Safety Data Sheet MasterTop SRS 40TC also DEGADUR 410 Revision date : 2013/12/20 Page: 1/6

Transcription

1 MasterTop SRS 40TC also DEGADUR 410 Revision date : 2013/12/20 Page: 1/6 Version: 2.2 ( /SDS_GEN_CA/EN) 1. Product and Company Identification Company BASF Canada Inc. 100 Milverton Drive Mississauga, ON L5R 4H1, CANADA 24 Hour Emergency Response Information CANUTEC (reverse charges): (613) BASF HOTLINE: (800) 454-COPE (2673) 2. Hazards Identification Emergency overview FLAMMABLE. SENSITIZER. May cause sensitization by skin contact. State of matter: liquid Colour: colourless Odour: sweetish, ester-like Potential health effects Irritation / corrosion: May cause slight irritation to the eyes. May cause slight irritation to the skin. May cause slight irritation to the respiratory tract. Sensitization: Caused skin sensitization in animal studies. Caused sensitization in humans. Chronic toxicity: Repeated dose toxicity: After repeated exposure the prominent effect is local irritation. Signs and symptoms of overexposure: Overexposure may cause:, asthma, tiredness, loss of memory, pain in the extremities, sleep disturbances, headache Potential environmental effects Aquatic toxicity: The product has not been tested.

2 MasterTop SRS 40TC also DEGADUR 410 Revision date : 2013/12/20 Page: 2/6 Version: 2.2 ( /SDS_GEN_CA/EN) 3. Composition / Information on Ingredients CAS Number Content (W/W) Hazardous ingredients >= <= 60.0 % methyl methacrylate >= <= 30.0 % 2-ethylhexyl acrylate 4. First-Aid Measures If inhaled: If not breathing, give artificial respiration. Remove victim to fresh air and away from exposure immediately. If on skin: If symptoms persist, seek medical advice. Wash thoroughly with soap and water. If in eyes: Flush with copious amounts of water for at least 15 minutes. If swallowed: Never induce vomiting or give anything by mouth if the victim is unconscious or having convulsions. Do not induce vomiting unless told to by a poison control center or doctor. If person is conscious and can swallow, give two glasses of water. 5. Fire-Fighting Measures Flash point: 9 C Information on: methyl methacrylate Autoignition: 435 C Literature data. Suitable extinguishing media: carbon dioxide, dry powder, foam, water spray Hazards during fire-fighting: See MSDS section 7 - Handling and storage. Further information: Run-off water from fire may cause pollution. Keep containers cool by spraying with water if exposed to fire. Containers may rocket or explode in heat of fire. 6. Accidental release measures Cleanup: Dike spillage. Contain spills and cover with absorbent material. 7. Handling and Storage Handling General advice: Take precautionary measures against static discharges. Ensure thorough ventilation of stores and work areas.

3 MasterTop SRS 40TC also DEGADUR 410 Revision date : 2013/12/20 Page: 3/6 Version: 2.2 ( /SDS_GEN_CA/EN) Storage General advice: Keep container tightly closed. Keep only in the original container in a cool, dry, well-ventilated place away from ignition sources, heat or flame. 8. Exposure Controls and Personal Protection Components with occupational exposure limits methyl methacrylate OSHA PEL PEL 100 ppm 410 mg/m3 ; ACGIH TLV TWA value 50 ppm ; STEL value 100 ppm ; Advice on system design: Provide local exhaust ventilation to maintain recommended P.E.L. Personal protective equipment Respiratory protection: Wear a NIOSH-certified (or equivalent) respirator as necessary. Wear respiratory protection if ventilation is inadequate. Hand protection: Wear chemical resistant protective gloves. Eye protection: Safety glasses with side-shields. Tightly fitting safety goggles (chemical goggles). Safety glasses/face shield Body protection: chemical-protection suit (f.e. according to EN 14605), Protective suit, Impermeable protective clothing General safety and hygiene measures: Food, beverages, and tobacco products shall not be carried, stored, or consumed where this material is in use. Hands and/or face should be washed before breaks and at the end of the shift. Handle in accordance with good industrial hygiene and safety practice. 9. Physical and Chemical Properties Form: liquid Odour: sweetish, ester-like Odour threshold: < 1 ppm Colour: colourless ph value: not applicable Boiling point: approx. 100 C Vapour pressure: The product has not been tested. Density: 0.98 g/cm3 ( 20 C) (DIN 51757) Bulk density: not applicable Information on: methyl methacrylate Partitioning coefficient n ( 20 C) octanol/water (log Pow): Viscosity, dynamic: mpa.s ( 20 C) (DIN 53018) Solubility in water: approx. 20 g/l ( 20 C) Other Information: If necessary, information on other physical and chemical parameters is indicated in this section. 10. Stability and Reactivity Conditions to avoid: Avoid all sources of ignition: heat, sparks, open flame. Avoid direct sunlight.

4 MasterTop SRS 40TC also DEGADUR 410 Revision date : 2013/12/20 Page: 4/6 Version: 2.2 ( /SDS_GEN_CA/EN) Substances to avoid: bases, strong oxidizing agents, strong acids, peroxides, amines Hazardous reactions: The product is chemically stable. Decomposition products: carbon oxides Thermal decomposition: > 95 F May decompose if overheated and/or subjected to prolonged heating. Oxidizing properties: not fire-propagating 11. Toxicological information Acute toxicity Information on: 2-ethylhexyl acrylate Assessment of acute toxicity: Of low toxicity after single ingestion. Virtually nontoxic after a single skin contact. The inhalation of a highly enriched/saturated vapor-air-mixture represents an unlikely acute hazard. Oral: Type of value: LD50 Species: rat Value: > 5,000 mg/kg Inhalation: Type of value: LC50 Species: rat Value: 29.8 mg/l Exposure time: 4 h Dermal: Type of value: LD50 Species: rabbit Value: > 5,000 mg/kg Irritation / corrosion Information on: methyl methacrylate Assessment of irritating effects: Irritating to skin. Not irritating to the eyes. Information on: 2-ethylhexyl acrylate Assessment of irritating effects: Not irritating to the eyes. Skin contact causes irritation. Sensitization Information on: methyl methacrylate Assessment of sensitization: Caused skin sensitization in animal studies. Information on: 2-ethylhexyl acrylate Assessment of sensitization: Sensitization after skin contact possible.

5 MasterTop SRS 40TC also DEGADUR 410 Revision date : 2013/12/20 Page: 5/6 Version: 2.2 ( /SDS_GEN_CA/EN) Repeated dose toxicity Information on: methyl methacrylate Assessment of repeated dose toxicity: After repeated exposure the prominent effect is local irritation. Information on: 2-ethylhexyl acrylate Assessment of repeated dose toxicity: The substance may cause damage to the olfactory epithelium after repeated inhalation. After repeated exposure the prominent effect is local irritation. 12. Ecological Information Other adverse effects: Acutely harmful for aquatic organisms. 13. Disposal considerations Waste disposal of substance: Dispose of in accordance with national, state and local regulations. Recommendations: Use excess product in an alternate beneficial application. 14. Transport Information Land transport TDG Hazard class: 3 Packing group: II ID number: UN 1866 Hazard label: 3 Proper shipping name: RESIN SOLUTION Sea transport IMDG Hazard class: 3 Packing group: II ID number: UN 1866 Hazard label: 3 Marine pollutant: NO Proper shipping name: RESIN SOLUTION Air transport IATA/ICAO Hazard class: 3 Packing group: II ID number: UN 1866 Hazard label: 3 Proper shipping name: RESIN SOLUTION

6 MasterTop SRS 40TC also DEGADUR 410 Revision date : 2013/12/20 Page: 6/6 Version: 2.2 ( /SDS_GEN_CA/EN) 15. Regulatory Information Federal Regulations Registration status: Chemical DSL, CA released / listed WHMIS classification: B2: Flammable Liquid D2B: Materials Causing Other Toxic Effects - Toxic material THIS PRODUCT HAS BEEN CLASSIFIED IN ACCORDANCE WITH THE HAZARD CRITERIA OF THE CPR AND THE MSDS CONTAINS ALL THE INFORMATION REQUIRED BY THE CPR. 16. Other Information We support worldwide Responsible Care initiatives. We value the health and safety of our employees, customers, suppliers and neighbors, and the protection of the environment. Our commitment to Responsible Care is integral to conducting our business and operating our facilities in a safe and environmentally responsible fashion, supporting our customers and suppliers in ensuring the safe and environmentally sound handling of our products, and minimizing the impact of our operations on society and the environment during production, storage, transport, use and disposal of our products. SDS Prepared by: BASF NA Product Regulations msds@basf.com BASF HOTLINE (800) 454 COPE (2673) SDS Prepared on: 2013/12/20 END OF DATA SHEET

7 MasterTop SRS 61BC Revision date : 2018/03/26 Page: 1/10 Version: 3.0 ( /SDS_GEN_CA/EN) 1. Identification Product identifier used on the label MasterTop SRS 61BC Recommended use of the chemical and restriction on use Recommended use*: for industrial and professional users * The Recommended use identified for this product is provided solely to comply with a Federal requirement and is not part of the seller's published specification. The terms of this (SDS) do not create or infer any warranty, express or implied, including by incorporation into or reference in the seller's sales agreement. Details of the supplier of the safety data sheet Company: BASF Canada Inc. 100 Milverton Drive Mississauga, ON L5R 4H1, CANADA Telephone: Emergency telephone number CANUTEC (reverse charges): (613) BASF HOTLINE: (800) 454-COPE (2673) Other means of identification Chemical family: No data available. 2. Hazards Identification According to Hazardous Products Regulations (HPR) (SOR/ ) Classification of the product Flam. Liq. 2 Flammable liquids Skin Corr./Irrit. 2 Skin corrosion/irritation Skin Sens. 1A Skin sensitization STOT SE 3 (irritating to Specific target organ toxicity single exposure respiratory system) STOT RE 2 (oral) Specific target organ toxicity repeated exposure Aquatic Acute 3 Hazardous to the aquatic environment - acute

8 MasterTop SRS 61BC Revision date : 2018/03/26 Page: 2/10 Version: 3.0 ( /SDS_GEN_CA/EN) Label elements Pictogram: Signal Word: Danger Hazard Statement: H225 H315 H317 H335 H373 H402 Highly flammable liquid and vapour. Causes skin irritation. May cause an allergic skin reaction. May cause respiratory irritation. May cause damage to organs through prolonged or repeated oral exposure. Harmful to aquatic life. Precautionary Statements (Prevention): P280 Wear protective gloves and eye/face protection. P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P260 Do not breathe dust/gas/mist/vapours. P271 Use only outdoors or in a well-ventilated area. P243 Take action to prevent static discharges. P273 Avoid release to the environment. P241 Use explosion-proof electrical/ventilating/lighting/equipment. P272 Contaminated work clothing should not be allowed out of the workplace. P240 Ground and bond container and receiving equipment. P242 Use only non-sparking tools. P264 Wash with plenty of water and soap thoroughly after handling. Precautionary Statements (Response): P312 Call a POISON CENTER or doctor/physician if you feel unwell. P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. P314 Get medical advice/attention if you feel unwell. P304 + P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing. P333 + P311 If skin irritation or rash occurs: Call a POISON CENTER or doctor/physician. P332 + P313 If skin irritation occurs: Get medical advice/attention. P362 + P364 Take off contaminated clothing and wash it before reuse. P370 + P378 In case of fire: Use to extinguish. Precautionary Statements (Storage): P233 Keep container tightly closed. P403 + P235 Store in a well-ventilated place. Keep cool. P405 Store locked up. Precautionary Statements (Disposal): P501 Dispose of contents/container to hazardous or special waste collection point. Hazards not otherwise classified

9 MasterTop SRS 61BC Revision date : 2018/03/26 Page: 3/10 Version: 3.0 ( /SDS_GEN_CA/EN) If applicable information is provided in this section on other hazards which do not result in classification but which may contribute to the overall hazards of the substance or mixture. 3. Composition / Information on Ingredients According to Hazardous Products Regulations (HPR) (SOR/ ) CAS Number Weight % Chemical name >= < 75.0% Methyl methacrylate >= < 20.0% 2-Butenedioic acid (Z)-, dibutyl ester >= < 5.0% 1,4-butanediol dimethacrylate >= < 1.0% 1,1'-(p-tolylimino)dipropan-2-ol 4. First-Aid Measures Description of first aid measures General advice: First aid personnel should pay attention to their own safety. Remove contaminated clothing. If inhaled: Remove the affected individual into fresh air and keep the person calm. If breathing difficulties develop, aid in breathing and seek immediate medical attention. If on skin: Wash thoroughly with soap and water. Under no circumstances should organic solvent be used. If irritation develops, seek medical attention. If in eyes: Wash affected eyes for at least 15 minutes under running water with eyelids held open, consult an eye specialist. If swallowed: Rinse mouth and then drink plenty of water. Do not induce vomiting due to aspiration hazard. Do not induce vomiting unless told to by a poison control center or doctor. Most important symptoms and effects, both acute and delayed Symptoms: skin irritation, allergic symptoms Hazards: No applicable information available. Indication of any immediate medical attention and special treatment needed Note to physician Treatment: Treat according to symptoms (decontamination, vital functions), no known specific antidote. 5. Fire-Fighting Measures Extinguishing media

10 MasterTop SRS 61BC Revision date : 2018/03/26 Page: 4/10 Version: 3.0 ( /SDS_GEN_CA/EN) Suitable extinguishing media: dry powder, alcohol-resistant foam Unsuitable extinguishing media for safety reasons: water jet Special hazards arising from the substance or mixture Hazards during fire-fighting: carbon dioxide, carbon monoxide, harmful vapours, nitrogen oxides, fumes/smoke, carbon black Advice for fire-fighters Protective equipment for fire-fighting: Wear a self-contained breathing apparatus. Further information: The degree of risk is governed by the burning substance and the fire conditions. Containers may rocket or explode in heat of fire. Keep containers cool by spraying with water if exposed to fire. Collect contaminated extinguishing water separately, do not allow to reach sewage or effluent systems. Contaminated extinguishing water must be disposed of in accordance with official regulations. 6. Accidental release measures Personal precautions, protective equipment and emergency procedures Use personal protective clothing. Avoid prolonged inhalation. Avoid contact with the skin, eyes and clothing. Avoid all sources of ignition: heat, sparks, open flame. Environmental precautions Prevent spread over a wide area (e.g. by containment or oil barriers). Contain contaminated water/firefighting water. Do not discharge into drains/surface waters/groundwater. Methods and material for containment and cleaning up For large amounts: Pump off product. For residues: Pick up with inert absorbent material (e.g. sand, earth etc.). Correctly dispose of recovered product immediately. 7. Handling and Storage Precautions for safe handling Take precautionary measures against static discharges. Keep away from sources of ignition - No smoking. Provide good room ventilation even at ground level (vapours are heavier than air). Protection against fire and explosion: Sources of ignition should be kept well clear. Take precautionary measures against static discharges. Substance/product can form explosive mixture with air. Vapours are heavier than air and may accumulate in low areas and travel a considerable distance up to the source of ignition. Conditions for safe storage, including any incompatibilities Segregate from foods and animal feeds.

11 MasterTop SRS 61BC Revision date : 2018/03/26 Page: 5/10 Version: 3.0 ( /SDS_GEN_CA/EN) Further information on storage conditions: Keep only in the original container in a cool, wellventilated place. Protect from direct sunlight. Keep away from sources of ignition. Keep at temperature not exceeding 25 C. Vapours may travel along floor and ignite at a location distant from the handling point. 8. Exposure Controls/Personal Protection Components with occupational exposure limits Methyl methacrylate OSHA PEL PEL 100 ppm 410 mg/m3 ; TWA value 100 ppm 410 mg/m3 ; ACGIH TLV TWA value 50 ppm ; STEL value 100 ppm ; Advice on system design: No applicable information available. Personal protective equipment Respiratory protection: Wear a NIOSH-certified (or equivalent) organic vapour/particulate respirator. Hand protection: Wear chemical resistant protective gloves. Eye protection: Safety glasses with side-shields. Body protection: Body protection must be chosen based on level of activity and exposure., Antistatic apron General safety and hygiene measures: Avoid inhalation of dusts/mists/vapours. Avoid contact with the skin, eyes and clothing. Avoid prolonged and/or repeated contact with the skin. Handle in accordance with good building materials hygiene and safety practice. When using, do not eat, drink or smoke. Hands and/or face should be washed before breaks and at the end of the shift. At the end of the shift the skin should be cleaned and skin-care agents applied. Gloves must be inspected regularly and prior to each use. Replace if necessary (e.g. pinhole leaks). 9. Physical and Chemical Properties Form: slightly viscous Odour: ester-like Odour threshold: < 1 ppm Colour: bluish ph value: not applicable Melting point: No applicable information available. Boiling point: approx. 100 C Sublimation No applicable information available. temperature: Flash point: 10 C Information on: Methyl methacrylate Flash point: 10 C (DIN 51755, closed cup) Flammability: Highly flammable. Lower explosion limit: 2.1 %(V)

12 MasterTop SRS 61BC Revision date : 2018/03/26 Page: 6/10 Version: 3.0 ( /SDS_GEN_CA/EN) Information on: Methyl methacrylate Lower explosion limit: For liquids not relevant for classification and labelling. The lower explosion point may be 5-15 C below the flash point. Upper explosion limit: 12.5 %(V) Information on: Methyl methacrylate Upper explosion limit: For liquids not relevant for classification and labelling. Autoignition: Study does not need to be conducted. Vapour pressure: approx. 40 hpa ( 20 C) Density: 1.01 g/cm3 ( 20 C) Relative density: No applicable information available. Vapour density: No applicable information available. Partitioning coefficient n- not applicable octanol/water (log Pow): Thermal decomposition: Vapours may form explosive mixture with air. No decomposition if stored and handled as prescribed/indicated. Viscosity, dynamic: approx mpa.s ( 23 C) Viscosity, kinematic: No applicable information available. Solubility in water: approx. 20 g/l ( 20 C) Miscibility with water: ( 20 C) partly miscible Solubility (quantitative): No applicable information available. Solubility (qualitative): No applicable information available. Evaporation rate: No applicable information available. Other Information: If necessary, information on other physical and chemical parameters is indicated in this section. 10. Stability and Reactivity Reactivity No hazardous reactions if stored and handled as prescribed/indicated. Corrosion to metals: Corrosive effects to metal are not anticipated. Oxidizing properties: Based on its structural properties the product is not classified as oxidizing. Chemical stability The product is stable if stored and handled as prescribed/indicated. Possibility of hazardous reactions No hazardous reactions if stored and handled as prescribed/indicated. Conditions to avoid Avoid all sources of ignition: heat, sparks, open flame. Incompatible materials strong oxidizing agents, amines, peroxides, sulphur compounds, alkalies, reducing agents

13 MasterTop SRS 61BC Revision date : 2018/03/26 Page: 7/10 Version: 3.0 ( /SDS_GEN_CA/EN) Hazardous decomposition products Decomposition products: No hazardous decomposition products if stored and handled as prescribed/indicated. Thermal decomposition: Vapours may form explosive mixture with air. No decomposition if stored and handled as prescribed/indicated. 11. Toxicological information Primary routes of exposure Routes of entry for solids and liquids are ingestion and inhalation, but may include eye or skin contact. Routes of entry for gases include inhalation and eye contact. Skin contact may be a route of entry for liquefied gases. Acute Toxicity/Effects Acute toxicity Assessment of acute toxicity: Virtually nontoxic after a single ingestion. Virtually nontoxic by inhalation. Virtually nontoxic after a single skin contact. Based on available Data, the classification criteria are not met. The product has not been tested. The statement has been derived from the properties of the individual components. Assessment other acute effects Assessment of STOT single: Causes temporary irritation of the respiratory tract. Irritation / corrosion Assessment of irritating effects: Causes skin irritation. May cause irritations to the respiratory tract. Sensitization Assessment of sensitization: May cause sensitization by skin contact. Chronic Toxicity/Effects Repeated dose toxicity Assessment of repeated dose toxicity: Repeated oral exposure may affect certain organs. The product has not been tested. The statement has been derived from the properties of the individual components. Genetic toxicity Assessment of mutagenicity: The chemical structure does not suggest a specific alert for such an effect. Based on available Data, the classification criteria are not met. Carcinogenicity Assessment of carcinogenicity: The chemical structure does not suggest a specific alert for such an effect. Based on available Data, the classification criteria are not met. Reproductive toxicity Assessment of reproduction toxicity: The chemical structure does not suggest a specific alert for such an effect. Based on available Data, the classification criteria are not met. Teratogenicity

14 MasterTop SRS 61BC Revision date : 2018/03/26 Page: 8/10 Version: 3.0 ( /SDS_GEN_CA/EN) Assessment of teratogenicity: The chemical structure does not suggest a specific alert for such an effect. Based on available Data, the classification criteria are not met. Other Information Based on our experience and the information available, no adverse health effects are expected if handled as recommended with suitable precautions for designated uses. The product has not been tested. The statements on toxicology have been derived from the properties of the individual components. Symptoms of Exposure skin irritation, allergic symptoms 12. Ecological Information Toxicity Aquatic toxicity Assessment of aquatic toxicity: Acutely harmful for aquatic organisms. The product has not been tested. The statement has been derived from the properties of the individual components. Persistence and degradability Assessment biodegradation and elimination (H2O) Inherently biodegradable. The insoluble fraction can be removed by mechanical means in suitable waste water treatment plants. Bioaccumulative potential Assessment bioaccumulation potential Discharge into the environment must be avoided. Mobility in soil Assessment transport between environmental compartments No data available. Additional information Other ecotoxicological advice: May cause long-term adverse effects in the aquatic environment. 13. Disposal considerations Waste disposal of substance: Observe national and local legal requirements. Residues should be disposed of in the same manner as the substance/product. Container disposal: Contaminated packaging should be emptied as far as possible; then it can be passed on for recycling after being thoroughly cleaned.

15 MasterTop SRS 61BC Revision date : 2018/03/26 Page: 9/10 Version: 3.0 ( /SDS_GEN_CA/EN) 14. Transport Information Land transport TDG Hazard class: 3 Packing group: II ID number: UN 1866 Hazard label: 3 Proper shipping name: RESIN SOLUTION Sea transport IMDG Hazard class: 3 Packing group: II ID number: UN 1866 Hazard label: 3 Marine pollutant: NO Proper shipping name: RESIN SOLUTION Air transport IATA/ICAO Hazard class: 3 Packing group: II ID number: UN 1866 Hazard label: 3 Proper shipping name: RESIN SOLUTION 15. Regulatory Information Federal Regulations Registration status: Chemical DSL, CA released / listed NFPA Hazard codes: Health: 2 Fire: 3 Reactivity: 2 Special: 16. Other Information SDS Prepared by: BASF NA Product Regulations SDS Prepared on: 2018/03/26 We support worldwide Responsible Care initiatives. We value the health and safety of our employees, customers, suppliers and neighbors, and the protection of the environment. Our commitment to Responsible Care is integral to conducting our business and operating our facilities in a safe and environmentally responsible fashion, supporting our customers and suppliers in ensuring the safe and environmentally sound handling of our products, and minimizing the impact of our

16 MasterTop SRS 61BC Revision date : 2018/03/26 Page: 10/10 Version: 3.0 ( /SDS_GEN_CA/EN) operations on society and the environment during production, storage, transport, use and disposal of our products. END OF DATA SHEET

17 MasterTop SRS 71TC Revision date : 2018/04/20 Page: 1/10 Version: 6.0 ( /SDS_GEN_CA/EN) 1. Identification Product identifier used on the label MasterTop SRS 71TC Recommended use of the chemical and restriction on use Recommended use*: for industrial and professional users * The Recommended use identified for this product is provided solely to comply with a Federal requirement and is not part of the seller's published specification. The terms of this (SDS) do not create or infer any warranty, express or implied, including by incorporation into or reference in the seller's sales agreement. Details of the supplier of the safety data sheet Company: BASF Canada Inc. 100 Milverton Drive Mississauga, ON L5R 4H1, CANADA Telephone: Emergency telephone number CANUTEC (reverse charges): (613) BASF HOTLINE: (800) 454-COPE (2673) Other means of identification Chemical family: No data available. 2. Hazards Identification According to Hazardous Products Regulations (HPR) (SOR/ ) Classification of the product Flam. Liq. 2 Flammable liquids Acute Tox. 4 (oral) Acute toxicity Skin Corr./Irrit. 2 Skin corrosion/irritation Skin Sens. 1B Skin sensitization STOT SE 3 (irritating to Specific target organ toxicity single exposure respiratory system) STOT RE 2 (oral) Specific target organ toxicity repeated exposure Aquatic Acute 2 Hazardous to the aquatic environment - acute

18 MasterTop SRS 71TC Revision date : 2018/04/20 Page: 2/10 Version: 6.0 ( /SDS_GEN_CA/EN) Label elements Pictogram: Signal Word: Danger Hazard Statement: H225 H315 H302 H317 H335 H373 H401 Highly flammable liquid and vapour. Causes skin irritation. Harmful if swallowed. May cause an allergic skin reaction. May cause respiratory irritation. May cause damage to organs (Kidney) through prolonged or repeated exposure (oral). Toxic to aquatic life. Precautionary Statements (Prevention): P280 Wear protective gloves and eye/face protection. P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P260 Do not breathe dust/gas/mist/vapours. P271 Use only outdoors or in a well-ventilated area. P243 Take action to prevent static discharges. P273 Avoid release to the environment. P241 Use explosion-proof electrical/ventilating/lighting/equipment. P272 Contaminated work clothing should not be allowed out of the workplace. P270 Do not eat, drink or smoke when using this product. P264 Wash with plenty of water and soap thoroughly after handling. P240 Ground and bond container and receiving equipment. P242 Use only non-sparking tools. Precautionary Statements (Response): P312 Call a POISON CENTER or doctor/physician if you feel unwell. P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. P314 Get medical advice/attention if you feel unwell. P304 + P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing. P333 + P311 If skin irritation or rash occurs: Call a POISON CENTER or doctor/physician. P330 Rinse mouth. P332 + P313 If skin irritation occurs: Get medical advice/attention. P362 + P364 Take off contaminated clothing and wash it before reuse. P370 + P378 In case of fire: Use to extinguish. Precautionary Statements (Storage): P233 Keep container tightly closed. P403 + P235 Store in a well-ventilated place. Keep cool. P405 Store locked up. Precautionary Statements (Disposal):

19 MasterTop SRS 71TC Revision date : 2018/04/20 Page: 3/10 Version: 6.0 ( /SDS_GEN_CA/EN) P501 Dispose of contents/container to hazardous or special waste collection point. Hazards not otherwise classified If applicable information is provided in this section on other hazards which do not result in classification but which may contribute to the overall hazards of the substance or mixture. 3. Composition / Information on Ingredients According to Hazardous Products Regulations (HPR) (SOR/ ) CAS Number Weight % Chemical name >= < 75.0% Methyl methacrylate >= < 10.0% 1,4-butanediol dimethacrylate >= < 10.0% 2-Butenedioic acid (Z)-, dibutyl ester >= < 5.0% 2-hydroxy-4-methoxybenzophenone >= < 5.0% 1,1'-(p-tolylimino)dipropan-2-ol 4. First-Aid Measures Description of first aid measures General advice: First aid personnel should pay attention to their own safety. Remove contaminated clothing. If inhaled: Remove the affected individual into fresh air and keep the person calm. If breathing difficulties develop, aid in breathing and seek immediate medical attention. If on skin: Wash thoroughly with soap and water. Under no circumstances should organic solvent be used. If irritation develops, seek medical attention. If in eyes: Wash affected eyes for at least 15 minutes under running water with eyelids held open, consult an eye specialist. If swallowed: Rinse mouth and then drink plenty of water. Do not induce vomiting due to aspiration hazard. Do not induce vomiting unless told to by a poison control center or doctor. Most important symptoms and effects, both acute and delayed Symptoms: The most important known symptoms and effects are described in the labelling (see section 2) and/or in section 11. Hazards: No applicable information available. Indication of any immediate medical attention and special treatment needed Note to physician Treatment: Treat according to symptoms (decontamination, vital functions), no known specific antidote.

20 MasterTop SRS 71TC Revision date : 2018/04/20 Page: 4/10 Version: 6.0 ( /SDS_GEN_CA/EN) 5. Fire-Fighting Measures Extinguishing media Suitable extinguishing media: dry powder, alcohol-resistant foam Unsuitable extinguishing media for safety reasons: water jet Special hazards arising from the substance or mixture Hazards during fire-fighting: carbon dioxide, carbon monoxide, harmful vapours, nitrogen oxides, fumes/smoke, carbon black Advice for fire-fighters Protective equipment for fire-fighting: Wear a self-contained breathing apparatus. Further information: The degree of risk is governed by the burning substance and the fire conditions. Containers may rocket or explode in heat of fire. Keep containers cool by spraying with water if exposed to fire. Collect contaminated extinguishing water separately, do not allow to reach sewage or effluent systems. Contaminated extinguishing water must be disposed of in accordance with official regulations. 6. Accidental release measures Personal precautions, protective equipment and emergency procedures Use personal protective clothing. Avoid prolonged inhalation. Avoid contact with the skin, eyes and clothing. Avoid all sources of ignition: heat, sparks, open flame. Environmental precautions Prevent spread over a wide area (e.g. by containment or oil barriers). Contain contaminated water/firefighting water. Do not discharge into drains/surface waters/groundwater. Methods and material for containment and cleaning up For large amounts: Pump off product. For residues: Pick up with inert absorbent material (e.g. sand, earth etc.). Correctly dispose of recovered product immediately. 7. Handling and Storage Precautions for safe handling Take precautionary measures against static discharges. Keep away from sources of ignition - No smoking. Provide good room ventilation even at ground level (vapours are heavier than air). Protection against fire and explosion: Sources of ignition should be kept well clear. Take precautionary measures against static discharges. Substance/product can form explosive mixture with air. Vapours are heavier than air and may accumulate in low areas and travel a considerable distance up to the source of ignition.

21 MasterTop SRS 71TC Revision date : 2018/04/20 Page: 5/10 Version: 6.0 ( /SDS_GEN_CA/EN) Conditions for safe storage, including any incompatibilities Observe VCI storage rules. Further information on storage conditions: Keep container tightly closed and in a well-ventilated place. Keep away from heat. Avoid all sources of ignition: heat, sparks, open flame. 8. Exposure Controls/Personal Protection Components with occupational exposure limits Methyl methacrylate OSHA PEL PEL 100 ppm 410 mg/m3 ; TWA value 100 ppm 410 mg/m3 ; ACGIH TLV TWA value 50 ppm ; STEL value 100 ppm ; Methyl methacrylate OSHA PEL PEL 100 ppm 410 mg/m3 ; TWA value 100 ppm 410 mg/m3 ; ACGIH TLV TWA value 50 ppm ; STEL value 100 ppm ; Advice on system design: No applicable information available. Personal protective equipment Respiratory protection: Wear a NIOSH-certified (or equivalent) organic vapour/particulate respirator. Hand protection: Wear chemical resistant protective gloves. Eye protection: Safety glasses with side-shields. Body protection: Body protection must be chosen based on level of activity and exposure., Antistatic apron General safety and hygiene measures: Avoid inhalation of dusts/mists/vapours. Avoid contact with the skin, eyes and clothing. Avoid prolonged and/or repeated contact with the skin. Handle in accordance with good building materials hygiene and safety practice. When using, do not eat, drink or smoke. Hands and/or face should be washed before breaks and at the end of the shift. At the end of the shift the skin should be cleaned and skin-care agents applied. Gloves must be inspected regularly and prior to each use. Replace if necessary (e.g. pinhole leaks). 9. Physical and Chemical Properties Form: liquid Odour: sweetish, ester-like Odour threshold: No applicable information available. Colour: light blue ph value: not applicable Freezing point: No data available. Boiling point: 101 C Sublimation point: No applicable information available. Flash point: 10 C Flammability: Highly flammable.

22 MasterTop SRS 71TC Revision date : 2018/04/20 Page: 6/10 Version: 6.0 ( /SDS_GEN_CA/EN) Lower explosion limit: 2.1 %(V) Upper explosion limit: 12.5 %(V) Autoignition: not determined Vapour pressure: approx. 40 hpa ( 20 C) Density: approx. 1.0 g/cm3 ( 20 C) Relative density: No applicable information available. Vapour density: > 1 ( 20 C) Partitioning coefficient n- No applicable information available. octanol/water (log Pow): Thermal decomposition: Vapours may form explosive mixture with air. No decomposition if stored and handled as prescribed/indicated. Viscosity, dynamic: mpa.s ( 23 C) Viscosity, kinematic: No applicable information available. Solubility in water: approx. 20 g/l ( 20 C) Miscibility with water: ( 20 C) slightly soluble Solubility (quantitative): No applicable information available. Solubility (qualitative): No applicable information available. Evaporation rate: No applicable information available. Other Information: If necessary, information on other physical and chemical parameters is indicated in this section. 10. Stability and Reactivity Reactivity No hazardous reactions if stored and handled as prescribed/indicated. Corrosion to metals: Corrosive effects to metal are not anticipated. Oxidizing properties: Based on its structural properties the product is not classified as oxidizing. Chemical stability The product is stable if stored and handled as prescribed/indicated. Possibility of hazardous reactions No hazardous reactions if stored and handled as prescribed/indicated. Conditions to avoid Avoid all sources of ignition: heat, sparks, open flame. Incompatible materials strong oxidizing agents Hazardous decomposition products Decomposition products: No hazardous decomposition products if stored and handled as prescribed/indicated. Thermal decomposition:

23 MasterTop SRS 71TC Revision date : 2018/04/20 Page: 7/10 Version: 6.0 ( /SDS_GEN_CA/EN) Vapours may form explosive mixture with air. No decomposition if stored and handled as prescribed/indicated. 11. Toxicological information Primary routes of exposure Routes of entry for solids and liquids are ingestion and inhalation, but may include eye or skin contact. Routes of entry for gases include inhalation and eye contact. Skin contact may be a route of entry for liquefied gases. Acute Toxicity/Effects Acute toxicity Assessment of acute toxicity: Virtually nontoxic by inhalation. Virtually nontoxic after a single skin contact. Harmful if swallowed. The product has not been tested. The statement has been derived from the properties of the individual components. Oral Type of value: ATE Value: 1,880 mg/kg Inhalation No applicable information available. Dermal No applicable information available. Assessment other acute effects Assessment of STOT single: Causes temporary irritation of the respiratory tract. Irritation / corrosion Assessment of irritating effects: Skin contact causes irritation. Information on: Methyl methacrylate Assessment of irritating effects: Irritating to skin. Not irritating to the eyes. Skin Information on: Methyl methacrylate Species: rabbit Result: Irritant. Method: similar to OECD guideline 404 Eye Information on: Methyl methacrylate Species: rabbit Result: non-irritant Method: Draize test Sensitization

24 MasterTop SRS 71TC Revision date : 2018/04/20 Page: 8/10 Version: 6.0 ( /SDS_GEN_CA/EN) Assessment of sensitization: Sensitization after skin contact possible. Information on: Methyl methacrylate Assessment of sensitization: Caused skin sensitization in animal studies. Chronic Toxicity/Effects Repeated dose toxicity Assessment of repeated dose toxicity: Repeated exposure may affect certain organs. Information on: Methyl methacrylate Assessment of repeated dose toxicity: After repeated exposure the prominent effect is local irritation. Genetic toxicity Assessment of mutagenicity: The chemical structure does not suggest a specific alert for such an effect. Based on available Data, the classification criteria are not met. Carcinogenicity Assessment of carcinogenicity: The chemical structure does not suggest a specific alert for such an effect. Based on available Data, the classification criteria are not met. Reproductive toxicity Assessment of reproduction toxicity: The chemical structure does not suggest a specific alert for such an effect. Based on available Data, the classification criteria are not met. Teratogenicity Assessment of teratogenicity: The chemical structure does not suggest a specific alert for such an effect. Based on available Data, the classification criteria are not met. Other Information Based on our experience and the information available, no adverse health effects are expected if handled as recommended with suitable precautions for designated uses. The product has not been tested. The statements on toxicology have been derived from the properties of the individual components. Symptoms of Exposure The most important known symptoms and effects are described in the labelling (see section 2) and/or in section Ecological Information Toxicity Aquatic toxicity Assessment of aquatic toxicity: Acutely toxic for aquatic organisms. The product has not been tested. The statement has been derived from the properties of the individual components. Persistence and degradability Assessment biodegradation and elimination (H2O)

25 MasterTop SRS 71TC Revision date : 2018/04/20 Page: 9/10 Version: 6.0 ( /SDS_GEN_CA/EN) Inherently biodegradable. The insoluble fraction can be removed by mechanical means in suitable waste water treatment plants. Bioaccumulative potential Assessment bioaccumulation potential Discharge into the environment must be avoided. Mobility in soil Assessment transport between environmental compartments No data available. Additional information Other ecotoxicological advice: Do not discharge product into the environment without control. The product has not been tested. The statements on ecotoxicology have been derived from the properties of the individual components. 13. Disposal considerations Waste disposal of substance: Observe national and local legal requirements. Residues should be disposed of in the same manner as the substance/product. Container disposal: Contaminated packaging should be emptied as far as possible; then it can be passed on for recycling after being thoroughly cleaned. 14. Transport Information Land transport TDG Hazard class: 3 Packing group: II ID number: UN 1866 Hazard label: 3 Proper shipping name: RESIN SOLUTION Sea transport IMDG Hazard class: 3 Packing group: II ID number: UN 1866 Hazard label: 3 Marine pollutant: NO Proper shipping name: RESIN SOLUTION Air transport IATA/ICAO Hazard class: 3 Packing group: II

26 MasterTop SRS 71TC Revision date : 2018/04/20 Page: 10/10 Version: 6.0 ( /SDS_GEN_CA/EN) ID number: UN 1866 Hazard label: 3 Proper shipping name: RESIN SOLUTION 15. Regulatory Information Federal Regulations Registration status: Chemical DSL, CA released / listed NFPA Hazard codes: Health: 2 Fire: 3 Reactivity: 2 Special: 16. Other Information SDS Prepared by: BASF NA Product Regulations SDS Prepared on: 2018/04/20 We support worldwide Responsible Care initiatives. We value the health and safety of our employees, customers, suppliers and neighbors, and the protection of the environment. Our commitment to Responsible Care is integral to conducting our business and operating our facilities in a safe and environmentally responsible fashion, supporting our customers and suppliers in ensuring the safe and environmentally sound handling of our products, and minimizing the impact of our operations on society and the environment during production, storage, transport, use and disposal of our products. END OF DATA SHEET