Safety Data Sheet in Accordance with regulation 2015/830 Page 1 of 7
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1 Safety Data Sheet in Accordance with regulation 2015/830 Page 1 of 7 Date of issue: Replaces Data Sheet of: --- "*" alterations as compared to previous version; n.ap. = not applicable; = not available SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1 Product identifier Trade Name: CLASSIC AIR FILTER OIL SPRAY Article No.: Preparation No.: Registration No.: n.ap. 1.2 Relevant identified uses of the substance or mixture and uses advised against Identified uses: lubricant 1.3 Details of the supplier of the safety data sheet Address of the Company / Supplier: CLASSIC Schmierstoff GmbH & Co. KG, Lange Straße , D Hoya Telephone: , Telefax: , schmierstoffe@classic-oil.de Responsible for the data sheet: CoSiChem AG, Ernst-Lemmer-Straße 23, D Marburg, info@cosichem.de 1.4 Emergency telephone number Emergency - Telephone of Company / Undertaking Information Centre Specialising in Symptoms of Poisoning Telephone: (8:30 16:30) Telephone: SECTION 2: Hazards identification 2.1 Classification of the substance or mixture Aerosol 1; H222 H229 / Asp. Tox. 1; H304 / Skin Irrit. 2; H315 / STOT SE 3; H336 / Aquatic Chronic 2; H Label elements Classification according to 1272/2008/EC: Yes. Applicable Exemptions: No. Signal word(s): Danger Component(s): contains: Hydrocarbons, C6-7 Hydrocarbons, C9-C10, n-alkanes, isoalkanes, cyclics, <2% aromatics Hazard pictogram(s): H - Phrases: H222: Extremely flammable aerosol. H229: Pressurised container: May burst if heated. H304: May be fatal if swallowed and enters airways. H315: Causes skin irritation. H336: May cause drowsiness or dizziness. H411: Toxic to aquatic life with long lasting effects. P - Phrases: P102: Keep out of reach of children. P210: Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P211: Do not spray on an open flame or other ignition source. P251: Do not pierce or burn, even after use. P410+P412: Protect from sunlight. Do no expose to temperatures exceeding 50 C/122 F. P260: Do not breathe spray. P273: Avoid release to the environment. P280: Wear protective gloves/protective clothing/eye protection/face protection. P301+P310: IF SWALLOWED: Immediately call a POISON CENTER/ doctor. P331: Do NOT induce vomiting. P304+P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. P312: Call a POISON CENTER/doctor if you feel unwell. P501: Dispose of contents/container to special waste collection point. Additional Markings: In use, may form flammable/explosive vapour-air mixture. The above mentioned labelling is valid for distribution to private consumer. 2.3 Other hazards Solvents may degrease the skin. This mixture contains no substances which are assessed to be PBT or vpvb.
2 Safety Data Sheet in Accordance with regulation 2015/830 Page 2 of 7 SECTION 3: Composition/information on ingredients 3.1 Substances n. ap. 3.2 Mixtures Chemical Characterisation: Mixture aerosol Ingredients: Material H - phrases m% - CAS - No. EC - No. REACH - No. range Hydrocarbons, C n. av. Hydrocarbons, C9-C10, n-alkanes, isoalkanes, cyclics, <2% aromatics n. av. n-hexane xxxx Text of H - phrases: see section 16 Flam. Liq. 2; H225 Skin Irrit. 2; H315 Asp. Tox. 1; H304 STOT SE 3; H336 Aquatic Chronic 2; H411 Flam. Liq. 3; H226 Asp. Tox. 1; H304 STOT SE 3; H336 Aquatic Chronic 3; H412 Flam. Liq. 2; H225 Repr. 2; H361f Asp. Tox. 1; H304 STOT RE 2; H373 Skin Irrit. 2; H315 STOT SE 3; H336 Aquatic Chronic 2; H % 5-10% 0.1-1% SECTION 4: First aid measures 4.1 Description of first aid measures Inhalation: Move to fresh air in case of accidental inhalation of vapours or decomposition products. If symptoms persist, call a physician Skin Contact: Wash off with warm water and soap. Take off all contaminated clothing immediately. If skin irritation persists, call a physician Eye Contact: In case of eye contact, remove contact lens and rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. If symptoms persist, call a physician Ingestion: Call a physician immediately. Do not induce vomiting. Clean mouth with water and afterwards drink plenty of water. 4.2 Most important symptoms and effects, both acute and delayed Ingestion may cause gastrointestinal irritation, nausea, vomiting and diarrhoea. Risk of product entering the lungs on vomiting after ingestion. Just a sip may lead to life threatening lung damage. 4.3 Indication of any immediate medical attention and special treatment needed Treat symptomatically. Risk of product entering the lungs on vomiting after ingestion. Just a sip may lead to life threatening lung damage. Later control for pneumonia and lung oedema.
3 Safety Data Sheet in Accordance with regulation 2015/830 Page 3 of 7 SECTION 5: Firefighting measures 5.1 Extinguishing media Suitable Extinguishing Media: Use dry chemical, CO 2, water spray or "alcohol" foam Extinguishing Media to Avoid: High volume water jet. 5.2 Special hazards arising from the substance or mixture In the event of fire the following can be released: Hazardous decomposition products due to incomplete combustion, carbon oxides. 5.3 Advice for firefighters Special Protective Equipment: Wear positive pressure self-contained breathing apparatus. Wear full protective clothing Additional Information: Fire residues and contaminated fire extinguishing water must be disposed of in accordance with local regulations. Use water spray to cool unopened containers. SECTION 6: Accidental release measures 6.1 Personal precautions, protective equipment and emergency procedures See chapter Contaminated surfaces will be extremely slippery. 6.2 Environmental precautions Do not flush into surface water or sanitary sewer system. Do not allow material to contaminate ground water system. Local authorities should be advised if significant spillages cannot be contained. 6.3 Methods and material for containment and cleaning up Prevent spreading over a wide area (e.g. by containment or oil barriers). Soak up with oil absorbent material. Keep in suitable, closed containers for disposal. 6.4 Reference to other sections SECTION 7: Handling and storage 7.1 Precautions for safe handling Precautions for Safe Handling: Avoid contact with skin and eyes. Remove and wash contaminated clothing before re-use. When using, do not eat, drink or smoke. Wash hands before breaks and at the end of workday. Do not breathe vapours or spray mist Precautions in Case of Fire and Explosion: Keep away from sources of ignition - No smoking. Keep away from fire, sparks and heated surfaces. Take measures to prevent the build up of electrostatic charge. 7.2 Conditions for safe storage, including any incompatibilities Storage Instructions: Keep containers tightly closed in a dry, cool and well-ventilated place. Store in original container. Keep at temperatures between 5 and 40 C. Protect from frost, heat and sunlight Store away from: Incompatible with oxidizing agents Further Information on Storage Conditions: Pressurized container. Protect from sunlight and do not expose to temperatures exceeding 50 C. 7.3 Specific end use(s)
4 Safety Data Sheet in Accordance with regulation 2015/830 Page 4 of 7 SECTION 8: Exposure controls/personal protection 8.1 Control parameters Material Limit Value n-hexane 8.2 Exposure controls Appropriate engineering controls Provide appropriate exhaust ventilation at machinery. 50 ppm 180 mg/m³, TWA: 20 ppm 72 mg/m³ Individual protection measures 8.2.2a Respiratory Protection: In case of insufficient ventilation, wear suitable respiratory equipment. Recommended filter type: A 8.2.2b Hand Protection: Use protective skin cream before handling the product. Protective gloves complying with EN 374. nitrile rubber (0,4 mm) break through time > 8 h The data about break through time/strength of material are standard values! The exact break through time/strength of material has to be obtained from the producer of the protective glove. Please observe the instructions regarding permeability and breakthrough time which are provided by the supplier of the gloves. Also take into consideration the specific local conditions under which the product is used, such as the danger of cuts, abrasion, and the contact time c Eye Protection: In case of contact through splashing: safety glasses 8.2.2d Skin Protection: Long sleeved clothing 8.2.2e Further Information: Observe wearing time limits: Environmental exposure controls: Do not allow material to contaminate ground water system. Do not flush into surface water or sanitary sewer system. SECTION 9: Physical and chemical properties 9.1 Information on basic physical and chemical properties Form: aerosol Colour: red Odour: characteristic ph-value, undiluted: n.ap. ph-value, 1% aqueous solution: Boiling point / Boiling - range ( C): Melting point / Melting range ( C): Flash point ( C): -12, closed cup Flammability (EEC A10/A13): Ignition temperature ( C): Autoflammability (EEC A16): Oxidising properties: Explosion hazard: Explosion limits (Vol.%) lower:, upper: Vapour pressure: Vapour density (Air = 1): Density (g/ml): 0,801 (20 C) Solubility (in Water): immiscible Partition coefficient, n-octanol / Water: Viscosity: < 20,5 mm² / s Solvent content (m %): Not relevant Thermal decomposition ( C): Evaporation rate: 9.2 Other information Odour threshold:
5 Safety Data Sheet in Accordance with regulation 2015/830 Page 5 of 7 SECTION 10: Stability and reactivity 10.1 Reactivity 10.2 Chemical stability Stable under normal conditions Possibility of hazardous reactions In use, may form flammable/explosive vapour-air mixture Conditions to avoid Heat, flames and sparks. Extremes of temperature and direct sunlight Incompatible materials Incompatible with oxidizing agents Hazardous decomposition products No decomposition if stored and applied as directed. To avoid thermal decomposition, do not overheat. SECTION 11: Toxicological information 11.1 Information on toxicological effects Acute Health Effects: Inhalation: Ingestion: Skin Contact: Skin corrosion / irritation: Serious eye damage / irritation: Respiratory or skin sensitisation: Germ cell mutagenicity: Carcinogenicity: Reproductive toxicity: STOT-single exposure: STOT-repeated exposure: Aspiration hazard: Causes skin irritation. May cause eye irritation with susceptible persons. May cause drowsiness or dizziness. n. av. May be fatal if swallowed and enters airways Practical Experience Practical Experience Observations relevant for classification: Further Observations: Repeated or prolonged exposure may cause skin irritation and dermatitis, due to degreasing properties of the product. Classification of the preparation has been done by calculation in accordance with EEC directives. SECTION 12: Ecological information 12.1 Toxicity We have no quantitative data concerning the ecological effects of this product. An environmental hazard cannot be excluded in the event of unprofessional handling or disposal. Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment Persistence and degradability No data is available on the product itself Bioaccumulative potential 12.4 Mobility in soil 12.5 Results of PBT and vpvb assessment This mixture contains no substances which are assessed to be PBT or vpvb Other adverse effects COD-Value, mg/g: BOD5-Value, mg/g: AOX-Remarks: Not applicable Significant Components: Hydrocarbons Other adverse effects: Not applicable.
6 Safety Data Sheet in Accordance with regulation 2015/830 Page 6 of 7 SECTION 13: Disposal considerations 13.1 Waste treatment methods Recommendation: Waste - Code - No.: The Waste code should be assigned in discussion between the user, the producer and the waste disposal company. In addition comply with the regional authorities Contaminated Packaging Recommendation: Wash with suitable cleaner. Otherwise as described under Residues Safe Handling: As described under Residues. SECTION 14: Transport information ADR IMDG IATA 14.1 UN number UN proper shipping name UN 1950 Druckgaspackungen 14.3 Transport hazard class(es) Druckgaspackungen (Hydrocarbons, C6-7) MARINE POLLUTANT Aerosols, flammable 14.4 Packing group n.ap. n.ap. n.ap Environmental hazards 14.6 Special precautions for user Transport category: 2 Classification Code: 5F Hazard - No.: n.ap. LQ: 1 L Yes. F-D, S-U 14.7 Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code Packing Instructions (Passenger) 203 Packing Instructions (Cargo) 203 SECTION 15: Regulatory information 15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture 15.2 Chemical safety assessment : n.ap.
7 Safety Data Sheet in Accordance with regulation 2015/830 Page 7 of 7 SECTION 16: Other information Text of H phrases mentioned in Section 3 EUH066: Repeated exposure may cause skin dryness or cracking. H225: Highly flammable liquid and vapour. H226: Flammable liquid and vapour. H304: May be fatal if swallowed and enters airways. H315: Causes skin irritation. H336: May cause drowsiness or dizziness. H361f: Suspected of damaging fertility. H373: May cause damage to organs <or state all organs affected, if known> through prolonged or repeated exposure <state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard>. H411: Toxic to aquatic life with long lasting effects. H412: Harmful to aquatic life with long lasting effects. This datasheet has been compiled in accordance with EU regulation 2015/830. The statements in this Material Safety Data Sheet were made to the best of our knowledge and are as accurate as possible. They are given for information only. They do not constitute a contractual guarantee of a product s properties. They must neither be altered nor transferred to other products. Prepared by: CoSiChem AG, Ernst-Lemmer-Straße 23, D Marburg, info@cosichem.de, Receipt of Data: , clg_0312
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