1. Identification of the substance/mixture and of the company/undertaking

Transcription

1 1. Identification of the substance/mixture and of the company/undertaking 1.1 Product identifier Trade name: Article number: MOULD & TOOL CLEANER IS Relevant identified uses of the substance or mixture and uses advised against 1.3 Details of the supplier of the safety data sheet Manufacturer/Supplier: Further information obtainable from: 1.4 Emergency telephone number: Tygris Industrial Unit 31 Kyle Road Industrial Estate Irvine Ayshire KA12 8LE Tel +44 (0) Fax +44 (0) Technical Department Tel +44 (0) Compilation Date: 17/07/2015 Page 1 of 9

2 2. Hazards identification 2.1. Classification of the substance or mixture Classification (EC 1272/2008) Physical and Chemical Hazards Flam. Aerosol 1 - H222; H229 Human health Eye Irrit. 2 - H319; STOT SE 3 - H335; H336 Asp. Tox. 1 - H304 Environment Aquatic Chronic 2 - H411 Classification (1999/45/EEC) Xi;R36. F+;R12. N;R51/53. R67. The Full Text for all R-Phrases and Hazard Statements are Displayed in Section Label elements Label In Accordance With (EC) No. 1272/2008 Signal Word Hazard Statements Precautionary Statements Danger H222 Extremely flammable aerosol. H229 Pressurised container: may burst if heated H319 Causes serious eye irritation. H335 May cause respiratory irritation H336 May cause drowsiness or dizziness. H411 Toxic to aquatic life with long lasting effects. P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. - No smoking. P211 Do not spray on an open flame or other ignition source. P251 Do not piece or burn, even after use. P261 Avoid breathing vapor/spray. P271 Use only outdoors or in a well-ventilated area. P280 Wear protective gloves, eye and face protection. P410+P412 Protect from sunlight. Do not expose to temparatures exceeding 50 C/122 F. P501 Dispose of contents/container in accordance with national regulations. P102 Keep out of reach of children Supplementary Precautionary Statements 2.3. Other hazards PRESSURISED CONTAINER - Increase in temperature to greater than 50 C will cause internal pressure to rise potentially causing bursting/explosion. Compilation Date: 17/07/2015 Page 2 of 9

3 3. Composition/information on ingredients 3.2. Mixtures 4-HYDROXY-4-METHYLPENTAN-2-ONE 30-60% Index No. REACH Registration No. CAS-No.: EC No.: Classification (EC 1272/2008) Flam. Liq. 3 - H226 Eye Irrit. 2 - H319 STOT SE 3 - H336 Classification (67/548/EEC) Xi;R36 HYDROCARBONS, C9, AROMATICS 30-60% Index No. REACH Registration No CAS-No.: - EC No.: Classification (EC 1272/2008) Classification (67/548/EEC) Flam. Liq. 3 - H226 STOT SE 3 - H335, H336 Asp.Tox. 1 - H304 Aquatic Chronic 2 - H411 BUTANE 10-30% Index No. REACH Registration No. CAS-No.: EC No.: Classification (EC 1272/2008) Flam. Gas 1 - H220 Press. Gas, Liquefied - H280 Classification (67/548/EEC) F+;R12 The Full Text for all R-Phrases and Hazard Statements are Displayed in Section 16 Compilation Date: 17/07/2015 Page 3 of 9

4 4. First aid measures 4.1. Description of first aid measures Inhalation Ingestion Skin contact Eye contact Move affected person to fresh air at once. Get medical attention immediately. Keep affected person warm and at rest. For breathing difficulties oxygen may be necessary. Rinse mouth thoroughly with water. Get medical attention. Give plenty of water to drink. Wash skin thoroughly with soap and water. Get medical attention if any discomfort continues. If liquid has entered the eyes, proceed as follows. Get medical attention if any discomfort continues. Continue to rinse for at least 15 minutes. Remove any contact lenses and open eyelids wide apart. Continue to rinse for at least 15 minutes 4.2. Most important symptoms and effects, both acute and delayed Inhalation Ingestion Skin contact Eye contact Irritation of nose, throat and airway. Vapours may cause headache, fatigue, dizziness and nausea. May cause chemical burns in mouth and throat. May cause stomach pain or vomiting. Prolonged skin contact may cause redness and irritation. Irritating to eyes. Redness. Pain Indication of any immediate medical attention and special treatment needed Notes for the doctor Treat symptomatically 5. Firefighting measures 5.1 Extinguishing Media Extinguishing media 5.2. Special hazards arising from the substance or mixture Unusual Fire & Explosion Hazards 5.3. Advice for firefighters Special Fire Fighting Procedures Use: Powder. Dry chemicals, sand, dolomite etc. Water spray, fog or mist. Aerosol cans may explode in a fire, due to excessive build up. Containers close to fire should be removed or cooled with water. Use water to keep fire exposed containers cool and disperse vapours. Compilation Date: 17/07/2015 Page 4 of 9

5 6. Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures 6.2. Environmental precautions 6.3. Methods and material for containment and cleaning up 6.4. Reference to other sections Any spillage needs to be contained and not allowed to enter water courses. Wear necessary protective equipment. Extinguish all ignition sources. Avoid sparks, flames, heat and smoking. Ventilate. Let evaporate. Keep out of confined spaces because of explosion risk. If leakage cannot be stopped, evacuate area. For personal protection, see Section 8. For waste disposal, see section Handling and storage 7.1 Precautions for safe handling Keep away from heat, sparks and open flame. Avoid spilling, skin and eye contact. Ventilate well, avoid breathing vapours. Use approved respirator if air contamination is above accepted level Conditions for safe storage, including any incompatibilities 7.3. Specific end use(s) Aerosol cans: Must not be exposed to direct sunlight or temperatures above 50 C. 8. Exposure controls/personal protection 8.1. Control parameters Name STD TWA - 8 Hrs STEL - 15 Min 4-HYDROXY-4- WEL 50 ppm 241 mg/m3 75 ppm 362 mg/m3 METHYLPENTAN-2-ONE BUTANE WEL 600 ppm 1450 mg/m3 750 ppm 1810 mg/m3 WEL = Workplace Exposure Limits 8.2. Exposure controls Protective equipment Engineering measures Respiratory equipment Hand protection Eye protection Other Protection Hygiene measures Provide adequate general and local exhaust ventilation. No specific recommendation made. Use protective gloves. Chemical splash goggles General workwear only DO NOT SMOKE IN WORK AREA! Wash hands at the end of each work shift and before eating, smoking and using the toilet. Promptly remove any clothing that becomes contaminated. When using do not eat, drink or smoke. Compilation Date: 17/07/2015 Page 5 of 9

6 9. Physical and chemical properties 9.1. Information on basic physical and chemical properties Appearance Colour Odour Flash point Flammability Limit - Upper/ Lower Auto-Ignition temperature 9.2. Other information Aerosol Colourless. Characteristic. -74 C C 10. Stability and reactivity Reactivity Chemical stability Possibility of hazardous reactions Conditions to avoid Incompatible materials Hazardous decomposition products May react with other cleaning chemicals. Stable at normal ambient temperatures. Avoid heat, flames and other sources of ignition. Do not mix or use with other products. Fire creates: Vapours/gases/fumes of: Carbon monoxide (CO). Carbon dioxide (CO2). 11. Toxicological information Information on toxicological effects Inhalation Ingestion Skin contact Eye contact Irritating to respiratory system. Vapours may cause headache, fatigue, dizziness and nausea. Prolonged inhalation of high concentrations may damage respiratory system. May cause burns in mucous membranes, throat, oesophagus and stomach. may cause stomach pains or vomiting. Prolonged or repeated exposure may cause severe irritation. Irritation of eyes and mucous membranes. Compilation Date: 17/07/2015 Page 6 of 9

7 12. Ecological information Ecotoxicity Toxicity Persistence and degradability Bioaccumulative potential Mobility in soil Results of PBT and vpvb assessment Other adverse effects Toxic to aquatic organisms. May cause long term adverse effects in the aquatic environment. Aquatic toxicity has not been carried out on this product. Data for raw materials contained in this product, when available, can be provided when necessary. The product is biodegradable The product does not contain any substances expected to be bioaccumulating. The product contains volatile organic compounds (VOCs) which will evaporate easily from all surfaces. This product does not contain any substances classified as PBT or vpvb. 13. Disposal considerations Waste treatment methods Empty containers must not be punctured or burned because of explosion hazard. Dispose of waste and residues in accordance with local authority requirements. Compilation Date: 17/07/2015 Page 7 of 9

8 14. Transport information UN number UN No. (ADR/RID/ADN) 1950 UN No. (IMDG) 1950 UN No. (ICAO) UN proper shipping name Proper Shipping Name AEROSOLS Transport hazard class(es) ADR/RID/ADN Class 2 ADR/RID/ADN Class Class 2: Gases ADR Label No. 2.1 IMDG Class 2.1 ICAO Class/Division 2.1 Transport Labels Packing group Packing group Environmental hazards Environmentally Hazardous Substance/Marine Pollutant Not applicable. No Special precautions for user EMS Tunnel Restriction Code (D) Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code Compilation Date: 17/07/2015 Page 8 of 9

9 15. Regulatory information Safety, health and environmental regulations/legislation specific for the substance or mixture Uk Regulatory References The Control of Substances Hazardous to Health Regulations The Chemicals (Hazard Information and Packaging for Supply) Regulations 2009 (S.I 2009 No. 716). Statutory Instruments Approved Code Of Practice Guidance Notes Chemical safety assessment Classification and Labelling of Substances and Preparations Dangerous for Supply. Workplace Exposure Limits EH40. Introduction to Local Exhaust Ventilation HS(G)37. CHIP for everyone HSG228 Approved Classification and Labelling Guide (Sixth edition) L Other information Risk Phrases In Full Hazard Statements In Full R10 Flammable. R66 Repeated exposure may cause skin dryness or cracking. R65 Harmful: may cause lung damage if swallowed. R38 Irritating to skin. R36/37/38 Irritating to eyes, respiratory system and skin. R20/21 Harmful by inhalation and in contact with skin. R36 Irritating to eyes. R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. R12 Extremely flammable. R67 Vapours may cause drowsiness and dizziness. R20 Harmful by inhalation. H220 Extremely flammable gas. H222 Extremely flammable aerosol. H226 Flammable liquid and vapour. H229 Pressurised container: may burst if heated H280 Contains gas under pressure; may explode if heated. H304 May be fatal if swallowed and enters airways. H319 Causes serious eye irritation. H335 May cause respiratory irritation. H336 May cause drowsiness or dizziness. H411 Toxic to aquatic life with long lasting effects. DISCLAIMER This information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process. Such information is, to the best of the company s knowledge and belief, accurate and reliable as of the date indicated. However, no warranty guarantee or representation is made to its accuracy, reliability or completeness. It is the user s responsibility to satisfy himself as to the suitability of such information for his own particular use. Compilation Date: 17/07/2015 Page 9 of 9