Ivoclar Vivadent AG, Bendererstrasse 2, FL Schaan Principality of Liechtenstein. Fluor Protector. Fürstentum Liechtenstein

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1 Page 1 of 5 Company Ivoclar Vivadent AG, Bendererstrasse 2, FL Schaan Principality of Liechtenstein Commercial product name and supplier Commercial product name / Designation Application / Use Producer Supplier TOX emergency number Protective varnish for desensitisation and caries prophylaxis Ivoclar Vivadent AG, Bendererstrasse 2, FL Schaan Fürstentum Liechtenstein Emergency-Call: +423 / or Ivoclar Vivadent AG, FL-9494 Schaan, Liechtenstein Composition Chemical characterization Hazardous components CAS No CAS No CAS No Mixture of ethyl acetate, isoamylpropionate, polyisocyanate and fluorsilane > 65 % Ethyl acetate Xi: Irritant. F: Highly flammable. R11: Highly flammable. R36: Irritating to eyes. R66: Repeated exposure may cause skin dryness or cracking R67: Vapours may cause drowsiness and dizziness. < 21 % Isoamylpropionate < 12 % Polyisocyanate 3 Hazards identification Highly flammable and irritating. Irritating to eyes, respiratory system and skin. Do not breathe vapour First aid measures Eye contact Skin contact Ingestion Inhalation Flush eyes with plenty of water (10-15 min.). Call a physician. Wash thoroughly with soap and water. No hazards anticipated from swallowing small amounts incidentally to normal handling. Take into fresh air. Remove contaminated clothing.

2 Page 2 of Fire-fighting measures Suitable extinguishing media Extinguishing media to avoid Water fog, carbon dioxide, foam, dry chemicals. Do not use direct water stream. Cool containers in the vicinity of the blaze using a water spray. 6 Accidental release measures Clean up with absorbent material. Dispose of according to local and national regulations Handling and storage Handling Industrial hygiene Storage Place of storage Fire- and explosion-protection Only adequately trained personnel should handle this product. Keep out of reach of children. Usual hygienic measures for dental practice. When using, do not eat, drink or smoke. Store at 2-28 C / F Store in dry well ventilated area away from sources of ignition and heat. Keep away from sources of ignition. 8 Exposure controls / Personal protection Technical measures Control of threshold limits Personal protective equipment Respiratory protection Hand protection Eye protection Other Good general ventilation should be sufficient. MAK (Maximale Arbeitsplatzkonzentration, Germany) is 400 ppm. ACGIH (American Conference of Governmental Industrial Hygienists, USA) Threshold Limit Value (TLV) is 400 ppm. Not required. Solvent resistant gloves. Safety goggles. Eye wash fountain should be located in immediate work area Physical and chemical properties Appearance Colour Odour clear liquid colourless characteristic 9.4 Change of physical state Test method:

3 Page 3 of Density g/cm³ (20 C) Vapour pressure Viscosity Solubility Solubility in water 9.9 ph Flash point Ignition temperature 9 C > 400 C 9.12 Explosion limits 9.13 Lower: Upper: Stability and reactivity Thermal decomposition None, if used in accordance to instructions Hazardous decomposition products None under normal conditions of storage and use Hazardous reactions None, if used in accordance to instructions. The product is highly flammable. Avoid ignition sources such as flames or spark producing equipment Toxicological information Acute toxicity Subacute / Chronic toxicity Oral LD50 for rats: > 5'000 mg/kg No data available Excessive exposure may cause eye and respiratory irritation. 12 Ecological information German 'Wassergefaehrdungs Klasse (WGK): 1 The product must not enter effluent, ground water, surface water or the soil.

4 Page 4 of 5 13 Disposal considerations Take to an approved landfill or a waste incineration plant, under conditions approved by the local authority EU waste key Transport information 14.1 Transport at land ADR 3 RID 3 UN Number 1173 Kemler Number --- Proper shipping name Ethyl acetate 14.2 Transport at sea ADNR 3 IMDG UN Number 1173 EMS F-E, S-D MFAG 330 Proper shipping name Ethyl acetate 14.3 Air transport ICAO / IATA-DGR Class 3 UN Number 1173 Proper shipping name Ethyl acetate Passenger airplane Cargo Airplane Subsidiary Risk --- Labels Flamm. liquid Packing Instructions 305 max. 5 L Packing Instructions 307 max. 60 L 14.4 Sample shipment not allowed by mail Regulatory information UN number 1173 National regulations This product requires classification according to the criteria of the "Gefahrstoffverordnung". The product is a medical device according to the EC-directive 93/42/EEC. This product is classified as a medical device under US regulations and has been reviewed by the US Food and drug Administration EU number ---

5 Page 5 of Hazard symbols F Xi 15.5 Hazard designation Xi: Irritant. F: Highly flammable. Contains Ethyl acetate, Isoamylpropionate, Polyisocyanate Risk phrases Safety phrases 15.8 MAK value 400 ml/m³ (ppm) BVD classification (CH) VbF (D) R: 11-36/37/ /37/38 S: F1 l AI 16 Other information Version: 5 Changes: 4.3/11.1/11.2/13 Highly flammable. Irritating to eyes, respiratory system and skin. 2 Keep out of the reach of children. 16 Keep away from sources of ignition - No smoking. 23 Do not breathe vapour. 26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advise. The above mentioned data correspond to our present state of knowledge and experience. The safety data sheet serves as description of the products in regard to necessary safety measures. The indications do not have the meaning of guarantees on properties. This safety data sheet has been generated with the safety database 'ChemManager', ASSiST Applied Software Solutions in Science and Technology AG, Weiherweg 3, CH-4104 Oberwil, Switzerland 91/155/EEC