MATERIAL SAFETY DATA SHEET K5-UB Component A Revised Date: 09/18/12 Page 1 of 6

Transcription

1 K5-UB Component A Revised Date: 09/18/12 Page 1 of 6 SECTION 1: PRODUCT AND COMPANY IDENTIFICATION Product Name: Component: Company: K5-UB A (SPI) th St Ct S, Ste D Lakewood, WA Phone: Toll Free: Fax: EMERGENCY CONTACT: For Spills, Leaks, Fire or Exposure call CHEMTREC Toll Free: International Calls: Fax: SECTION 2: COMPOSITION/INFORMATION ON INGREDIENTS Name CAS# % W Polyurethane Toluenediisocyanate, 2,6- Toluenediisocyanate, 2, >99 <0.09 <0.09 SECTION 3: HAZARDS IDENTIFICATION OSHA/HCS Status: This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR ). Emergency Overview: Danger! Keep away from heat and sources of ignition Mild eye irritant Mild skin irritant This product contains no listed carcinogens according to IARC, ACGIH, NTP and/or OSHA in concentrations of 0.1 percent or greater Section 3 Notes: Read the entire MSDS for a more thorough evaluation of the hazards.

2 K5-UB Component A Revised Date: 09/18/12 Page 2 of 6 SECTION 4: FIRST AID MEASURES Eye Contact: Skin Contact: Ingestion: Inhalation: Notes to Physician: Supplemental Health Information Immediately flush eyes with plenty of water for a minimum of 20 minutes, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Wash immediately with plenty of water for at least 20 minutes. Wash off with soap and water. Immediately remove, contaminated clothing, and any extraneous chemical, if possible do so without delay. Prevent aspiration of vomit. Turn victim s head to the side. Move individual to fresh air. Seek medical advice. If breathing has stopped or is labored, give assisted respirations. Supplemental oxygen may be indicated. If the heart has stopped, trained personnel should begin cardiopulmonary resuscitation immediately. Following severe exposure the patient should be kept under medical review for at least 48 hours as delayed pulmonary oedema may develop. In case of accident or if you feel unwell, seek medical attention immediately. SECTION 5: FIRE-FIGHTING MEASURES Flash Point: Suitable Extinguishing Media: Specific Hazard: Special Protective Equipment for Firefighters: Further information: Not established Alcohol resistant foam, carbon dioxide (CO 2 ), Dry chemical, sand, or limestone powder. Incomplete combustion may form carbon monoxide. Burning produces obnoxious and toxic fumes. Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode and full protective clothing (Bunker Gear). Do not allow run-off from firefighting to enter drains or water courses. SECTION 6: ACCIDENTAL RELEASE MEASURES Accidental Release Measures: For major spills call CHEMTREC Toll Free or for International call Personal Precautions: Environmental Precautions: Methods for Cleaning Up: Use self-contained breathing apparatus and chemically protective clothing. Wear suitable protective clothing, gloves, and eye/face protection. Evacuate personnel to safe areas. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. If emergency personnel are unavailable, contain spilled material. For small spills, add absorbent (soil may be used in the absence of other suitable materials), scoop up material and place in a sealable, liquid-proof container for disposal. For large spills, dike spilled material or otherwise contained material to ensure runoff does not reach a waterway. Place spilled material in an appropriate container for disposal. Additional Advice: If possible stop flow of product.

3 K5-UB Component A Revised Date: 09/18/12 Page 3 of 6 SECTION 7: HANDLING AND STORAGE General: Handling: Storage: Ideal storage temperature is F (16-32 C). Handling and storage should be in accordance with Local, State/Provincial or Federal regulations. Put on appropriate personal protective equipment (see Section 8). Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. Do not get in eyes or on skin or clothing. Do not breathe vapor or mist. Do not ingest. Use only with adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Keep in the original container or an approved alternative made from a compatible material, kept tightly closed when not in use. Empty containers retain product residue and can be hazardous. Do not reuse container. Store in accordance with local regulations. Store in original container protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10) and food and drink. Keep container tightly closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabeled containers. Use appropriate containment to avoid environmental contamination. SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION Consult local authorities for acceptable exposure limits. Preventive Measures: Engineering Controls: Personal Protection Eye Protection: Skin Protection: Respiratory Protection: Protective Clothing: Special instructions for protection and hygiene Conditions of use, adequacy of engineering or other control measures, and actual exposures will dictate the need for specific protective devices at your workplace. Use local exhaust ventilation to maintain airborne concentrations below the TVL. Suitable respiratory equipment should be used in cases of insufficient ventilation or where operational procedures demand it. For guidance on engineering control measures refer to publications such as the ACGIH current edition of Industrial Ventilation, a Manual of Recommended Practice. Full face shield with goggles underneath when molten material is being handled. Chemical safety glasses. The following protective materials are recommended: GLOVES neoprene, nitrile-butadiene rubber, butyl rubber. Thin disposable gloves should be avoided for repeated or long term use. The breakthrough time of the selected glove(s) must be greater than the intended use period. Long sleeve shirts and trousers without cuffs. When the product is sprayed or heated without adequate ventilation, an approved MSHA/NIOSH positive-pressure, supplied-air respirator may be required. Air purifying respirators equipped with organic vapor cartridges and a HEPA (P100) particulate filter may be used under certain conditions when a cartridge change-out schedule has been developed in accordance with the OSHA respiratory protection standard (29 CFR ). Protective clothing should be selected and used in accordance with Guidelines for the Selection of Chemical Protective Clothing published by ACGIH. Provide readily accessible eye wash stations and safety showers. Wash at the end of each work shift and before eating, smoking, or using the toilet.

4 K5-UB Component A Revised Date: 09/18/12 Page 4 of 6 SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES General Appearance Information Physical State: Viscous Color: Light Yellow Important Health, Safety and Environmental Information Boiling Point: N/A ph: Neutral Flash Point: 320 F (160 C) Solubility (in water): Reacts violently with water Relative Density: 1.15 (water = 1). Density: lb/gt3 (1.15 g/cm3) at 70 F (21 C) Vapor Pressure <0.07 mmhg at 21 C Viscosity: 6,000 mpa.s at 104 F (40 C) Viscosity: 6,00 mpa.s at 158 F (70 C) SECTION 10: STABILITY AND REACTIVITY Stability and Reactivity: Incompatibility (Materials to Avoid): Hazardous decomposition products: Stable under normal conditions. Oxidizing agents and alcohols. Preparation reacts slowly with water resulting in evolution of CO 2. Reaction with water or contaminants or excessive heat may result in sufficient pressure to burst container. Carbon monoxide, carbon dioxide (CO 2 ), isocyanates, carbanates, cyanic acids, cyanogen, nitrile, and toxic cyanates. SECTION 11: TOXICOLOGICAL INFORMATION Acute Health Hazard Ingestion: Ingestion components toluenedissocyanate, 2, 4- Eye irritation/corrosion Acute dermal irritation/corrosion: No data available LD50: 5,800 mg/kg Mild eye irritation Mild skin irritation SECTION 12: ECOLOGICAL INFORMATION Ecotoxicity effects Aquatic toxicity: Toxicity to other organisms: Persistence and degradability Mobility: Bioaccumulation: No data available No data available No data available No data available

5 K5-UB Component A Revised Date: 09/18/12 Page 5 of 6 SECTION 13: DISPOSAL CONSIDERATIONS Waste from residues/unused products: The generation of waste should be avoided or minimized wherever possible. Avoid dispersal of spilled material into soil, waterways, drains, and sewers. Disposal of this product and any waste by-products must be handled in accordance with federal, state, and local environmental control regulations. Empty containers must be either given to an approved/certified drum recycler or disposal service, ordecontaminated using approved methods described/mandated by regional/local waste disposal authority requirements. SECTION 14: TRANSPORTATION INFORMATION EMERGENCY CONTACT: For Spills, Leaks, Fire or Exposure call CHEMTREC Toll Free: International Calls: CFR IATA IMDG CTC Further information: Not regulated Not regulated Not regulated Not regulated Not dangerous goods SECTION 15: REGULATORY INFORMATION COUNTRY REGULATORY LIST NOTIFICATION USA TSCA Included on Inventory EU EINECS Included on EINECS inventory or polymer substance, monomers included on EINECS inventory or no longer polymer. Canada DSL Included in Inventory Australia AICS Not on Inventory Japan ENCS Not on Inventory South Korea ECL Included on Inventory China SEPA Included on Inventory Philippines PICCA Included on Inventory EPA SARA Title III Section 312 (40 CFR 370) No SARA Hazards Hazard Classification: EPA DARA Title III Section 313 (40 CFR 372) None Component(s) above in de minimus level: US California Safe Drinking Water & Toxic Enforcement Act (Proposition 65) WHMIS Hazard Classification: WARNING! This product contains a chemical known in the State of California to cause cancer. Toluenediisocyanate, 2,4- Toluenediisocyanate, 2,6- Not Rated

6 K5-UB Component A Revised Date: 09/18/12 Page 6 of 6 This product has been classified according to the hazard criteria of the CPR and the MSDS contains all the information required by the CPR. SECTION 16: OTHER INFORMATION Label Requirements: DANGER! IRRITATING TO EYES AND SKIN. HARMFUL IF SWALLOWED. CAUSES RESPIRATORY TRACT IRRITATION. HAZARDOUS MATERIAL INFORMATION SYSTEM (U.S.A.) NATIONAL FIRE PROTECTION ASSOCIATION (U.S.A.) Fire Hazard Health 1 Fire Hazard 1 1 Reactivity 1 Health 1 1 Instability For Your Protection: Preparation Information: The information and recommendations in this publication is to the best of our knowledge, reliable. The toxicity and risk characteristics of products made by SPI will necessarily differ from the toxicity and risk characteristics that occur when such products are used with other materials during a manufacturing process. The resulting risk characteristics should be determined and made known to ultimate end-users and processors. The user is responsible to comply with all applicable federal, provincial or municipal laws and regulations. SPI MAKES NO WARRANTIES OF ANY KIND, EXPRESSED OR IMPLIED, INCLUDING THOSE OF MERCHANTABILITY AND FITNESS FOR A PARTICULAR PURPOSE. This MSDS supersedes ALL previous MSDS versions.

7 Page 1 of 8 SECTION 1: PRODUCT AND COMPANY IDENTIFICATION Product Name: Component: Company: K5-UB B (SPI) th St Ct S, Ste D Lakewood, WA Phone: Toll Free: Fax: EMERGENCY CONTACT: For Spills, Leaks, Fire or Exposure call CHEMTREC Toll Free: International Calls: Fax: SECTION 2: COMPOSITION/INFORMATION ON INGREDIENTS Name CAS# % W Polyoxypropylenediamine Chemical Identity is Proprietary Chemical Identity is Proprietary N/A N/A SECTION 3: HAZARDS IDENTIFICATION OSHA/HCS Status: Emergency Overview: This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR ). Danger! CAUSES EYE AND SKIN BURNS. HARMFUL IF SWALLOWED. CAUSES RESPIRATORY TRACT IRRITATION. Toxic if swallowed. Corrosive to eyes and skin. Causes burns. Irritating to respiratory system. Do not breathe vapor or mist. Do not ingest. Do not get in eyes or on skin or clothing. Use only with adequate ventilation. Keep container tightly closed and sealed until ready for use. Wash thoroughly after handling. Section 3 Notes: Read the entire MSDS for a more thorough evaluation of the hazards.

8 Page 2 of 8 SECTION 4: FIRST AID MEASURES Eye Contact: Skin Contact: Ingestion: Inhalation: Notes to Physician: Get medical attention immediately. Immediately flush eyes with plenty of water for a minimum of 15 minutes, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Chemical burns must be treated promptly by a physician. Continue flushing for an additional 15 minutes if medical attention is not immediately available. Get medical attention immediately. Flush contaminated skin with plenty of water. Continue to rinse skin with large amounts of running water for at least 10 minutes. Remove contaminated clothing and shoes. Chemical burns must be treated promptly by a physician. Wash clothing before reuse. Clean shoes thoroughly before reuse. Get medical attention immediately. Wash out mouth with water. Move exposed person to fresh air. Do not induce vomiting unless directed to do so by medical personnel. Chemical burns must be treated promptly by a physician. Never give anything by mouth to an unconscious person. Get medical attention immediately. Move exposed person to fresh air. If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. Keep person warm and at rest. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband. Symptomatic treatment and supportive therapy as indicated. Administer oxygen if necessary. Following severe exposure the patient should be kept under medical review for at least 48 hours as delayed pulmonary edema may develop. SECTION 5: FIRE-FIGHTING MEASURES Flash Point: Extinguishing Media: Suitable: Not Suitable: Special Exposure Hazards: Special Protective Equipment for Firefighters: Closed cup: >365 F (185 C). Use an extinguishing agent suitable for the surrounding fire. None known. No Specific Hazard. Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode.

9 Page 3 of 8 SECTION 6: ACCIDENTAL RELEASE MEASURES Accidental Release Measures: Personal Precautions: Environmental Precautions: Methods for Cleaning Up: For major spills call CHEMTREC Toll Free or for International call Immediately contact emergency personnel. Keep unnecessary personnel away. Use suitable protective equipment. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains, and sewers. If emergency personnel are unavailable, contain spilled material. For small spills, add absorbent (soil may be used in the absence of other suitable materials), scoop up material and place in a sealable, liquid-proof container for disposal. For large spills, dike spilled material or otherwise contained material to ensure runoff does not reach a waterway. Place spilled material in an appropriate container for disposal. SECTION 7: HANDLING AND STORAGE General: Handling: Storage: Ideal storage temperature is F (15-32 C). Handling and storage should be in accordance with Local, State/Provincial or Federal regulations. Put on appropriate personal protective equipment (see Section 8). Eating, drinking, and smoking should be prohibited in areas where this material is handled, stored, and processed. Workers should wash hands and face before eating, drinking, and smoking. Do not get in eyes or on skin or clothing. Do not breathe vapor or mist. Do not ingest. Use only with adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Keep in the original container or an approved alternative made from a compatible material, kept tightly closed when not in use. Empty containers retain product residue and can be hazardous. Do not reuse container. Store in accordance with local regulations. Store in original container protected from direct sunlight in a dry, cool, and well-ventilated area, away from incompatible materials (see Section 10), food, and drink. Keep container tightly closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabeled containers. Use appropriate containment to avoid environmental contamination.

10 Page 4 of 8 SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION Consult local authorities for acceptable exposure limits. Preventive Measures: Engineering Controls: Personal Protection Eye Protection: Skin Protection: Respiratory Protection: Hands: Work Hygienic Practices: Conditions of use, adequacy of engineering or other control measures, and actual exposures will dictate the need for specific protective devices at your workplace. Use local exhaust ventilation to maintain airborne concentrations below the TVL. Suitable respiratory equipment should be used in cases of insufficient ventilation or where operational procedures demand it. For guidance on engineering control measures refer to publications such as the ACGIH current edition of Industrial Ventilation, a Manual of Recommended Practice. Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists, or dusts. Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. Use a properly fitted, air-purifying, or air-fed respirator complying with an approved standard if a risk assessment indicates this is necessary. Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator. Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. Follow the usual precautionary measures for handling chemicals. Keep away from food and beverages. Immediately remove all soiled and contaminated clothing. Avoid contact with eyes, skin, and clothing. Wash hands after use. Wash all contaminated clothing and shoes before reuse. SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES General Appearance Information Physical State: Liquid Color: Various colors Odor: Amine odor Odor Threshold: Not available Important Health, Safety and Environmental Information

11 Page 5 of 8 ph: 10.5 Boiling Point: Not available Melting Point: Not available Flash Point: Closed Cup: >365 F (185 C) Oxidizing Properties: Not available Relative Density: 0.99 Solubility: Slightly soluble in water. Very slightly soluble in methanol. Viscosity: Kinematic: 2.48 cm 2 /s (248 cst at 25 C) Vapor Density: Not available Volatile Organic Compounds (VOC): 0 grams/liter SECTION 10: STABILITY AND REACTIVITY Stability and Reactivity: Incompatibility (Materials to Avoid): Hazardous Polymerization: The product is stable. Will react with acids. Not available. SECTION 11: TOXICOLOGICAL INFORMATION Toxicity Data Polyoxypropylenediamine Potential Acute Health Effects Ingestion: Inhalation: Eyes: Skin: Potential Chronic Health Effects Target Organs: Carcinogenicity: Mutagenicity: Teratogenicity: Developmental Effects: Fertility Effects: Test Result Route Species LD mg/kg Dermal Rabbit LD mg/kg Oral Rat Toxic if swallowed. May cause burns to mouth, throat, and stomach. Irritating to respiratory system. Corrosive to eyes. Causes burns. Corrosive to the skin. Causes burns. None known. No known significant effects or critical hazards. No known significant effects or critical hazards. No known significant effects or critical hazards. No known significant effects or critical hazards No known significant effects or critical hazards.

12 Page 6 of 8 SECTION 12: ECOLOGICAL INFORMATION NO DATA AVAILABLE SECTION 13: DISPOSAL CONSIDERATIONS Waste Disposal Method: The generation of waste should be avoided or minimized wherever possible. Avoid dispersal of spilled material into soil, waterways, drains, and sewers. Disposal of this product and any waste by-products must be handled in accordance with federal, state, and local environmental control regulations. Empty containers must be either given to an approved/certified drum recycler or disposal service, ordecontaminated using approved methods described/mandated by regional/local waste disposal authority requirements. SECTION 14: TRANSPORTATION INFORMATION EMERGENCY CONTACT: For Spills, Leaks, Fire or Exposure call CHEMTREC Toll Free: International Calls: DOT Classification Proper Shipping Name: Amines, liquid, Corrosive, N.O.S., (Polyoxypropylenediamine) Hazard Class: 8 UN Number: UN2735 Packing Group: III TDG Classification Proper Shipping Name: Hazard Class: UN Number: Packing Group: IMDG Class Proper Shipping Name: Hazard Class: UN Number: Packing Group: IATA-DGR Class Proper Shipping Name: Hazard Class: UN Number: Packing Group: Amines, liquid, Corrosive, N.O.S., (Polyoxypropylenediamine) 8 UN2735 III Amines, liquid, Corrosive, N.O.S., (Polyoxypropylenediamine) 8 UN2735 III Amines, liquid, Corrosive, N.O.S., (Polyoxypropylenediamine) 8 UN2735 III

13 Page 7 of 8 SECTION 15: REGULATORY INFORMATION United States HCS Classification: US Federal Regulations: CERCLA: Hazardous Substances SARA 313 California Prop 65 Toxic Material Corrosive Material United States Inventory (TSCA 8b): All components are listed or exempted. No ingredients listed. No ingredients listed. This product does not contain nor is it manufactured with ozone depleting substances. No ingredients listed. Canada WHMIS: CEPA: Class D-1B: Material causing immediate and serious toxic effects (toxic). Class E: Corrosive material. Canada Inventory: All components are listed or exempted. This product has been classified according to the hazard criteria of the CPR and the MSDS contains all the information required by the CPR. SECTION 16: OTHER INFORMATION Label Requirements: CAUSES EYE AND SKIN BURNS. HARMFUL IF SWALLOWED. CAUSES RESPIRATORY TRACT IRRITATION. HAZARDOUS MATERIAL INFORMATION SYSTEM (U.S.A.) NATIONAL FIRE PROTECTION ASSOCIATION (U.S.A.) Fire Hazard Health 3 Fire Hazard 1 1 Reactivity 0 Health 3 0 Instability For Your Protection: The information and recommendations in this publication is to the best of our knowledge, reliable. The toxicity and risk characteristics of products made by SPI will necessarily differ from the toxicity and risk characteristics that occur when such products are used with other materials during a manufacturing process. The resulting risk characteristics should be determined and made known to ultimate end-users and processors. The user is responsible to

14 Page 8 of 8 comply with all applicable federal, provincial or municipal laws and regulations. SPI MAKES NO WARRANTIES OF ANY KIND, EXPRESSED OR IMPLIED, INCLUDING THOSE OF MERCHANTABILITY AND FITNESS FOR A PARTICULAR PURPOSE. Preparation Information: This MSDS supersedes ALL previous MSDS versions.