MARK V LAB. SECTION 1: Identification of the substance/mixture and of the company/undertaking. SECTION 2: Hazards identification

Transcription

1 GFE Date of issue: 01/01/2018 Version: 1.0 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Product form Trade name Synonyms : Mixture : GFE Epoxy Mounting Powder : Epoxy Molding Compound 1.2. Relevant identified uses of the substance or mixture and uses advised against 1.3. Details of the supplier of the safety data sheet Sumitomo Bakelite North America, Inc. 24 Mill St. Manchester, CT USA T Emergency telephone number Emergency number : CHEMTREC: SECTION 2: Hazards identification 2.1. Classification of the substance or mixture GHS-US classification Not classified 2.2. Label elements GHS-US labeling Signal word (GHS-US) Precautionary statements (GHS-US) : Warning : P202 - Do not handle until all safety precautions have been read and understood P264 - Wash hands, forearms and face thoroughly after handling P273 - Avoid release to the environment P280 - Wear protective gloves/protective clothing/eye protection/face protection P501 - Dispose of contents/container in accordance with all federal, state, and local health and environmental regulations Other hazards Other hazards not contributing to the classification : High concentration of airborne dust may form an explosive mixture with air. Ensure that good housekeeping practices are followed, as well as applicable guidelines such as National Fire Protection Association (NFPA) 654, Prevention of Fire and Dust Explosions from the Manufacturing, Processing, and Handling of Combustible Particulate Solids Unknown acute toxicity (GHS US) SECTION 3: Composition/Information on ingredients 3.1. Substances 3.2. Mixtures Name Product identifier % GHS-US classification quartz (CAS No) Carc. 1A, H350 Full text of H-phrases: see section 16

2 SECTION 4: First aid measures 4.1. Description of first aid measures First-aid measures general First-aid measures after inhalation : Never give anything by mouth to an unconscious person. If you feel unwell, seek medical advice (show the label where possible). : Call a POISON CENTER or doctor/physician if you feel unwell. Remove victim to fresh air and keep at rest in a position comfortable for breathing. Allow victim to breathe fresh air. Allow the victim to rest. 02/01/2018 EN (English US) Page 1 First-aid measures after skin contact : Wash with plenty of soap and water. Wash contaminated clothing before reuse. Remove affected clothing and wash all exposed skin area with mild soap and water, followed by warm water rinse. First-aid measures after eye contact : Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Obtain medical attention if pain, blinking or redness persist. Rinse immediately with plenty of water. First-aid measures after ingestion : Rinse mouth. Do NOT induce vomiting. Call a POISON CENTER or doctor/physician if you feel unwell. Obtain emergency medical attention Most important symptoms and effects, both acute and delayed Symptoms/injuries : Not expected to present a significant hazard under anticipated conditions of normal use Indication of any immediate medical attention and special treatment needed SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media : Foam. Dry powder. Carbon dioxide. Water spray. Sand. Unsuitable extinguishing media : Do not use a heavy water stream Special hazards arising from the substance or mixture Explosion hazard : high concentration of airborne dust may form an explosive mixture with air. Reactivity : Thermal decomposition generates : Corrosive vapors Advice for firefighters Firefighting instructions Protection during firefighting : Use water spray or fog for cooling exposed containers. Exercise caution when fighting any chemical fire. Prevent fire-fighting water from entering environment. : Do not enter fire area without proper protective equipment, including respiratory protection. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures General measures : Remove ignition sources. Use special care to avoid static electric charges. No open flames. No smoking For non-emergency personnel Emergency procedures For emergency responders Protective equipment Emergency procedures : Evacuate unnecessary personnel. : Equip cleanup crew with proper protection. : Ventilate area Environmental precautions Prevent entry to sewers and public waters. Notify authorities if liquid enters sewers or public waters Methods and material for containment and cleaning up Methods for cleaning up : On land, sweep or shovel into suitable containers. Minimize generation of dust. Store away from other materials Reference to other sections See Heading 8. Exposure controls and personal protection. SECTION 7: Handling and storage 02/01/2018 EN (English US) 2/7

3 7.1. Precautions for safe handling Additional hazards when processed Precautions for safe handling Hygiene measures : Avoid breathing fumes from molding or other processes involving heat. Avoid breathing dusts from cutting, machining or deflashing operations. Guard against dust accumulation of this material. High concentrations of airborne dust may form explosive mixture with air. As with all chemicals, good industrial hygiene practices should be followed when handling this material. : Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work. Provide good ventilation in process area to prevent formation of vapor. : Do not eat, drink or smoke when using this product. Wash contaminated clothing before reuse. Contaminated work clothing should not be allowed out of the workplace Conditions for safe storage, including any incompatibilities Technical measures : Comply with applicable regulations. Storage conditions : Keep only in the original container. Keep container closed when not in use. Keep only in the original container in a cool, well ventilated place away from : Incompatible products : Strong bases. Strong acids. Incompatible materials : Sources of ignition. Direct sunlight. Storage area : Store in cool, dry place below 40 degrees F Specific end use(s) SECTION 8: Exposure controls/personal protection 8.1. Control parameters ACGIH OSHA ACGIH ACGIH TWA (mg/m³) mg/m³ (Silica-Crystalline Quartz; USA; Timeweighted average exposure limit 8 h; TLV - Adopted Value; Respirable fraction) OSHA Remark (OSHA) (3) See Table Z Exposure controls Personal protective equipment : Avoid all unnecessary exposure. Hand protection Eye protection Skin and body protection Respiratory protection : Wear protective gloves. : Chemical goggles or safety glasses. : Wear suitable protective clothing. : Where exposure through inhalation may occur from use, respiratory protection equipment is recommended. Wear appropriate mask. : Do not eat, drink or smoke during use. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state : Solid Appearance Color : Black Colored Granules. : Black Odor : Characteristic odour Mild odour slight Odor threshold 02/01/2018 EN (English US) 3/7

4 ph Melting point Freezing point Boiling point Flash point Relative evaporation rate (butyl acetate=1) Flammability (solid, gas) Explosion limits Explosive properties Oxidizing properties Vapor pressure : Negligible at 20 degrees celsius Relative density : Relative vapor density at 20 C Specific gravity / density Solubility : g/cm³ : Negligible in water. Log Pow Log Kow Auto-ignition temperature Decomposition temperature Viscosity Viscosity, kinematic Viscosity, dynamic 9.2. SECTION 10: Stability and reactivity Reactivity Thermal decomposition generates : Corrosive vapors. 02/01/2018 EN (English US) 4/7

5 10.2. Chemical stability Stable under recommended handling and storage conditions (see section 7). Not established Possibility of hazardous reactions Not established Conditions to avoid Direct sunlight. Extremely high or low temperatures Incompatible materials Strong acids. Strong bases Hazardous decomposition products Phenol, formaldehyde, alkyl phenols and hydrocarbons of variable composition, COx, NOx, acrid vapors and fumes may be generated at elevated SECTION 11: Toxicological information Information on toxicological effects Acute toxicity : Not classified Skin corrosion/irritation : Not classified Serious eye damage/irritation : Not classified Respiratory or skin sensitization : Not classified Germ cell mutagenicity : Not classified Carcinogenicity : Not classified IARC group Based on available data, the classification criteria are not met 1 - Carcinogenic to humans Reproductive toxicity : Not classified Specific target organ toxicity single exposure : Not classified Based on available data, the classification criteria are not met Specific target organ toxicity repeated : exposure Not classified Aspiration hazard : Not classified Potential Adverse human health effects and : symptoms Based on available data, the classification criteria are not met. SECTION 12: Ecological information Toxicity Persistence and degradability Persistence and degradability Not established. Persistence and degradability Biochemical oxygen demand (BOD) Biodegradability: not applicable. 02/01/2018 EN (English US) 5/7

6 Chemical oxygen demand (COD) ThOD Bioaccumulative potential Bioaccumulative potential Mobility in soil Other adverse effects Not established. : Avoid release to the environment. SECTION 13: Disposal considerations Waste treatment methods Product/Packaging disposal recommendations Ecology - waste materials : Dispose in a safe manner in accordance with local/national regulations. : Avoid release to the environment. SECTION 14: Transport information Department of Transportation (DOT) In accordance with DOT Not regulated for transport Additional information : No supplementary information available. ADR Transport by sea Air transport SECTION 15: Regulatory information US Federal regulations Listed on the United States TSCA (Toxic Substances Control Act) inventory International regulations CANADA EU-Regulations National regulations Listed on IARC (International Agency for Research on Cancer) US State regulations SECTION 16: Indication of changes : Revision - See : *. 02/01/2018 EN (English US) 6/7

7 Full text of H350 H- phrases: : None. May cause cancer SDS US (GHS HazCom 2012 ) SBNA THE INFORMATION CONTAINED HEREIN IS BASED ON DATA CONSIDERED ACCURATE. HOWEVER, NO WARRANTY IS EXPRESSED OR IMPLIED REGARDING THE ACCURACY OF THESE DATA OR THE RESULT TO BE OBTAINED FROM THE USE THEREOF. ASSUMES NO RESPONSIBILITY FOR PERSONAL INJURY OR PROPERTY DAMAGE TO VENDEES, USERS OR THIRD PARTIES CAUSED BY THE MATERIAL. SUCH VENDEES OR USERS ASSUME ALL RISKS ASSOCIATED WITH THE USE OF THE MATERIAL. 02/01/2018 EN (English US) 7/7