obtain medical attention. If victim is drowsy or unconscious, place on left side with head down. Do not leave individual unattended. Never give anything by mouth to an unconscious person. Do not induce vomiting, seek immediate medical attention. The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. This company shall not be held liable for any inaccuracies.

5 Trade Name: PANGOFOL CHLOROPRENE CEMENT (BLACK) 5 PREPARED BY: SECTION 10: PREPARATION INFORMATION M ichel Leblanc REVISION DATE: May 05, 2010 REPLACING OLD VERSION FROM: March 06, 2007 (March 26, 2010) REASON: Sections 1 and 10 AMERICAN BILTRITE has compiled the information and recommendations contained in this Material Safety Data Sheet from sources believed to be reliable and to represent the most reasonable current opinion on the subject when the MSDS was prepared. No warranty, guaranty or representation is made as to the correctness or sufficiency of the information. The user of this product must decide for himself what safety measures are necessary to safely use this product, either alone or in combination with other products. N/A: Not applicable : Not determined N/E: Not established