Material Safety Data Sheet

Transcription

1 SECTION 1. PRODUCT AND COMPANY IDENTIFICATION Product name: Company: Chemtura Corporation 199 Benson Road Middlebury, CT United States of America Telephone: Emergency telephone number: CHEMTREC: (24 hours) : Chemtura Corporation Emergency Response: CHEMTURA : For additional emergency telephone numbers see section 16 of the Safety Data Sheet. Prepared by: 07/27/2011 Product Safety Department (US) MSDSRequest@chemtura.com SECTION 2. HAZARDS IDENTIFICATION Emergency Overview WARNING! Form: liquid Colour: clear Odour: characteristic Hazard Summary OSHA Hazards : : Irritating to eyes, respiratory system and skin. Also harmful by inhalation. May cause sensitization by inhalation and skin contact. SENSITISER IRRITANT Carcinogenicity: IARC No component of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC. SAP / 8 SDS Number:

2 OSHA NTP ACGIH No component of this product present at levels greater than or equal to 0.1% is identified as a carcinogen or potential carcinogen by OSHA. No component of this product present at levels greater than or equal to 0.1% is identified as a known or anticipated carcinogen by NTP. No component of this product present at levels greater than or equal to 0.1% is identified as a carcinogen or potential carcinogen by ACGIH. SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS Hazardous components Component / CAS-No. 3-isocyanatomethyl-3,5,5-trimethylcyclohexyl isocyanate Weight percent 1.8 >= 1 - < 5 % SECTION 4. FIRST AID MEASURES First aid procedures Inhalation Skin contact Eye contact Ingestion : Move to fresh air. Give oxygen or artificial respiration if needed. Call a physician or poison control centre immediately. : Take off contaminated clothing and shoes immediately. Wash off immediately with plenty of water for at least 15 minutes. If symptoms persist, call a physician. : In case of eye contact, remove contact lens and rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Get medical attention immediately. : If swallowed, DO NOT induce vomiting unless directed to do so by medical personnel. If accidentally swallowed obtain immediate medical attention. If a person vomits when lying on his back, place him in the recovery position. SECTION 5. FIRE-FIGHTING MEASURES Flammable properties Flash point : > 212 F (> 100 C) Method: closed cup Fire fighting Suitable extinguishing media : Foam Carbon dioxide (CO2) Dry chemical Extinguishing media - large fires Water spray Water mist SAP / 8 SDS Number:

3 Protective equipment and precautions for firefighters Specific hazards during fire fighting : Burning produces noxious and toxic fumes. Exposure to decomposition products may be a hazard to health. Do not allow run-off from fire fighting to enter drains or water courses. Special protective equipment for fire-fighters : Wear full protective clothing and self-contained breathing apparatus. Wear suitable protective clothing, gloves and eye/face protection. SECTION 6. ACCIDENTAL RELEASE MEASURES Personal precautions Environmental precautions Methods for containment / Methods for cleaning up : Ensure adequate ventilation. Use personal protective equipment. Keep people away from and upwind of spill/leak. : Avoid release to the environment. : Wear suitable protective clothing, gloves and eye/face protection. Wear respiratory protection. Prevent further leakage or spillage if safe to do so. Contain spillage, soak up with non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite) and transfer to a container for disposal according to local / national regulations (see section 13). Keep in suitable, closed containers for disposal. SECTION 7. HANDLING AND STORAGE Handling Handling procedures : Use only in area provided with appropriate exhaust ventilation. Wear personal protective equipment. Do not breathe vapours/dust. Do not get in eyes or mouth or on skin. Protect from moisture. Keep away from water. Keep container tightly closed. Do not handle until all safety precautions have been read and understood. Wash thoroughly after handling. Storage Requirements for storage areas and containers : Keep containers tightly closed in a dry, cool and well-ventilated place. Protect from moisture. Isocyanate based products react with water liberating carbon dioxide, which can lead to excessive pressure in closed containers, and form solid insoluble polymers, which can block pipes, valves, etc. Contact with copper or copper alloys and galvanized surfaces must be avoided and valves etc made of these materials must not be used in equipment for storing and handling diisocyanates. Do not store in open containers. Store in original containers away from incompatible materials. SAP / 8 SDS Number:

4 SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Exposure Guidelines Components with workplace control parameters Components / CAS-No. Value / Basis / Update 3-isocyanatomethyl-3,5,5-trimethylcyclohexyl TWA isocyanate ACGIH TWA OSHA P STEL OSHA P Control parameters ppm ppm 0.02 ppm Further information Engineering measures Personal protective equipment Eye protection : Face-shield Safety glasses with side-shields Do not wear contact lenses. Hand protection : Impervious gloves Skin and body protection Respiratory protection : impervious clothing : When workers are facing concentrations above the exposure limit they must use appropriate certified respirators. SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance Form Colour Odour : liquid : clear : characteristic Safety data Flash point : > 212 F (> 100 C) SAP / 8 SDS Number:

5 Method: closed cup Density Water solubility Solubility in other solvents : g/cm3 at 68 F (20 C) : Note: immiscible : Medium: Organic solvents Note: soluble SECTION 10. STABILITY AND REACTIVITY Conditions to avoid Materials to avoid Hazardous decomposition products : Remarks: Exposure to moisture. : Remarks: Alcohols Water : Note: nitrogen oxides (NOx) Carbon oxides Hydrogen cyanide Other hazardous decomposition products may be formed. SECTION 11. TOXICOLOGICAL INFORMATION Further information : Symptoms may be delayed. Persons allergic to isocyanates, and particularly those suffering from asthma or other respiratory conditions, should not work with isocyanates. May cause irritation of respiratory tract. The product itself has not been tested. 12. ECOLOGICAL INFORMATION Further information on ecology Additional ecological : There is no data available for this product. information SECTION 13. DISPOSAL CONSIDERATIONS Further information : In accordance with local and national regulations. SECTION 14. TRANSPORT INFORMATION DOT TDG SAP / 8 SDS Number:

6 IATA IMDG RID SECTION 15. REGULATORY INFORMATION OSHA Hazards CERCLA Reportable Quantity SARA 311/312 Hazards : Sensitiser, Irritant : : Acute Health Hazard Chronic Health Hazard EPCRA - EMERGENCY PLANNING COMMUNITY RIGHT - TO - KNOW SARA 302 Reportable : Quantity 3-isocyanatomethyl-3,5,5-trimethylcyclohexyl 500 lbs isocyanate SARA 304 Components : This material does not contain any components with a section 304 EHS RQ. SARA 313 Components : 3-isocyanatomethyl-3,5,5-trimethylcyclohexyl isocyanate Massachusetts Right To Know Components : 3-isocyanatomethyl-3,5,5-trimethylcyclohexyl isocyanate OSHA a. United states occupational safety and health administration substances, 29 cfr , sub part z.acgih American conference of governmental industrial hygienists threshold limit value (TLV) substancesepa extremely hazardous substances. 29 cfr parts 300 and 355. Federal register 52 fr (4/22/87). Amended in 52 fr (12/17/87) and 53 fr 5547 (2/25/88). These substances are subject to the superfund amendment and reauthorization act (SARA) title III.CERCLA hazardous substances. 40 cfr part 302. May be subject to emergency release notification under SARA Title III.Toxic chemical release substances. 52 fr (6/4/87). Subject to SARA Title III. Pennsylvania Right To Know Components : Polymer in Trixene SC SAP / 8 SDS Number:

7 3-isocyanatomethyl-3,5,5-trimethylcyclohexyl isocyanate OSHA a. United states occupational safety and health administration substances, 29 cfr , sub part z. ACGIH American conference of governmental industrial hygienists threshold limit value (TLV) substances EPA extremely hazardous substances. 29 cfr parts 300 and 355. Federal register 52 fr (4/22/87). Amended in 52 fr (12/17/87) and 53 fr 5547 (2/25/88). These substances are subject to the superfund amendment and reauthorization act (SARA) title III. CERCLA hazardous substances. 40 cfr part 302. May be subject to emergency release notification under SARA Title III. Toxic chemical release substances. 52 fr (6/4/87). Subject to SARA Title III. New Jersey Right To Know Components : Polymer in Trixene SC isocyanatomethyl-3,5,5-trimethylcyclohexyl isocyanate OSHA a. United states occupational safety and health administration substances, 29 cfr , sub part z. ACGIH American conference of governmental industrial hygienists threshold limit value (TLV) substances EPA extremely hazardous substances. 29 cfr parts 300 and 355. Federal register 52 fr (4/22/87). Amended in 52 fr (12/17/87) and 53 fr 5547 (2/25/88). These substances are subject to the superfund amendment and reauthorization act (SARA) title III. CERCLA hazardous substances. 40 cfr part 302. May be subject to emergency release notification under SARA Title III. Toxic chemical release substances. 52 fr (6/4/87). Subject to SARA Title III. California Prop. 65 Components : This product does not contain any chemicals known to State of California to cause cancer, birth defects, or any other reproductive harm. The components of this product are reported in the following inventories: US.TSCA On TSCA Inventory DSL AICS NZIoC ENCS All components of this product are on the Canadian DSL list. Not in compliance with the inventory KECI SAP / 8 SDS Number:

8 PICCS IECSC SECTION 16. OTHER INFORMATION Further information HMIS Classification : Health hazard: 2 Flammability: 1 Physical hazards: 0 NFPA Classification 1 : Health hazard: 2 Fire Hazard: 1 Reactivity Hazard: Other Emergency Phone Number Latin America: Brazil All other countries +44 (0) Mexico: The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. SAP / 8 SDS Number: