EU Safety Data Sheet. habasit. Vulcol (Version 99)

Transcription

1 Company Page 1 of 8 Habasit AG, Römerstrasse 1, CH-4153 Reinach Tel (0)61/ , Telefax ++41 (0)61/ Commercial product name and supplier Commercial product name / Designation Application / Use Producer Supplier TOX emergency number Public Product No. Elastomer adhesive for flat belts, conveyor- and processingbelts, machine tapes Habasit AG, Römerstrasse 1, CH-4153 Reinach Tel (0) 61/ Telefax ++41 (0) 61/ Habasit AG, Römerstrasse 1, CH-4153 Reinach Tel (0) 61/ Telefax ++41 (0) 61/ (0)44 / (Toxicological Information Centre, CH Zurich) 2 Hazards identification Highly flammable. Possible risk of harm to the unborn child. Vapours may cause drowsiness and dizziness. Possible risk of irreversible effects. Irritating to eyes and skin. Harmful: danger of serious damage to health by prolonged exposure through inhalation.

2 Page 2 of Composition Chemical characterization Hazardous components CAS No CAS No CAS No CAS No NBR solution Adhesive Dangerous substances according to the criteria of the EU Directive 1999/45/EC: 2.5 % phenole EINECS/ELINCS No.: T: Toxic. R34: Causes burns. R24/25: Toxic in contact with skin and if swallowed. MAK values (D): 5 ppm 19 mg/m % Ethylacetat EINECS/ELINCS No.: Xi: Irritant. F: Highly flammable. R11: Highly flammable. R36: Irritating to eyes. R66: Repeated exposure may cause skin dryness or cracking. R67: Vapours may cause drowsiness and dizziness % Methyl ethyl ketone EINECS/ELINCS No.: Xi: Irritant. F: Highly flammable. R11: Highly flammable. R36: Irritating to eyes. R66: Repeated exposure may cause skin dryness or cracking. R67: Vapours may cause drowsiness and dizziness. MAK values (D): 200 ppm 600 mg/m % Toluene EINECS/ELINCS No.: Xn: Harmful. F: Highly flammable. R11: Highly flammable. R38: Irritating to skin. R63: Possible risk of harm to the unborn child. R65: Harmful: may cause lung damage if swallowed. R67: Vapours may cause drowsiness and dizziness. R48/20: Harmful: danger of serious damage to health by prolonged exposure through inhalation. MAK values (D): 50 ppm 190 mg/m3 None 4 First aid measures Remove to fresh air if effects occur. Consult a physician Eye contact Skin contact Ingestion Inhalation In case of eye contact, thoroughly rinse with water and consult a doctor. Rinse off immediately with soap and plenty of water. Remove soiled clothing and shoes. In case of irritation, consult a doctor. Do not induce vomiting. Call a physician and/or transport to emergency facility immediately. Take into fresh air. In case of difficulty with breathing, seek medical advice. Remove contaminated clothing Fire-fighting measures Suitable extinguishing media Water fog, carbon dioxide, dry chemical, foam, alcohol

3 resistant foam. Page 3 of Extinguishing media to avoid Do not use direct water stream. During a fire, smoke may contain the original material in addition to unidentified toxic and/or irritating compounds. Wear self-contained breathing apparatus. Violent eruption of containers may occur under fire conditions. 6 Accidental release measures Do not allow to flow off into the drains or waters. Remove all ignition hazards. Ensure adequate ventilation. Keep personnel at a distance, upwind of the hazard. Wear personal protective clothing. Clean up with absorbent material, then collect for disposal. Sweep up and transfer into properly labeled containers for recovery or disposal, see Section 13, Disposal Considerations Handling and storage Handling Industrial hygiene Storage Place of storage Fire- and explosion-protection Flammable: keep away from possible ignition sources. Vapours of this product are heavier than air and will collect in low areas such as pits, storage tanks, and other confined areas. Ensure efficient venting while applying the product. Take off immediately all contaminated clothing. Avoid contact with skin and eyes and do not breathe vapours. Wash hands before smoking or eating. Store containers tightly closed in a cool, well ventilated area. Take precautionary measures against electrostatic charging. Keep away from sources of ignition. 8 Exposure controls / Personal protection Exposure controls Exposure limit values Provide general and/or local exhaust ventilation to control airborne levels below the exposure guidelines. European Union: Methyl ethyl ketone: 8 hours: 200ppm / 600 mg/m3 Short-term exposure (15 min): 300ppm / 900 mg/m3 Germany: Ethylacetate: MAK (Maximale Arbeitsplatzkonzentration): 400ppm / 1500 mg/m3 Short-term exposure (4x15min), 2 (I): 800ppm / 3000 mg/m3 Methyl ethyl ketone: MAK (Maximale Arbeitsplatzkonzentration): 200ppm / 600

4 Page 4 of 8 mg/m3 Short-term exposure (4x15min), 1 (I): 200ppm / 600 mg/m3 May be absorbed through skin in harmful amounts Toluene: MAK (Maximale Arbeitsplatzkonzentration): 50ppm / 190 mg/m3 Short-term exposure 4 (II): 200ppm / 760 mg/m3 May be absorbed through skin in harmful amounts Phenol MAK (Maximale Arbeitsplatzkonzentration): 2ppm / 7.8mg/m3 May be absorbed through skin in harmful amounts Occupational exposure controls Respiratory protection Hand protection Eye protection Other Respiratory protection usually not required with adequate ventilation. In exceptional cases (spillage or accidental release, exceeding airborne aerosols limit), a respirator must be worn. Comply with any wearing time limits! Respirator cartridge: gas filter type A, brown (organic gases and vapors). Disposable polyethylene or latex gloves provide adequate hand protection for occasional application of adhesive. In the case of frequent application of adhesive, gloves made of the following materials are better suited, but only to a limited extent (penetration time with complete immersion >= 10 minutes.): butyl rubber - BR (0.7mm / 0.028"). These gloves are not suitable for continuous contact (complete immersion)! Recommendation: dispose of contaminated gloves. Gloves made of the following materials are not suited to the application of adhesive: thick fabric, leather. Use safety glasses. Work clothing. 8.4 Environmental exposure controls Physical and chemical properties Appearance Colour Odour liquid amber to brown solvent 9.4 Change of physical state Test method: Boiling point 9.5 Density Vapour pressure 76 C (1013 mbar) 105 hpa

5 9.7 Viscosity mpa s (20 C) 9.8 Solubility Water partially miscible Page 5 of ph Not applicable Flash point 9.11 Ignition temperature -4 C ethyl acetate 460 C (1013 mbar) Ethyl acetate: 9.12 Explosion limits Lower: 1.2 Vol% Upper: 11.5 Vol% 9.13 Part. coeff. n-octanol/water Evaporat. rate ((1013 mbar) ) VOC (volatile organic carbons) 63% Stability and reactivity Thermal decomposition No decomposition until start of boiling Hazardous decomposition products In case of fire, watch for hyrogen cyanide and hydrochloric acid Conditions / materials to avoid None known None Toxicological information Acute toxicity Subacute / Chronic toxicity LD50 (oral, rat) 636 mg/kg LD50 (dermal, rabbit) mg/kg Phenol No data available for the product itself. Toluene: LD50 (oral, rat) 300 mg/kg Irritating to mucous membranes and skin. LC50 (inh., rat) 4 h 316 mg/l May cause eye irritation. Repr. Cat Harmful by inhalation, in contact with skin and if swallowed. Excessive exposure may cause headache, dizziness, drowsiness.

6 Page 6 of Ecological information Ecotoxicity Mobility Persistence and degradability Bioaccumulative potential No data available for the product itself. 13 Disposal considerations National/regional regulations have to be observed. Individual packs to be added to the domestic waste, after evaporation of the solvents. Unopened or expired packs may be disposed of as special waste. Dispose uncleaned packaging as the unused product. Customers are advised to check their local legislation governing the disposal of hazardous chemical waste EU waste key adhesive 14 Transport information 14.1 Transport at land ADR 3 RID 3 UN Number 1133 Kemler Number 33 Packing Group Proper shipping name II UN 1133 adhesive, containing flammable liquid, 3, II (D/E) 14.2 Transport at sea ADNR - IMDG - UN Number 1133 EMS F-E, S-D MFAG - Packing Group II Proper shipping name UN 1133 Adhesive containing flammable liquids, 3, II, Flp. -4 C c.c. Marine pollutant

7 14.3 Air transport ICAO / IATA-DGR UN Number Proper shipping name Subsidiary Risk Labels Packing Group Passenger airplane Packing Instructions max. Cargo Airplane Packing Instructions max Page 7 of ADR: Limited quantity LQ 6: max. 5 litres per inner packing, max. 30 litres in total 15 Regulatory information EEC Classification and User Label Information according to Directive 1999/45/EC UN number 1133 National regulations 15.3 EINECS/ELINCS number 15.4 Hazard symbols F Xn 15.5 Hazard designation Xn: Harmful. F: Highly flammable. Contains phenole, Toluene Risk phrases 15.7 Safety phrases 15.8 MAK value R: /38-48/ /38 48/20 S: Highly flammable. Possible risk of harm to the unborn child. Vapours may cause drowsiness and dizziness. Possible risk of irreversible effects. Irritating to eyes and skin. Harmful: danger of serious damage to health by prolonged exposure through inhalation. 16 Keep away from sources of ignition - No smoking. 23 Do not breathe vapour. 24 Avoid contact with skin. 26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advise. 37 Wear suitable gloves. 60 This material and its container must be disposed of as hazardous waste.

8 15.9 BVD classification (CH) VbF (D) F1 l Fu PN2 Z AI None. Page 8 of 8 16 Other information Read the producer s technical documents. For industrial use only. Observe the expiry date. Avoid exposure - obtain special instructions before use. Applicable local workplace hygiene regulations as well as statutory regulations must be observed. These details are not transferable to other products. The above mentioned data correspond to our present state of knowledge and experience. The safety data sheet serves as description of the products in regard to necessary safety measures. The indications do not have the meaning of guarantees on properties. This safety data sheet has been generated with the safety database 'ChemManager', ASSiST Applied Software Solutions in Science and Technology AG, Weiherweg 3, CH-4104 Oberwil, Switzerland Regulation (EC) No 1907/2006 (REACH)